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The European Physical Journal A

Solution of the master equation for quantum systems weakly coupled to reservoirs and far from thermal equilibrium

Hermann Haken

Published Aug 1, 1974• 7 citations
Publisher
DOI
10.1007/bf01668818

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Relaxation process of a strongly coupled quantum system toward thermal equilibrium

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Markovian quantum master equations are generally thought to satisfy the following three conditions: (i) they describe the dynamics of time scales that are larger than the reservoir correlation time scale, (ii) these stationary solutions give the thermal equilibrium states with a reservoir, and (iii) they can be written in the Lindblad form. In fact, for single systems such as a single harmonic oscillator and a single two-level system, Markovian quantum master equations satisfying all these conditions can be obtained. However, for composite systems, which consist of more than one subsystem coupled with each other, such equations have not been obtained thus far. In this study, we found that we cannot use the Born–Markov approximation for obtaining quantum master equations for composite systems in the strong-coupling regime, no matter how short the reservoir correlation time is.
The master equation currently used to describe a two level atom interacting with a single mode field damped by contact with a thermal reservoir (the damped Jaynes-Cummings model) is shown not to have, as its steady state solution, the expected canonical density operator prescribed by the general principles of statistical mechanics for a system in thermal equilibrium. A modified master equation is derived here which satisfies this requirement. Except for a reservoir at zero temperature, this master equation differs from that which is currently used in that the damping terms contain contributions due to the atom-field interaction.
The study of quantum thermal machines, and more generally of open quantum systems, often relies on master equations. Two approaches are mainly followed. On the one hand, there is the widely used, but often criticized, local approach, where machine sub-systems locally couple to thermal baths. On the other hand, in the more established global approach, thermal baths couple to global degrees of freedom of the machine. There has been debate as to which of these two conceptually different approaches should be used in situations out of thermal equilibrium. Here we compare the local and global approaches against an exact solution for a particular class of thermal machines. We consider thermodynamically relevant observables, such as heat currents, as well as the quantum state of the machine. Our results show that the use of a local master equation is generally well justified. In particular, for weak inter-system coupling, the local approach agrees with the exact solution, whereas the global approach fails for non-equilibrium situations. For intermediate coupling, the local and the global approach both agree with the exact solution and for strong coupling, the global approach is preferable. These results are backed by detailed derivations of the regimes of validity for the respective approaches.