Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physica Scripta

Collisions of Highly Excited Atoms: Experiment and Theory

F. Gounand

Published Jan 1, 1988• 0 citations
Publisher

Abstract

We discuss some recent theoretical as well as experimental advances in collisions involving Rydberg atoms. We recall some basic properties of Rydberg atoms before showing that in most cases a simplified theoretical treatment of Rydberg collisions is possible. On the experimental side, special attention is paid to the opportunity offered by Rydberg states for the study of quasi-resonant processes.

DOI
10.1088/0031-8949/1988/t23/025

Related papers

Rydberg Atoms

Thomas F. Gallagher

In recent years, Rydberg atoms have been the subject of intense study, becoming the testing ground for several quantum mechanical problems. This book provides a comprehensive description of the physics of Rydberg atoms, highlighting their remarkable properties by reference to their behaviour in a wide range of physical situations. Following an overview of the basic properties of Rydberg atoms, their interactions with electric and magnetic fields are analysed in detail. The collisions of Rydberg atoms with neutral and charged species are described, and the use of multichannel quantum defect theory in the study of Rydberg atomic systems is discussed. Experimental and theoretical research in this extensive field is also reviewed, making the book valuable to both graduate students and established researchers in physics and physical chemistry.

Cambridge University Press eBooks•Sep 15, 1994•1,472 citations

Rydberg atoms

Thomas F. Gallagher

Recent investigations of Rydberg atoms are described in an effort to give a picture of their properties, many of which can be understood from the behaviour of the Coulomb radial functions. The authors begin by a discussion of Coulomb wavefunctions, and progress to a description of the energy level structure. The behaviour of Rydberg atoms in electric fields is discussed to provide an understanding of the phenomenon and to show how electric field ionisation may be used as a tool in a wide variety of experiments. Unique opportunities to study the interaction with black-body radiation and vacuum fluctuations are discussed. A survey of the broad range of Rydberg atom collisions, with ground-state atoms and molecules, charged particles and other Rydberg atoms, is presented to show the different physical interactions responsible. This is followed by a brief summary of the study of autoionising Rydberg states, a stepping stone toward the elusive 'double Rydberg' atom. Finally typical experimental procedures are described.

Reports on Progress in Physics•Feb 1, 1988•194 citations

Collisions of Rydberg atoms with ions: A review of recent work on charge transfer from highly excited targets

Keith B. MacAdam

Charge transfer from high‐n atomic targets populates comparably excited states of ionic projectiles. This paper reviews a decade of accelerating experimental and theoretical progress in the field, which offers an unusual variety of challenges in the preparation of initial states and in the analysis of final states. Interesting dynamical questions at the interface of classical and quantum mechanics are posed by new experimental results. Rydberg atom phenomena are increasingly found to be important for other areas of atomic collision physics in all energy regimes.

AIP conference proceedings•Jan 1, 1993•0 citations

Highly excited atomic states

Борис М. Смирнов

The properties of highly excited atoms are examined. Methods for producing and detecting such atoms are analyzed. Various processes that involve atoms in Rydberg states are described, including transitions between high-lying excited states induced by collisions with electrons and atoms, quenching by electrons and atoms, ionization by collisions with electrons, atoms, and molecules, charge exchange with ions, and so on.

Soviet Physics Uspekhi•Aug 31, 1980•15 citations

Orbital alignment effects in near-resonant Rydberg atoms-rare gas collisions

William A. Isaacs, Morrison

Recent experimental and theoretical studies of near-resonant energy transfer collisions involving rare-gas atoms and alkali or alkaline earth atoms which have been initially excited to an aligned state via one or more linearly polarized rasters have yielded a wealth of insight into orbital alignment and related effects. We have extended this inquiry to initially aligned Rydberg states, examining state-to-state and alignment-selected cross sections using quantum collision theory augmented by approximations appropriate to the special characteristics of the Rydberg state (e.g., the quasi-free-electron model and the impulse approximation).

Bulletin of the American Physical Society•May 1, 1993•0 citations

Studies of highly excited atoms

Ravinder Kachru

Rydberg states of atoms have intrinsic properties that should allow their use as highly sensitive and tunable detectors at far infrared wavelengths. The intrinsic limit of such atomic detectors are collisional processes. This report describes the results of a research program to better understand an important class of collisions--namely, the resonant collision of two Rydberg atoms. We have extensively measured the linewidths and the collision cross sections and have determined thier dependence on parameters such as the principal quantum number and the Rydberg state angular momentum. The resonant collisions are shown to occur for a wide variety of initial states with cross sections of the order of 10 to the 9th power square-Angstroms and scaling as (n*O to the 4th order).

sri•Apr 2, 1986•0 citations
We discuss some recent theoretical as well as experimental advances in collisions involving Rydberg atoms. We recall some basic properties of Rydberg atoms before showing that in most cases a simplified theoretical treatment of Rydberg collisions is possible. On the experimental side, special attention is paid to the opportunity offered by Rydberg states for the study of quasi-resonant processes.
In recent years, Rydberg atoms have been the subject of intense study, becoming the testing ground for several quantum mechanical problems. This book provides a comprehensive description of the physics of Rydberg atoms, highlighting their remarkable properties by reference to their behaviour in a wide range of physical situations. Following an overview of the basic properties of Rydberg atoms, their interactions with electric and magnetic fields are analysed in detail. The collisions of Rydberg atoms with neutral and charged species are described, and the use of multichannel quantum defect theory in the study of Rydberg atomic systems is discussed. Experimental and theoretical research in this extensive field is also reviewed, making the book valuable to both graduate students and established researchers in physics and physical chemistry.
Recent investigations of Rydberg atoms are described in an effort to give a picture of their properties, many of which can be understood from the behaviour of the Coulomb radial functions. The authors begin by a discussion of Coulomb wavefunctions, and progress to a description of the energy level structure. The behaviour of Rydberg atoms in electric fields is discussed to provide an understanding of the phenomenon and to show how electric field ionisation may be used as a tool in a wide variety of experiments. Unique opportunities to study the interaction with black-body radiation and vacuum fluctuations are discussed. A survey of the broad range of Rydberg atom collisions, with ground-state atoms and molecules, charged particles and other Rydberg atoms, is presented to show the different physical interactions responsible. This is followed by a brief summary of the study of autoionising Rydberg states, a stepping stone toward the elusive 'double Rydberg' atom. Finally typical experimental procedures are described.
Charge transfer from high‐n atomic targets populates comparably excited states of ionic projectiles. This paper reviews a decade of accelerating experimental and theoretical progress in the field, which offers an unusual variety of challenges in the preparation of initial states and in the analysis of final states. Interesting dynamical questions at the interface of classical and quantum mechanics are posed by new experimental results. Rydberg atom phenomena are increasingly found to be important for other areas of atomic collision physics in all energy regimes.
Recent experimental and theoretical studies of near-resonant energy transfer collisions involving rare-gas atoms and alkali or alkaline earth atoms which have been initially excited to an aligned state via one or more linearly polarized rasters have yielded a wealth of insight into orbital alignment and related effects. We have extended this inquiry to initially aligned Rydberg states, examining state-to-state and alignment-selected cross sections using quantum collision theory augmented by approximations appropriate to the special characteristics of the Rydberg state (e.g., the quasi-free-electron model and the impulse approximation).
Rydberg states of atoms have intrinsic properties that should allow their use as highly sensitive and tunable detectors at far infrared wavelengths. The intrinsic limit of such atomic detectors are collisional processes. This report describes the results of a research program to better understand an important class of collisions--namely, the resonant collision of two Rydberg atoms. We have extensively measured the linewidths and the collision cross sections and have determined thier dependence on parameters such as the principal quantum number and the Rydberg state angular momentum. The resonant collisions are shown to occur for a wide variety of initial states with cross sections of the order of 10 to the 9th power square-Angstroms and scaling as (n*O to the 4th order).