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International Journal of Modern Physics B

THERMODYNAMICS OF THE TODA CHAIN

Alessandro Cuccoli, Roberto Livi, M. Spicci, V. Tognetti, Ruggero Vaia

Published Aug 15, 1994• 12 citations
Publisher

Abstract

A review of the classical and quantum thermodynamic properties of the Toda chain is provided, together with a survey of the techniques that have been used to work them out, i.e., the bilateral Laplace transform method for the classical system, the Bethe–Ansatz and the variational path-integral approach for the quantum one. For the classical Toda chain we also recall some of the main dynamical features, i.e. the integrability of the model and the soliton-like solutions of the equations of motion. In the quantum case a comparison between the Bethe–Ansatz and the variational method is made. In particular it is shown as the latter offers the possibility of also evaluating static correlation functions.

DOI
10.1142/s021797929400097x

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A review of the classical and quantum thermodynamic properties of the Toda chain is provided, together with a survey of the techniques that have been used to work them out, i.e., the bilateral Laplace transform method for the classical system, the Bethe–Ansatz and the variational path-integral approach for the quantum one. For the classical Toda chain we also recall some of the main dynamical features, i.e. the integrability of the model and the soliton-like solutions of the equations of motion. In the quantum case a comparison between the Bethe–Ansatz and the variational method is made. In particular it is shown as the latter offers the possibility of also evaluating static correlation functions.
The aim of the explicit evaluation of the equilibrium thermodynamic properties of the quantum Toda lattice is reached here by a method that reduces the evaluation of quantum-statistical averages to a classical configurational integral. This is done by constructing an effective potential of the same form as the original one, whose parameters are renormalized by the quantum fluctuations. In addition to quantum specific heat (in agreement with Bethe-ansatz calculations), explicit results for meaningful static correlation functions are reported.
A very curious situation arises in the context of the calculation of the partition function from the spectrum of an integrable Hamiltonian. Despite the validity of the Bethe ansatz equations for all energy eigenvalues of the model the direct evaluation of the partition function is rather difficult. In contrast to ideal quantum gases the eigenstates are not explicitly known: the Bethe ansatz equations provide just implicit descriptions that pose problems of their own kind. Yet, knowing the behaviour of quantum chains at finite temperatures is important for many reasons. As a matter of fact, the groundstate is strictly inaccessible due to the very fundamentals of thermodynamics. Therefore the study of finite temperatures is relevant for theoretical as well as experimental reasons. At high temperatures, quantum systems show only trivial static properties without correlations. Lowering the temperature, the systems enter a large regime with non-universal correlations and finally approach the quantum critical point at exactly zero temperature showing universal, non-trivial properties with divergent correlation lengths governed by conformal field theory [51]. In Chapter 5 of this book we have discussed the traditional Thermodynamical Bethe Ansatz (TBA) as developed for the Heisenberg model and the Hubbard model [155, 433–435] on the basis of a method [496] invented for the Bose gas.
In our previous work thermodynamics of two-componet (soliton and phonon) gas is constructed from the Yang-Yang equation for one-component integrable quantum gas. We call this the two-component Bethe ansatz (TCBA) scheme. The method is applied to the Toda lattice and its classical limit is analyzed. The key parameter kF which distinguishes solitons from phonons within the TCBA scheme is chosen such that the resultant equations for effective energies of the modes coincide with those expected from the simple-minded ideal-gas phenomenology. The soliton specific heat exhibits a peculiar temperature dependence at low temperatures. It is however compensated with the anharmonic part of phonons.
We obtain the exact generalized hydrodynamics for the integrable Toda system. The Toda system can be seen in a dual way, both as a gas and as a chain. In the gas point of view, using the elastic and factorized scattering of Toda particles, we obtain the generalized free energy and exact average currents and write down the Euler hydrodynamic equations. This is written both as a continuity equation for the density of asymptotic momenta and in terms of normal modes. This is based on the classical thermodynamic Bethe ansatz (TBA), with a single quasiparticle type of Boltzmann statistics. By explicitly connecting chain and gas conserved densities and currents, we then derive the thermodynamics and hydrodynamics of the chain. As the gas and chain have different notions of length, they have different hydrodynamics, and, in particular, the velocities of normal modes differ. We also give a derivation of the classical TBA equations for the gas thermodynamics from the factorized scattering of Toda particles.
A linear chain with exponential plus linear interactions (Toda lattice) can be mapped by the Bethe ansatz to a Fermi gas. The thermodynamics is treated by analogy to the delta-function Bose gas (Yang and Yang). Analytical solutions are given for the strongly anharmonic regime and low temperatures; the general case is treated numerically. For the case of weak anharmonicity the specific heats are compared with earlier approximate calculations. The anharmonic part of the specific heat is shown to be not very different from the corresponding classical result which can be interpreted as the specific heat of an ideal gas of solitons. For the quantum case the soliton-gas picture needs further investigation.