Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physical Review

Transport Phenomena in Einstein-Bose and Fermi-Dirac Gases. I

Edwin A. Uehling, G. E. Uhlenbeck

Published Apr 1, 1933• 673 citations
Publisher

Abstract

The theory of gases in nonstationary states, given by Lorentz and Enskog, is generalized for the quantum statistics to give the hydrodynamical equations and the distribution function in first and second approximation, and formal expressions for the viscosity and heat conductivity coefficients. These results are valid for all statistics and for all degrees of degeneration. Two essential points contribute to this generality: (a) Exact expressions independent of statistics and degeneration can be given for the coordinate and time derivatives of the coefficient $A$ of the equilibrium distribution function in terms of the pressure and temperature gradients and time derivatives, though a closed expression for this coefficient as a function of $v$ and $T$ is known only in limiting cases; (b) The function $W$ of the general equation of state for ideal gases in all statistics $pv=(\frac{\mathrm{RT}}{M})W({v}^{\frac{2}{3}}T)$ is adiabatically invariant. Numerical values of the viscosity and heat conductivity coefficients, which should come out of the formal theory on the introduction of special assumptions about the molecular forces, have not yet been obtained. It is our hope that these results, when found, may furnish an experimental test of the existence of Einstein-Bose statistics in real gases, as is required by theory.

DOI
10.1103/physrev.43.552

Related papers

Transport coefficients and relaxation times

Allan Griffin, Tetsuro Nikuni, E. Zaremba

In Chapter 17, we derived two-fluid hydrodynamic equations that include damping related to transport coefficients. Our entire analysis was based on the coupled ZNG equations for the condensate and in the thermal cloud. These involved a generalized GP equation for the condensate and a kinetic equation for the thermal atoms. A crucial role is played by the C 12 collision term in the kinetic equation, which describes the interactions between atoms in the condensate and in the thermal cloud. Our analysis of the deviation from the diffusive local equilibrium solution of the kinetic equation was based on the Chapman–Enskog approach, extensively developed for classical gases and first applied to Bose-condensed gases by Kirkpatrick and Dorfman (1983, 1985a). This approach required a careful treatment of the novel feature relating to the C 12 collisions both in the kinetic equation describing the thermal atoms and also in the source term Γ 12 in the generalized GP equation for the condensate. Using the Chapman– Enskog approach to solve the kinetic equation for a trapped Bose gas, we obtained explicit expressions for the function ψ( p, r , t ) that describes the deviation from diffusive local equilibrium, as defined by (17.25) and (17.39). This deviation can be related to various transport coefficients, as discussed in Chapter 17. These transport coefficients are determined by the solutions of the three integral equations (17.40)–(17.42) for the three contributions to the deviation function ψ( p, r , t ) in (17.39). In Section 18.1, we will solve these integral equations and obtain explicit expressions for the thermal conductivity k , the shear viscosity η and the four second viscosity coefficients ζ i .

Cambridge University Press eBooks•Feb 19, 2009•0 citations

Transport Phenomena in a Bose-Einstein Gas

William Band

This paper develops the formal first order perturbation theory of transport phenomena in an ideal Bose-Einstein gas.The perturbation relaxation time is an unknown parameter in the theory. The ratio of thermal conductivity to viscosity is independent of this relaxation time; it increases discontinuously by a factor almost 2 at the Bose-Einstein condensation temperature ${T}_{\ensuremath{\lambda}}$. The isothermal Knudsen heat of transport through a small hole, classically equal to $2kT$, drops rapidly to zero as $T$ falls to ${T}_{\ensuremath{\lambda}}$: the Bose-Einstein gas flowing isothermally through a small hole carries no heat when its temperature is below ${T}_{\ensuremath{\lambda}}$ and it exhibits corresponding thermo-mechanical effects.The mathematical analysis is carried out in terms of an approximation in which the lowest energy states of the gas are treated discretely while above an arbitrary level they are treated by an integration approximation. The treatment is capable of generalization to models in which there are anomalies in the lowest level spacings.

Physical Review•Jun 15, 1949•4 citations

Density Expansion of Quantum Transport Coefficients

Jerome Weinstock

A formal density expansion of transport coefficients expressed in terms of momentum autocorrelation functions is derived for a degenerate quantum gas (Bose-Einstein or Fermi-Dirac statistics) at any frequency and for noncentral as well as central forces. The result to lowest order in density is reduced to the solution of a well-defined quantum two-body problem, and the first density correction is reduced to the solution of a well-defined quantum three-body problem. It is confirmed that at zero frequency one only needs the asymptotic forms of the collision operator to calculate quantum transport coefficients. It is further pointed out that the coefficients of the third- and higher order terms of the density expansion diverge at zero frequency, in analogy with the classical case. A "renormalization" is suggested which, it is believed, leads to a nonanalytic density dependence for quantum gases distinct from the nonanalytic behavior associated with degeneracy statistics.

Physical Review•Feb 5, 1967•8 citations

Quantum ideal gases: Fermi-Dirac and Bose-Einstein statistics

Mark E. Tuckerman

Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed

•Aug 1, 2023•0 citations

The Landau–Khalatnikov two-fluid equations

Allan Griffin, Tetsuro Nikuni, E. Zaremba

In Chapter 15, we showed that in the limit of short collision times the coupled equations of motion for the condensate and noncondensate atoms lead to Landau's non-dissipative two-fluid hydrodynamics. However the approach used in Chapter 15 was not based on a small expansion parameter, in contrast with the more systematic Chapman–Enskog procedure used to derive hydrodynamic damping in the kinetic theory of classical gases. In the present chapter, we generalize the procedure of Chapter 15 to trapped Bose-condensed gases, in order to derive two-fluid hydrodynamic equations that include dissipation due to transport processes. We solve the kinetic equation by expanding the nonequilibrium single-particle distribution function f ( p, r , t ) around the distribution function f (0) ( p, r , t ) that describes complete local equilibrium between the condensate and the noncondensate components. All hydrodynamic damping effects are included by taking into account deviations from the local equilibrium distribution function f (0) . Our discussion for a trapped Bose gas is a natural extension of the pioneering work of Kirkpatrick and Dorfman (1983, 1985a) for a uniform Bose-condensed gas. This chapter is mainly based on their work as well as on Nikuni and Griffin (2001a,b). We will prove that, with appropriate definitions of various thermodynamic variables, our two-fluid hydrodynamic equations including damping have precisely the structure of those first derived by Landau and Khalatnikov for superfluid He. In particular, the damping associated with the collisional exchange of atoms between the condensate and noncondensate components, which is discussed at length in Chapter 15, is now expressed in terms of frequency-dependent second viscosity coefficients. This special type of damping is a characteristic signature of a dilute Bose superfluid and exists in addition to the hydrodynamic damping associated with the shear viscosity and thermal conductivity of the normal fluid.

Cambridge University Press eBooks•Feb 19, 2009•0 citations

Kinetic theory of a normal quantum fluid. II. Transport properties

Charles D. Boley, Jeffrey B. Smith

Renormalized expressions for the transport coefficients of a normal quantum fluid are derived from a nonlocal kinetic equation. As was shown in the classical case by Forster and Martin and by R\'esibois, the expressions for the transport coefficients separate naturally into "kinetic" and "direct" parts. The kinetic terms are proportional to matrix elements of the inverse of the kinetic kernel, and have the same general structure as the "bare" transport coefficients obtained from a local Boltzmann equation. The direct terms are proportional to matrix elements of the kernel itself, and have no counterpart in calculations based on a local kinetic equation, as in the kinetic theory of gases. We evaluate the transport coefficients using the weak-coupling approximation to the kernel derived in a previous paper. Results are given, first, for both Bose and Fermi fluids at arbitrary temperature, and then for the Fermi fluid near $T=0$, where complete solutions are obtained. It is found that the direct parts of the shear viscosity and thermal conductivity are of higher order in $T$ than the kinetic parts, and are therefore negligible at very low temperature. The kinetic parts have the same leading temperature dependence as the predictions of the Landau theory. For the bulk viscosity, however, the direct and kinetic contributions begin at the same order (${T}^{2}$) in the temperature.

Physical review. B, Condensed matter•Jun 1, 1978•11 citations
The theory of gases in nonstationary states, given by Lorentz and Enskog, is generalized for the quantum statistics to give the hydrodynamical equations and the distribution function in first and second approximation, and formal expressions for the viscosity and heat conductivity coefficients. These results are valid for all statistics and for all degrees of degeneration. Two essential points contribute to this generality: (a) Exact expressions independent of statistics and degeneration can be given for the coordinate and time derivatives of the coefficient AAA of the equilibrium distribution function in terms of the pressure and temperature gradients and time derivatives, though a closed expression for this coefficient as a function of vvv and TTT is known only in limiting cases; (b) The function WWW of the general equation of state for ideal gases in all statistics pv=(RTM)W(v23T)pv=(\frac{\mathrm{RT}}{M})W({v}^{\frac{2}{3}}T)pv=(MRT​)W(v32​T) is adiabatically invariant. Numerical values of the viscosity and heat conductivity coefficients, which should come out of the formal theory on the introduction of special assumptions about the molecular forces, have not yet been obtained. It is our hope that these results, when found, may furnish an experimental test of the existence of Einstein-Bose statistics in real gases, as is required by theory.
In Chapter 17, we derived two-fluid hydrodynamic equations that include damping related to transport coefficients. Our entire analysis was based on the coupled ZNG equations for the condensate and in the thermal cloud. These involved a generalized GP equation for the condensate and a kinetic equation for the thermal atoms. A crucial role is played by the C 12 collision term in the kinetic equation, which describes the interactions between atoms in the condensate and in the thermal cloud. Our analysis of the deviation from the diffusive local equilibrium solution of the kinetic equation was based on the Chapman–Enskog approach, extensively developed for classical gases and first applied to Bose-condensed gases by Kirkpatrick and Dorfman (1983, 1985a). This approach required a careful treatment of the novel feature relating to the C 12 collisions both in the kinetic equation describing the thermal atoms and also in the source term Γ 12 in the generalized GP equation for the condensate. Using the Chapman– Enskog approach to solve the kinetic equation for a trapped Bose gas, we obtained explicit expressions for the function ψ( p, r , t ) that describes the deviation from diffusive local equilibrium, as defined by (17.25) and (17.39). This deviation can be related to various transport coefficients, as discussed in Chapter 17. These transport coefficients are determined by the solutions of the three integral equations (17.40)–(17.42) for the three contributions to the deviation function ψ( p, r , t ) in (17.39). In Section 18.1, we will solve these integral equations and obtain explicit expressions for the thermal conductivity k , the shear viscosity η and the four second viscosity coefficients ζ i .
This paper develops the formal first order perturbation theory of transport phenomena in an ideal Bose-Einstein gas.The perturbation relaxation time is an unknown parameter in the theory. The ratio of thermal conductivity to viscosity is independent of this relaxation time; it increases discontinuously by a factor almost 2 at the Bose-Einstein condensation temperature ${T}_{\ensuremath{\lambda}}$. The isothermal Knudsen heat of transport through a small hole, classically equal to 2kT2kT2kT, drops rapidly to zero as TTT falls to ${T}_{\ensuremath{\lambda}}$: the Bose-Einstein gas flowing isothermally through a small hole carries no heat when its temperature is below ${T}_{\ensuremath{\lambda}}$ and it exhibits corresponding thermo-mechanical effects.The mathematical analysis is carried out in terms of an approximation in which the lowest energy states of the gas are treated discretely while above an arbitrary level they are treated by an integration approximation. The treatment is capable of generalization to models in which there are anomalies in the lowest level spacings.
A formal density expansion of transport coefficients expressed in terms of momentum autocorrelation functions is derived for a degenerate quantum gas (Bose-Einstein or Fermi-Dirac statistics) at any frequency and for noncentral as well as central forces. The result to lowest order in density is reduced to the solution of a well-defined quantum two-body problem, and the first density correction is reduced to the solution of a well-defined quantum three-body problem. It is confirmed that at zero frequency one only needs the asymptotic forms of the collision operator to calculate quantum transport coefficients. It is further pointed out that the coefficients of the third- and higher order terms of the density expansion diverge at zero frequency, in analogy with the classical case. A "renormalization" is suggested which, it is believed, leads to a nonanalytic density dependence for quantum gases distinct from the nonanalytic behavior associated with degeneracy statistics.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
In Chapter 15, we showed that in the limit of short collision times the coupled equations of motion for the condensate and noncondensate atoms lead to Landau's non-dissipative two-fluid hydrodynamics. However the approach used in Chapter 15 was not based on a small expansion parameter, in contrast with the more systematic Chapman–Enskog procedure used to derive hydrodynamic damping in the kinetic theory of classical gases. In the present chapter, we generalize the procedure of Chapter 15 to trapped Bose-condensed gases, in order to derive two-fluid hydrodynamic equations that include dissipation due to transport processes. We solve the kinetic equation by expanding the nonequilibrium single-particle distribution function f ( p, r , t ) around the distribution function f (0) ( p, r , t ) that describes complete local equilibrium between the condensate and the noncondensate components. All hydrodynamic damping effects are included by taking into account deviations from the local equilibrium distribution function f (0) . Our discussion for a trapped Bose gas is a natural extension of the pioneering work of Kirkpatrick and Dorfman (1983, 1985a) for a uniform Bose-condensed gas. This chapter is mainly based on their work as well as on Nikuni and Griffin (2001a,b). We will prove that, with appropriate definitions of various thermodynamic variables, our two-fluid hydrodynamic equations including damping have precisely the structure of those first derived by Landau and Khalatnikov for superfluid He. In particular, the damping associated with the collisional exchange of atoms between the condensate and noncondensate components, which is discussed at length in Chapter 15, is now expressed in terms of frequency-dependent second viscosity coefficients. This special type of damping is a characteristic signature of a dilute Bose superfluid and exists in addition to the hydrodynamic damping associated with the shear viscosity and thermal conductivity of the normal fluid.
Renormalized expressions for the transport coefficients of a normal quantum fluid are derived from a nonlocal kinetic equation. As was shown in the classical case by Forster and Martin and by R\'esibois, the expressions for the transport coefficients separate naturally into "kinetic" and "direct" parts. The kinetic terms are proportional to matrix elements of the inverse of the kinetic kernel, and have the same general structure as the "bare" transport coefficients obtained from a local Boltzmann equation. The direct terms are proportional to matrix elements of the kernel itself, and have no counterpart in calculations based on a local kinetic equation, as in the kinetic theory of gases. We evaluate the transport coefficients using the weak-coupling approximation to the kernel derived in a previous paper. Results are given, first, for both Bose and Fermi fluids at arbitrary temperature, and then for the Fermi fluid near T=0T=0T=0, where complete solutions are obtained. It is found that the direct parts of the shear viscosity and thermal conductivity are of higher order in TTT than the kinetic parts, and are therefore negligible at very low temperature. The kinetic parts have the same leading temperature dependence as the predictions of the Landau theory. For the bulk viscosity, however, the direct and kinetic contributions begin at the same order (T2{T}^{2}T2) in the temperature.