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Physical Review Letters

Prospects for Bose-Einstein Condensation in Cesium

S. J. J. M. F. Kokkelmans, B. Verhaar, Kurt Gibble

Published Aug 1, 1998• 35 citations
Publisher

Abstract

We analyze all of the cold-collision data for Cs, consisting of atomic fountain frequency shifts and elastic scattering rates, to determine phase parameters that completely characterize cold collisions between two ground-state cesium atoms. We show that the fast decays of spin-polarized gas samples in two recent attempts to reach Bose-Einstein condensation in cesium are due to potential and Feshbach resonances which enhance the depolarizing atom-atom collisions. We discuss the prospects for realizing Bose-Einstein condensation in ${}^{133}\mathrm{Cs}$ and in ${}^{135}\mathrm{Cs}$.

DOI
10.1103/physrevlett.81.951

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We study conditions necessary for the observation of Bose-Einstein condensation in a magnetically trapped sample of atomic Cs gas. These conditions are associated with the value of the elastic scattering length, the rate of elastic scattering events, and the lifetime for decay of the density due to both magnetic dipole relaxation in two-body collisions, as well as recombination to Cs2{\mathrm{Cs}}_{2}Cs2​ in three-body collisions. We find that, on the basis of these conditions, the prospects for observing Bose-Einstein condensation are favorable for a gas of ground-state Cs atoms in the highest state of the lowest hyperfine manifold. In all calculated elastic and inelastic two-body rates we find a pronounced resonance structure, which can be understood in terms of the interplay between the singlet-triplet interaction and the hyperfine, Zeeman, and magnetic dipole interactions. The experimental observation of these resonances may help to eliminate present uncertainties about interaction potentials.
We study necessary conditions for the observation of Bose–Einstein condensation in a magnetically trapped sample of atomic cesium gas. These constraints are due to interatomic collisions in the sample. We show that the prospects for observing Bose–Einstein condensation are favorable for a gas of ground-state Cs atoms in the highest state of the lowest hyperfine manifold. An interesting aspect of the calculations is that the scattering length for this f = 3, m f = −3 hyperfine state shows pronounced resonance structures as a function of applied magnetic field leading to variations of two orders of magnitude. Most importantly, the scattering length can change sign near the resonances. This suggests a controllable means to change the behavior of the Bose condensate because for negative values a condensate is unstable and other (quantum-)collective effects might be observed. The origin of the resonances is understood from the bound singlet and triplet rovibrational Cs 2 states which are perturbed due to the hyperfine and Zeeman interactions. It is a long standing goal to achieve quantum-collective effects in atomic Fermi- or Bose gases. The prominent reasons are that for a relatively simple system with low density, a microscopic theoretical treatment of the phase transition is still feasible, and to have an experimental testing ground for more complicated quantum-coherent effects such as superfluidity in 4 He and superconductivity in metals. Here, we focus on atomic species which behave as (composite) bosons.
Ultracold Cs2_22​ Feshbach Spectroscopy
We have observed and located more than 60 magnetic field-induced Feshbach resonances in ultracold collisions of ground-state 133^{133}133Cs atoms. These resonances are associated with molecular states with up to four units of rotational angular momentum, and are detected through variations in the elastic, inelastic, and radiative collision cross sections. These observations allow us to greatly improve upon the interaction potentials between two cesium atoms and to reproduce the positions of most resonances to accuracies better than 0.5%. Based on the relevant coupling scheme between the electron spin, nuclear spin, and orbital angular momenta of the nuclei, quantum numbers and energy structure of the molecular states beneath the dissociation continuum are revealed. Finally, we predict the relevant collision properties for cesium Bose-Einstein condensation experiments.
We observe several Feshbach resonances in magnetic fields below 40 G for Cs atoms trapped in a 1D optical lattice. One resonance occurs in the lowest-energy ground state F=3F\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3F=3, mF=3{m}_{F}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3mF​=3 which is stable against inelastic binary collisions. This opens new possibilities for Bose condensation of Cs. When the elastic collision rate far exceeds the radial vibration frequency, we enter a 2D hydrodynamic regime where the thermalization rate is independent of density and temperature. Other resonances are also observed in the F=3F\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3F=3, ${m}_{F}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\ensuremath{-}3$ state through a dramatic increase in the dipolar relaxation rate.
We have measured the elastic collision cross section for spin polarized atomic cesium. Neutral cesium atoms are optically cooled, then loaded into a dc magnetic trap. We infer the scattering rate from the rate at which anisotropies in the initial energy distribution are observed to relax. The cross section for F=3, mF{\mathit{m}}_{\mathit{F}}mF​=-3 on F=3, mF{\mathit{m}}_{\mathit{F}}mF​=-3 is 1.5(4)\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}12}$ cm2{\mathrm{cm}}^{2}cm2, and is independent of temperature from 30 to 250 \ensuremath{\mu}K. This determination clarifies the technical requirements for attaining Bose-Einstein condensation in a magnetically trapped Cs vapor. We also study heating due to glancing collisions with 300 K background Cs atoms.
We have measured the rate of inelastic collisions in a cloud of doubly polarized ground-state cesium atoms ( F=mF=4{F\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}m}_{F}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}4F=mF​=4) confined in a magnetic trap for temperatures TTT between 8 and $70\ensuremath{\mu}\mathrm{K}$. We find a two-body rate coefficient varying as ${T}^{\ensuremath{-}0.63}$. At 8 $\ensuremath{\mu}\mathrm{K}$ it reaches $4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}12}\phantom{\rule{0ex}{0ex}}{\mathrm{cm}}^{3}{\mathrm{s}}^{\ensuremath{-}1}$ which is 3 orders of magnitude larger than predicted, ruling out a Bose-Einstein condensation of Cs in this internal state.