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Journal of Superconductivity and Novel Magnetism

Multicondensate Superconductivity in a Generalized BEC Formalism with Hole Cooper Pairs

Israel Chávez, M. Grether, MANUEL DE LLANO

Published Dec 12, 2014• 1 citation
Publisher
DOI
10.1007/s10948-014-2904-6

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The role in superconductors of hole-Cooper-pairs (CPs) are examined and contrasted with the more familiar electron-CPs, with special emphasis on their “background” effect in enhancing superconducting transition temperatures Tc — even when electron-CPs drive the transition. Both kinds of CPs are, of course, present at all temperatures. An analogy is drawn between the hole CPs in any many-fermion system with the antibosons in a relativistic ideal Bose gas that appear in substantial numbers only at higher and higher temperatures. Their indispensable role in yielding a lower Helmholtz free energy equilibrium state is established. For superconductors, the problem is viewed in terms of a generalized Bose-Einstein condensation (GBEC) theory that is an extension of the Friedberg-T.D. Lee 1989 boson-fermion BEC theory of high-Tc superconductors in that the GBEC theory includes hole CPs as well as electron-CPs — thereby containing as well as further extending BCS theory to higher temperatures with the same weak-coupling electron-phonon interaction parameters. We show that the Helmholtz free energy of both 2e- and 2h-CP pure condensates has a positive second derivative, and are thus stable equilibrium states. Finally, it is conjectured that the role of hole pairs in ultra-cold fermionic atom gases will likely be negligible because the very low densities involved imply a “shallow” Fermi sea.

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Abstract A recent re‐examination of BCS theory leads one to devise a generalized BEC formalism (GBEC), that is, essentially a boson‐fermion (BF) model containing three new ingredients: (i) Cooper pairs (CPs), in contrast to BCS pairs, as real bosons; (ii) BF vertex interactions (analogous to electron‐phonon vertices); and (iii) two‐hole CPs (2hCPs) accounted for along with two‐electron CPs (2eCPs). In addition to the usual normal phase at high‐enough temperaturesT, three condensed phases emerge at lower temperatures with substantially higherTcs than BCS theory. These are: two pure BEC phases of 2eCPs and of 2hCPs as well as a mixed phase with both kinds of CPs. BCS theory is precisely recovered with a mixed phase of equal numbers of both kinds of CPs. In contrast to the well‐known BCS exponential rise from zero ofTcas function of carrier‐number density the GBEC scheme exhibits the linear rise as function of doping as eminently observed in high‐Tcunderdoped superconductors such as YBCO. © 2012 Wiley Periodicals, Inc.

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The role in superconductors of hole-Cooper-pairs (CPs) are examined and contrasted with the more familiar electron-CPs, with special emphasis on their “background” effect in enhancing superconducting transition temperatures Tc — even when electron-CPs drive the transition. Both kinds of CPs are, of course, present at all temperatures. An analogy is drawn between the hole CPs in any many-fermion system with the antibosons in a relativistic ideal Bose gas that appear in substantial numbers only at higher and higher temperatures. Their indispensable role in yielding a lower Helmholtz free energy equilibrium state is established. For superconductors, the problem is viewed in terms of a generalized Bose-Einstein condensation (GBEC) theory that is an extension of the Friedberg-T.D. Lee 1989 boson-fermion BEC theory of high-Tc superconductors in that the GBEC theory includes hole CPs as well as electron-CPs — thereby containing as well as further extending BCS theory to higher temperatures with the same weak-coupling electron-phonon interaction parameters. We show that the Helmholtz free energy of both 2e- and 2h-CP pure condensates has a positive second derivative, and are thus stable equilibrium states. Finally, it is conjectured that the role of hole pairs in ultra-cold fermionic atom gases will likely be negligible because the very low densities involved imply a “shallow” Fermi sea.
Abstract A recent re‐examination of BCS theory leads one to devise a generalized BEC formalism (GBEC), that is, essentially a boson‐fermion (BF) model containing three new ingredients: (i) Cooper pairs (CPs), in contrast to BCS pairs, as real bosons; (ii) BF vertex interactions (analogous to electron‐phonon vertices); and (iii) two‐hole CPs (2hCPs) accounted for along with two‐electron CPs (2eCPs). In addition to the usual normal phase at high‐enough temperaturesT, three condensed phases emerge at lower temperatures with substantially higherTcs than BCS theory. These are: two pure BEC phases of 2eCPs and of 2hCPs as well as a mixed phase with both kinds of CPs. BCS theory is precisely recovered with a mixed phase of equal numbers of both kinds of CPs. In contrast to the well‐known BCS exponential rise from zero ofTcas function of carrier‐number density the GBEC scheme exhibits the linear rise as function of doping as eminently observed in high‐Tcunderdoped superconductors such as YBCO. © 2012 Wiley Periodicals, Inc.