Exact numerical calculations are made for the scattering of quantum mechanical particles from a square two-dimensional potential barrier. This treatment is an exact analog of both frustrated total reflection of perpendicularly polarized light and the longitudinal Goos-Hänchen shift. Quantum mechanical streamlines (which are analogous to either classical mechanical trajectories or optical rays) are plotted. These streamlines are smooth, continuous, and have continuous first derivatives even through the classically forbidden region. The streamlines form quantized vortices surrounding each of the nodal points (which result from interference between the incident and reflected waves). Similar vortices occur in reactive collisions of H + H2 (McCullough and Wyatt; Kuppermann, Adams, and Truhlar) and undoubtedly play an important role in molecular collision dynamics. The theory for these vortices is given in a companion paper. A comparison is given between our numerical calculations and the stationary phase approximation (SPA). Although our incident wave packet has a half-width of more than one de Broglie wavelength in contrast to the SPA which replaces the diffuse beams by rays with delta function profiles, the agreement was surprisingly good for both the Goos-Hänchen shifts and for the reflection coefficients. However, we found that the Goos-Hänchen shift for the transmitted beam is significantly smaller than for the reflected beam, although in the stationary phase approximation these two shifts are equal. Furthermore, we found that the scattering from the potential barrier has very little effect on the shape of the wave packets. The power series expansion of the incident Debye-Picht wave packet ψI has an extremely small radius of convergence, whereas the power series for ψI*ψI has a radius of convergence of more than two de Broglie wavelengths. The imaginary velocity viis introduced into the Madelung-Landau-London hydrodynamical formulation of quantum mechanics. The corresponding imaginary streamlines will be considered in a forthcoming paper. The time-independent Schrödinger equation for real wavefunctions is reduced to solving the nonlinear first order partial differential equation: ℏ▿·vi = 2(E − V) + vi2. Here, vi is irrotational. This equation may lead to interesting new methods of solving the Schrödinger equation. It does lead to a generalization of the Prager-Hirschfelder perturbation scheme which invokes an electrostatic analogy. The philosophical implications of the hydrodynamical formulation of quantum mechanics are discussed. Penetration of a one-dimensional square potential barrier is used to demonstrate exactly how tunneling occurs by particles ``riding over the barrier'' à la Bohm. Cases are cited where quantum and classical mechanical motions are identical.
Abstract We apply Brunetti and Fredenhagen’s concept of the time of occurrence of an event in quantum mechanics Brunetti and Fredenhagen (2002 Phys. Rev. A 66 044101) to the example of scattering off a spherical potential. Thereby, we re-derive the expression of Froissart, Goldberger, and Watson for the angular time delay Froissart et al (1963 Phys. Rev. 131 2820), clarifying some conceptual issues with their derivation. We also present an elementary re-derivation of the ‘space shift’ (essentially the impact parameter) defined in the quantum mechanical context by the same authors. We clarify the relation of both quantities to their classical counterparts in the context of the WKB approximation. As an example, we apply the concepts to scattering at a hard sphere. We find pronounced peaks in the both the time delay and the space shift at the minima of intensity in the forward diffraction region for short wavelength scattering and discuss whether these could in principle be observable.
We study the near-threshold behavior of scattering phase shifts, quantum reflection amplitudes, and quantization functions for systems described by a circularly symmetric potential in two spatial dimensions. In contrast to the three-dimensional case, the centrifugal potential $({m}^{2}\ensuremath{-}\frac{1}{4}){\ensuremath{\hbar}}^{2}∕(2M{r}^{2})$ is nonvanishing and even attractive for
s waves,
m=0, and the leading near-threshold energy dependence of phase shifts and amplitudes for scattering and quantum reflection is logarithmic in this case. The near-threshold behavior of the
s-wave phase shifts and amplitudes can nevertheless be characterized by a well-defined scattering length (for potentials falling off faster than
1∕r2) and an effective range (for potentials falling off faster than
1∕r4). For a potential with a bound state at energy ${E}_{n}=\ensuremath{-}{\ensuremath{\hbar}}^{2}{\ensuremath{\kappa}}_{n}^{2}∕(2M)$ very near threshold, the scattering length obeys $a\stackrel{{\ensuremath{\kappa}}_{n}\ensuremath{\rightarrow}0}{\ensuremath{\sim}}2{e}^{\ensuremath{-}{\ensuremath{\gamma}}_{\mathrm{E}}}∕{\ensuremath{\kappa}}_{n}+O({\ensuremath{\kappa}}_{n})$, with no term of order ${\ensuremath{\kappa}}_{n}^{0}$---in contrast to the three-dimensional case. Analytical results are derived for homogeneous potentials, and the necessary modification of the effective-range expansion is given for potentials proportional to
1∕r4. For $m\ensuremath{\ne}0$ we give analytical expressions for the near-threshold behavior of phase shifts as well as scattering and quantum reflection amplitudes, which are generally valid, even when
m is neither integer nor half-integer.
The concept of a generalized scattering amplitude is introduced and applied to quantum potential scatterings. After an outgoing spherical wave is factored out from a wave function, the remaining wave envelope is defined as the generalized scattering amplitude. The transformed Schr\"odinger equation, in terms of the generalized scattering amplitude, can be solved numerically by using a finite-difference method over the entire scattering domain. Example problems of scatterings by a spherical potential well and the (${\mathit{e}}^{\mathrm{\ensuremath{-}}}$,H) static field interaction potential are solved to validate the theoretical formulation and numerical method. The far-field solutions for the ordinary scattering amplitude and differential cross section agree very well with those obtained from the partial-wave analysis. The radial profiles of the generalized scattering amplitude and particle density function over the entire scattering region are also presented, and their properties are discussed. These results demonstrate that the method can be used to yield a complete and accurate solution to scattering problems involving arbitrary interaction potentials.
Quantum emitters coupled to traveling photons in waveguides, known as waveguide quantum electrodynamics (WQED), offer a powerful platform for understanding light-matter interactions and underpinning emergent quantum technologies. While WQED has been extensively studied in one dimension, two-dimensional (2D) WQED remains largely unexplored, where novel photonic scattering phenomena unique to higher dimensions are expected. Here, we present a comprehensive scattering theory for 2D WQED based on the Green function method. We show that the mean displacement between emitted and injected photons serves as a quantum analogue of the Goos-Hänchen shift. When a photon is injected into a single off-centered port, the quantum Goos-Hänchen (QGH) shift can be enhanced in backward scattering under resonant conditions with subradiant states. When a photon is injected into the center port, there is no QGH shift due to the mirror symmetry of structure. However, for multiple-port injection with transverse momentum, the QGH shift is recovered and proportional to the derivative of phase with respect to transverse momentum. Unlike the classical Goos-Hänchen shift, these effects can be flexibly tuned by the injected photon's frequency. Our work provides a general framework for exploring and manipulating photonic scattering in complex WQED networks.