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Physical Chemistry Chemical Physics

Rigorous solutions of a particle in δ potential fields in phase space

Jun Lu, Qian‐Shu Li, Zheng Sun

Published Jan 1, 2001• 6 citations
Publisher

Abstract

Within the framework of the quantum phase-space representation established by Torres-Vega and Frederick, the rigorous solutions of the Schrödinger equations of a particle in the δ potential fields are solved, and the Heisenberg uncertainty principle is interpreted in the phase space. Then it is found that, for the bound state of a particle in the δ potential well, the Wigner distribution function is the special result of the quantum phase-space probability density function with parameter k approaching infinity.

DOI
10.1039/b008186h

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Within the framework of the quantum phase-space representation established by Torres-Vega and Frederick, the rigorous solutions of the Schrödinger equations of a particle in the δ potential fields are solved, and the Heisenberg uncertainty principle is interpreted in the phase space. Then it is found that, for the bound state of a particle in the δ potential well, the Wigner distribution function is the special result of the quantum phase-space probability density function with parameter k approaching infinity.
This paper discusses the relationship between the Wigner function, along with other related quasiprobability distribution functions, and the probability density distribution function constructed from the wave function of the Schr\"odinger equation in quantum phase space, as formulated by Torres-Vega and Frederick (TF). At the same time, a general approach in solving the wave function of the Schr\"odinger equation of TF quantum phase space theory is proposed. The relationship of the wave functions between the TF quantum phase space representation and the coordinate or momentum representation is thus revealed.
The rigorous solutions of the stationary Schrodinger equation for hydrogen atom are solved with the wave-mechanics method within the framework of the quantum phase-space representation established by Torres-Vega and Frederick. The Fourier-like projection transformations of wave function from the phase space to position and momentum spaces are extended to three-dimensional systems. The eigenfunctions in general position and momentum spaces could be obtained through the transformations from eigenfunction in the phase space.