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Chemical Physics

Path-integral approach to a semiclassical stochastic description of quantum dissipative systems

Jesús Casado‐Pascual, Claus Denk, Manuel Morillo, Robert I. Cukier

Published Jun 1, 2001• 5 citations
Publisher
DOI
10.1016/s0301-0104(01)00301-9

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We develop the path integral theory for master equations of general Lindblad form (positive semigroups), describing Markovian open quantum systems. First the Hamiltonian path integral expression for the propagator is derived, which exhibits nicely the decoherence of pairs of phase space histories. A very appealing picture arises in the semiclassical limit where the degree of decoherence is expressible in terms of a phase space decoherence distance functional. For the important class of (effective) Hamiltonians quadratic in the momenta, we derive the Lagrangian version of the path integral propagator. We then evaluate the path integral approximately in a stationary phase approximation, leading to a Van Vleck-type propagator valid under semiclassical conditions. We also derive the propagator for the soluble damped harmonic oscillator in closed form from path integrals. Finally, connections to the active field of stochastic pure-state descriptions of open quantum systems are established, here in particular to linear quantum state diffusion.
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