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Journal of Applied Spectroscopy

The application of the laplace transform to the calculation of the interaction between an atom and the field of a light wave using perturbation theory

A. G. Makhanek, V. S. Korol'kov, Pavel A Apanasevich

Published Nov 1, 1970• 0 citations
Publisher
DOI
10.1007/bf00610551

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A Laplace transform relation between the distribution function $\mathrm{exp}{\ensuremath{-}\ensuremath{\beta}H}$ in quantum statistical mechanics and the Green's function of the wave equation has been noted by Koppe. This relationship may be extended to the stationary-state scattering equation. General properties of the transformation are discussed. Applications to the evaluation of the virial coefficients are considered. A further application of the perturbation methods of Brueckner and his collaborators is described.
In this article, by using the perturbation theory, we analytically solve the eigenvalue problem for the Hamiltonian describing the interaction of a Λ -type three-level atom with a single-mode radiation field without the rotating wave approximation (RWA). For this purpose, the atom–field interaction Hamiltonian, which contains the counter-rotating terms (CRTs), is transformed to an analytically solvable Hamiltonian by applying three successive unitary transformations. According to our calculations, the contribution of CRTs within the transformed Hamiltonian is in fact replaced by transforming the 'constant detuning' with the 'intensity-dependent detuning' in the first order, and the 'constant atom–field coupling' with the intensity-dependent coupling in the second order of the perturbation parameters. Then, by solving the eigenvalue problem for the transformed Hamiltonian, the eigenvector of the considered atom–field Hamiltonian is obtained analytically. Finally, after achieving the state vector of the atom–field system at an arbitrary time, a few nonclassical properties of the system state are investigated numerically. Meanwhile, we compare our results with the presence of RWA, from which the role of CRTs will be established.
A theoretical analysis is made of the interaction of a quantum system characterized by two groups of closely spaced levels with a strong resonant field of a steady-state pump wave and a weak field of a "verifying signal." The strong field is allowed for by the canonical transformation and the weak field by the perturbation theory. The first-order susceptibilities are obtained for the weak field in the form which can be used to study the dependences of the frequencies, intensities, and widths of lines in the scatteredradiation spectrum on the frequency and intensity of the strong wave.