In this paper, the non-exponential decay is analyzed with the help of simple computer experiments performed by T. Petrosky, simulating classical radiation damping. The non-exponential decay is studied and shown to depend on the preparation of the system. However, whatever the initial preparation, the system reaches the decay predicted by classical radiation theory after a short time we call the Zeno's time. The similitude of Petrosky's results with computer experiments for the approach to equilibrium in many-body systems is emphasized. However, while there one deals with times which are multiple of the relaxation time, the irreversibility manifest in radiation theory occurs always over a much shorter time scale, the Zeno's time. In atomic systems, this would be a time order of 10/sup /minus/18/ seconds. These results are of great interest for the understanding of the microscopic mechanism of radiation. Let us consider a charged oscillator. In a first stage, this oscillator has to produce the field oscillators to which it may transfer energy through the usual resonance mechanism. Radiation appears therefore as a kind of non linear autocatalytic process, involving a self-organization mechanism. The behavior during the Zeno period can be explained easily in terms of subdynamics as introduced by the Brussel's group. We see that there is no transition from reversibility to irreversibility. Irreversible processes start at the very moment at which the system is prepared. It is important to stress that an unstable particle is itself the result of irreversible processes. As a result, an unstable particle (or an excited atomic state) can no more be described in terms of wave functions, as irreversible processes are not included in Schroedinger's equation. 14 refs. 3 figs.
In this paper, the non-exponential decay is analyzed with the help of simple computer experiments performed by T. Petrosky, simulating classical radiation damping. The non-exponential decay is studied and shown to depend on the preparation of the system. However, whatever the initial preparation, the system reaches the decay predicted by classical radiation theory after a short time we call the Zeno's time. The similitude of Petrosky's results with computer experiments for the approach to equilibrium in many-body systems is emphasized. However, while there one deals with times which are multiple of the relaxation time, the irreversibility manifest in radiation theory occurs always over a much shorter time scale, the Zeno's time. In atomic systems, this would be a time order of 10/sup /minus/18/ seconds. These results are of great interest for the understanding of the microscopic mechanism of radiation. Let us consider a charged oscillator. In a first stage, this oscillator has to produce the field oscillators to which it may transfer energy through the usual resonance mechanism. Radiation appears therefore as a kind of non linear autocatalytic process, involving a self-organization mechanism. The behavior during the Zeno period can be explained easily in terms of subdynamics as introduced by the Brussel's group. We see that there is no transition from reversibility to irreversibility. Irreversible processes start at the very moment at which the system is prepared. It is important to stress that an unstable particle is itself the result of irreversible processes. As a result, an unstable particle (or an excited atomic state) can no more be described in terms of wave functions, as irreversible processes are not included in Schroedinger's equation. 14 refs. 3 figs.
The temporal behavior of quantum mechanical systems is reviewed. We mainly focus our attention on the time development of the so-called “survival” probability of those systems that are initially prepared in eigenstates of the unperturbed Hamiltonian, by assuming that the latter has a continuous spectrum. The exponential decay of the survival probability, familiar, for example, in radioactive decay phenomena, is representative of a purely probabilistic character of the system under consideration and is naturally expected to lead to a master equation. This behavior, however, can be found only at intermediate times, for deviations from it exist both at short and long times and can have significant consequences. After a short introduction to the long history of the research on the temporal behavior of such quantum mechanical systems, the short-time behavior and its controversial consequences when it is combined with von Neumann’s projection postulate in quantum measurement theory are critically overviewed from a dynamical point of view. We also discuss the so-called quantum Zeno effect from this standpoint. The behavior of the survival amplitude is then scrutinized by investigating the analytic properties of its Fourier and Laplace transforms. The analytic property that there is no singularity except a branch cut running along the real energy axis in the first Riemannian sheet is an important reflection of the time-reversal invariance of the dynamics governing the whole process. It is shown that the exponential behavior is due to the presence of a simple pole in the second Riemannian sheet, while the contribution of the branch point yields a power behavior for the amplitude. The exponential decay form is cancelled at short times and dominated at very long times by the branch-point contributions, which give a Gaussian behavior for the former and a power behavior for the latter. In order to realize the exponential law in quantum theory, it is essential to take into account a certain kind of macroscopic nature of the total system, since the exponential behavior is regarded as a manifestation of a complete loss of coherence of the quantum subsystem under consideration. In this respect, a few attempts at extracting the exponential decay form on the basis of quantum theory, aiming at the master equation, are briefly reviewed, including van Hove’s pioneering work and his well-known “λ2T” limit. In the attempt to further clarify the mechanism of the appearance of a purely probabilistic behavior without resort to any approximation, a solvable dynamical model is presented and extensively studied. The model describes an ultrarelativistic particle interacting with N two-level systems (called “spins”) and is shown to exhibit an exponential behavior at all times in the weak-coupling, macroscopic limit. Furthermore, it is shown that the model can even reproduce the short-time Gaussian behavior followed by the exponential law when an appropriate initial state is chosen. The analysis is exact and no approximation is involved. An interpretation for the change of the temporal behavior in quantum systems is drawn from the results obtained. Some implications for the quantum measurement problem are also discussed, in particular in connection with dissipation.
The quantum-mechanical theory of the decay of unstable states is revisited. We show that the decay is non-exponential both in the short-time and long-time limits using a more physical definition of the decay rate than the one usually used. We report results of numerical studies based on Winter's model that may elucidate qualitative features of exponential and non-exponential decay more generally. The main exponential stage is related to the formation of a radiating state that maintains the shape of its wave function with exponentially diminishing normalization. We discuss situations where the radioactive decay displays several exponents. The transient stages between different regimes are typically accompanied by interference of various contributions and resulting oscillations in the decay curve. The decay curve can be fully oscillatory in a two-flavor generalization of Winter's model with some values of the parameters. We consider the implications of that result for models of the oscillations reported by GSI.
The compatibility of irreversibility, as expressed by the second law of thermodynamics, with ordinary quantum mechanics requires an extension of the latter. Such an extension of a reversible formalism is made possible by the presence of self-energy processes (already found in quantum electrodynamics), which allows for the widening of the dynamics through the introduction of specific additional variables leading to the recognition of such processes. A projection technique modeled on that introduced long ago by the Brussels group defines a subdynamics that is shown to contain the starting formulation in its entirety. (It corresponds to a restricted class of initial conditions, namely the reversible ones.) A new kinetic description is obtained in which, e.g., collision processes for privileged components arise from the original interaction. This method is applied successively to various models, and we focus in this paper on the possible presence of temporal behaviour excluded in ordinary quantum mechanics. Among the differences between this framework and that of ordinary quantum mechanics, the possibility appears for the purely exponential decay of a particle, while ordinary quantum mechanics requires long time tails associated with the finite lower bound in the spectrum of the Hamiltonian.
Recent development of spectral analysis of the Liouville-von Neumann equation has revealed the fact that irreversibility is a rigorous dynamical property of Poincaré non-integrable systems with an infinite degrees of freedom interacting among each other through resonance coupling. In the present work we discuss this role of resonance in some examples of matter-field coupling systems for both classical and quantum mechanics: the one is a classical motion of a charged particle in electromagnetic waveguide, and the other is the decoherence problem of quantum matter-field interacting systems. In the first part of this dissertation, we study an accelerated motion of a charged classical dipole molecule with frequency ω1 inside the rectangular waveguide. If the particle is in free space, it is well known that its accelerated motion will eventually stop by radiating the field through the resonance interaction. This result is the so-called radiation damping. For the case in the waveguide, there are two possible situations, due to the existence of the cut-off frequency ωc of the waveguide. Under the cut-off frequency electromagnetic wave cannot propagate inside the waveguide. The stability of the dipole depends on the relation between ω1 and ωc. For ω1 < ωc, the dipole cannot resonate with the field. This corresponds to the Poincaré integrable system. For this case the dipole keeps its accelerated motion without emitting the radiating field. Therefore the radiation damping of the dipole molecules is suppressed inside the waveguide under the absence of resonance interaction. The motion of this steady state somewhat resembles a quantum ground state. We show that this steady state is dressed by electromagnetic field. The overlap of the dressing field leads to a force analogous to van der Waals force in quantum mechanics. The critical frequency determined by ω1 = ωc gives a critical size of the waveguide. For heavy molecules, such as HCl, this is of order 10−5m. We show that the size of the dressing field is the same order of the size of the waveguide. Hence we have a macroscopic size of the dressing in the waveguide. For ω1 > ωc, the dipole can resonate with the field, and the system becomes non-integrable in the sense of Poincaré. As a result, the accelerated motion eventually stop by emitting the resonance field. This corresponds to the problem of classical radiation damping. We show that there is non-negligible deviation of exponential decay in a short time scale of the order t ∼ 1/ω1. This corresponds to the quantum Zeno effect, well known in quantum unstable systems. After this period, the dipole decays exponentially in time by emitting the resonance field. We found by choosing ωc very close to ω1, we can increase the decay rate 105 times faster than the case where the dipole is in the free space, at the same time the emitted field travel 10−4 times slower than the speed of light. This is again a consequence of the existence of the cut-off frequency in the waveguide. Indeed, the cut-off frequency leads to a non-linear dispersion relation for the electromagnetic field. To some extent, the electromagnetic field is sticky inside the waveguide. Due to the large decay rate and slower speed of light, the size of the wavepacket emitted by the dipole is significantly small (about 10cm for HCl). This is even smaller than the quantum case in free space, where the wavepacket of the field emitted by the decay of electron in hydrogen atom is about 1m. In the second part of this dissertation, we study a quantum matter-field coupled system. We focus our attention on the problem of quantum decoherence in a system of a particle coupled with a field, the Hamiltonian of which has a similar structure to the problem of classical radiation damping mentioned above. We apply the complex spectral representation of the Liouville-von Neumann operator that gives a rigorous approach to the irreversible processes. We focus our attention on the time evolution of the field, which is commonly neglected in phenomenological approaches to the decoherence problem. We found a signature of decoherence in the field which has a characteristic time dependence proportional to t that comes from the secular effect between the particle and the field through the resonance interaction that breaks time-symmetry.
A discussion of the quantum Zeno effect and paradox is given. The quantum Zeno paradox claims that a continuously observed system, prepared in a state which is not an eigenstate of the Hamiltonian operator, never decays. To recover the classical behavior of unstable systems we consider a two-level system interacting with a Bose field, respectively prepared in the excited state and in the Poincare invariant vacuum state. Using time-dependent perturbation theory, we evaluate for a finite time interval the probability of spontaneous decay of the two-level system. Using the standard argument to obtain the quantum Zeno paradox, we consider N measurements where N goes to infinity and we obtain that the non-decay probability law is a pure exponential, therefore recovering the classical behavior.
Introduction The preceding chapters have focused on atomic transitions induced by applied radiation. That is, there is an optical field illuminating the atoms, and their response is calculated. It is implicitly assumed that an excited atom left alone will spontaneously return to the ground state, and conserve energy by emitting light that satisfies E 2 − E 1 = ħ ω 21 in accordance with the Planck and Bohr pictures. But this spontaneous emission process is not addressed quantitatively in these earlier chapters. Spontaneous emission is one of the most pervasive phenomena of atomic physics, and yet its origins remain among the least well-understood. The number of misconceptions is enormous, and they are to be found in textbooks, journal articles, and lecture notes. Because the natural decay of an excited atom adds energy to what is usually an empty mode of the electromagnetic field, the process is fundamentally quantum mechanical. Classical or even semi-classical descriptions cannot be assured to give correct answers. This is not to say that such discussion is to be avoided, but only that caution is needed in interpreting the results. Toward the end of the nineteenth century, many experimental results made it clear that classical mechanics needed to be supplemented by new theories. The first venture into the new physics was Planck's hypothesis that the energy of classical radiating oscillators like those discussed in Chap. 1 would have to be quantized into integer multiples of ħ ω. This notion led to his famous formula for the spectrum of thermal radiation from a non-reflective object (black body), and this formula describes a radiation field in thermodynamic equilibrium with its environment. The result of Planck's hypothesis in the context of thermal equilibrium plays a vital role in the discussion of spontaneous emission. Einstein A - and B -coefficients Soon after Bohr proposed a model of atomic structure consisting of discrete energy levels, connected by radiation whose energy satisfied Δ E = ħω when atoms made transition between them, Einstein published the first serious attempt to connect the absorption and emission processes. Absorption, he reasoned, could occur only in the presence of applied radiation, whereas spontaneous decay occurred without the application of any field.