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Physical review. B, Solid state

Origin of the Pairing Interaction in the Theory of Superconductivity

Leon N. Cooper, Birger Stölan

Published Aug 1, 1971• 7 citations
Publisher

Abstract

A strongly coupled many-body system (a system of fermions confined in a shell surrounding the Fermi surface for which the variation in the single-particle kinetic energy is neglected) is defined. Some general properties of this system are obtained, in particular a criterion for permissible approximations. It is shown that a set of diagrams in which an electron of momentum $\ensuremath{-}\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}$ and of spin \ensuremath{\downarrow} interacts with many electrons of momentum $\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}+\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}}$ and spin \ensuremath{\uparrow}, where $\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}}$ does not grow too large, can be consistently extracted from the totality of graphs generated by this strongly coupled Hamiltonian. When analyzed, these lead to a ground-state and single-particle spectrum displaying the important qualitative features of a BCS superconductor.

DOI
10.1103/physrevb.4.863

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Pairing Fluctuation Effects on the Single-Particle Spectra for the Superconducting State

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Single-particle spectra are calculated in the superconducting state for a fermionic system with an attractive interaction, as functions of temperature and coupling strength from weak to strong. The fermionic system is described by a single-particle self-energy that includes pairing-fluctuation effects in the superconducting state. The theory reduces to the ordinary BCS approximation in weak coupling and to the Bogoliubov approximation for the composite bosons in strong coupling. Several features of the single-particle spectral function are shown to compare favorably with experimental data for cuprate superconductors.

arXiv:cond-mat/0311424•Physical Review Letters•Mar 15, 2004•0 citations

Superconductivity from repulsion: Theoretical constraints

A. S. Alexandrov

Motivation With few exceptions [131] it is widely accepted that the conventional Bardeen–Cooper–Schrieffer (BCS) theory [12] and its intermediate-coupling Eliashberg extension [14] do not suffice to explain high-temperature superconductivity. As shown in the preceding chapters the true origin of high-temperature superconductivity could be found in a proper combination of the bare Coulomb repulsion with the bare electron–phonon interaction in the framework of the many-body polaron theory [51] beyond the BCS–Eliashberg approximation. Nevertheless some researchers have maintained that the repulsive electron–electron interaction alone should provide pairing at high temperatures without phonons despite substantial experimental evidence that the EPI is an important player and needs to be included in the successful theory of high- T c superconductivity. Following the original proposal by P. W. Anderson, many authors [22, 74] argued that the electron–electron interaction in high-temperature superconductors was strong but repulsive providing high T c without phonons via superexchange and/or spin fluctuations in the d -wave pairing channel ( l = 2). A motivation for this concept can be found in the earlier works by Kohn and Luttinger (KL) [132, 133] who showed that the Cooper pairing of fermions with any weak repulsion was possible since the two-particle interaction induced by many-body effects is attractive for pairs with large orbital momenta, l ≫ 1.

Cambridge University Press eBooks•May 2, 2013•0 citations

Applications of the Pairing Theory

J. R. Schrieffer

This chapter reviews the calculation of a number of system properties within the pairing approximation. Since the BCS theory was originally proposed, attempts to justify the pairing correlations basic to the theory have proceeded along two lines. The first approach has been to apply the BCS theory to a wide variety of phenomena in superconductors and check the theoretical predictions of the pairing approximation against experiment. The second approach has been to treat by various approximate methods the residual interactions neglected within the pairing scheme, hoping to show that these residual interactions introduce no major change in the predicted properties of the system. The interaction Hamiltonian, being a one-body operator, can at most change the state of one electron. While the majority of the electron–phonon interaction has been accounted for in forming the wave functions for the normal and superconducting states, there remains the part corresponding to resonant phonon absorption and emission processes.

CRC Press eBooks•Mar 5, 2018•0 citations

Superconductivity in high- Tc and related strongly correlated systems from variational perspective: Beyond mean field theory

Józef Spałek, Maciej Fidrysiak, M. Zegrodnik +1 more

The principal purpose of this topical review is to single out some of the universal features of high-temperature (high-Tc) and related strongly-correlated systems, which can be compared with experiment in a quantitative manner. The description starts with the concept of exchange-interaction-mediated (real-space) pairing, combined with strong correlations among narrow band electrons, for which the reference state is that of the Mott–Hubbard insulator. The physical discussion of concrete properties relies on variational approach, starting from generalized renormalized mean-field theory (RMFT) in the form of statistically-consistent Gutzwiller approximation (SGA), and its subsequent generalization, i.e., a systematic Diagrammatic Expansion of the Variational (Gutzwiller-type) Wave Function (DE-GWF). The solution leads to the two energy scales, one involving unconventional quasiparticles close to the Fermi energy, and the other reflecting the fully correlated state, involving electrons deeper below the Fermi surface. Those two regimes are separated by a kink in the dispersion relation, which is observed in photoemission. As a result, one obtains both the doping dependent properties in the correlated state, and effective renormalized quasiparticles. The reviewed ground-state characteristics for high-Tc systems encompass high-Tc superconductivity, nematicity, charge- (and pair-) density-wave effects, as well as non-BCS kinetic energy gain in the paired state. The calculated dynamic properties are: the universal Fermi velocity, the Fermi wave-vector, the effective mass enhancement, the pseudogap; and the d-wave gap magnitude. We discuss that, within the variational approach, the minimal realistic model is represented by the so-called t-J-U Hamiltonian. Inadequacy of the t-J and Hubbard models, particularly of their RMFT versions, is discussed explicitly. For heavy fermion systems, modeled by the Anderson lattice model and with the DE-GWF approach, we discuss the phase diagram, encompassing superconducting, Kondo insulating, ferro- and anti-ferromagnetic states. The superconducting state is then a two-d-wave gap system. If the orbital degeneracy of f-electrons is included, the coexistent ferromagnetic- (spin–triplet) superconducting phases appear and match those observed for UGe2 in a semiquantitative manner. Finally, in the second part, we generalize our approach to the collective spin and charge fluctuations in high-Tc systems, starting from variational approach, defining the saddle-point state, and combining it with 1/N expansion. The present scheme differs essentially from that starting from the saddle-point Hartree–Fock approximation, and incorporating the fluctuations in the random phase approximation (RPA). The spectrum of collective spin and charge excitations is determined for the Hubbard and t-J-U models, and subsequently compared quantitatively with recent experiments. The Appendices provide formal details to make this review self-contained.

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Bound States and Superfluidity in Strongly Coupled Fermion Systems

GERD RÖPKE

The two-particle spectrum in a dense Fermion system is treated using a thermodynamic Green function approach. A self-consistent description of possible bound states and a superfluid condensate in a correlated medium is given. A detailed understanding of superfluidity and superconductivity in correlated Fermion systems, especially the transition from the Cooper-paired state (weak-coupling limit) to the Bose condensed state of tightly bound pairs of Fermions (strong coupling limit) [1], is of great interest for very different physical systems. The problem of a unified treatment of Bose–Einstein condensation (BEC) and the Bardeen–Cooper–Schrieffer (BCS) phase arises not only in describing the electron structure of strongly correlated electron superfluids such as superconductors [2], the electronhole system in semiconductors [3], spin-polarized hydrogen and liquid He [4], but also in the theory of nuclear matter [5] and quark–gluon systems [6]. Recently, there have been several new approaches to this stimulating problem. A Monte-Carlo simulation of a finite He system at zero temperature has been performed in Ref. [7]. The microscopic theory of strongly coupled quantum fluids has been treated within the Jastrow approximation (cf. Ref. [8]) to obtain the ground state and low-lying excited states of strongly correlated boson quantum fluids. The crossover from weak to strong coupling superconductivity has been considered using a functional integral representation [2] (see also Ref. [7]).

Cambridge University Press eBooks•Apr 6, 1995•1 citation

GENERALIZED COOPER PAIRING IN SUPERCONDUCTORS

MANUEL DE LLANO, James F. Annett

We review Cooper pairing starting from its simplest, original 1956 version of two electrons interacting above the Fermi sea of an ideal Fermi gas (IFG). The two-electron interaction assumed extensively (if not exclusively), is the attractive two-parameter Cooper, and then BCS, model interactions. Hole Cooper pairs (CPs) and electron-hole CPs are then included along with the initial electron-CPs in terms of the single-fermion Green functions implied by the Bethe-Salpeter (BS) integral equation in the ladder approximation. A purely-imaginary CP energy "instability" is recovered that is well-documented in the literature at least since the late 1950's. A novel interpretation of this instability is that an unperturbed Hamiltonian different from the IFG one first used by Cooper suffices to obtain meaningful CPs. Instead of the IFG sea, a BCS-correlated Fermi "sea" used in the BS equation interpreted as the associated unperturbed Hamiltonian leads to real CP energies (with small imaginary terms implying damping). We survey how this has been achieved in 1D, 2D and 3D, and give a more detailed treatment in 2D. A vital distinction is that the original and generalized CPs are true bosons in contrast with BCS pairs that are not ordinary bosons but rather "hard-core bosons" as they do not obey strict Bose commutation rules. Another important common element of the original or generalized CPs (particularly in 2D where ordinary Bose-Einstein condensation (BEC) does not occur) is their linear dispersion relation in leading order in the total (or, center-of-mass) momentum power-series expansion of the CP energy. This theory encompasses, in principle, all empirically known superconductors including quasi-2D superconductors such as cuprates and the ET organic compounds, as well as quasi-1D ones such as the organometallic Bechgaard salts and nanotubes.

International Journal of Modern Physics B•Aug 20, 2007•19 citations
A strongly coupled many-body system (a system of fermions confined in a shell surrounding the Fermi surface for which the variation in the single-particle kinetic energy is neglected) is defined. Some general properties of this system are obtained, in particular a criterion for permissible approximations. It is shown that a set of diagrams in which an electron of momentum \ensuremath−k\ensuremath→\ensuremath{-}\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}\ensuremath−k\ensuremath→​ and of spin \ensuremath{\downarrow} interacts with many electrons of momentum k\ensuremath→+q\ensuremath→\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}+\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}}k\ensuremath→​+q\ensuremath→​ and spin \ensuremath{\uparrow}, where q\ensuremath→\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}}q\ensuremath→​ does not grow too large, can be consistently extracted from the totality of graphs generated by this strongly coupled Hamiltonian. When analyzed, these lead to a ground-state and single-particle spectrum displaying the important qualitative features of a BCS superconductor.
Single-particle spectra are calculated in the superconducting state for a fermionic system with an attractive interaction, as functions of temperature and coupling strength from weak to strong. The fermionic system is described by a single-particle self-energy that includes pairing-fluctuation effects in the superconducting state. The theory reduces to the ordinary BCS approximation in weak coupling and to the Bogoliubov approximation for the composite bosons in strong coupling. Several features of the single-particle spectral function are shown to compare favorably with experimental data for cuprate superconductors.
Motivation With few exceptions [131] it is widely accepted that the conventional Bardeen–Cooper–Schrieffer (BCS) theory [12] and its intermediate-coupling Eliashberg extension [14] do not suffice to explain high-temperature superconductivity. As shown in the preceding chapters the true origin of high-temperature superconductivity could be found in a proper combination of the bare Coulomb repulsion with the bare electron–phonon interaction in the framework of the many-body polaron theory [51] beyond the BCS–Eliashberg approximation. Nevertheless some researchers have maintained that the repulsive electron–electron interaction alone should provide pairing at high temperatures without phonons despite substantial experimental evidence that the EPI is an important player and needs to be included in the successful theory of high- T c superconductivity. Following the original proposal by P. W. Anderson, many authors [22, 74] argued that the electron–electron interaction in high-temperature superconductors was strong but repulsive providing high T c without phonons via superexchange and/or spin fluctuations in the d -wave pairing channel ( l = 2). A motivation for this concept can be found in the earlier works by Kohn and Luttinger (KL) [132, 133] who showed that the Cooper pairing of fermions with any weak repulsion was possible since the two-particle interaction induced by many-body effects is attractive for pairs with large orbital momenta, l ≫ 1.
This chapter reviews the calculation of a number of system properties within the pairing approximation. Since the BCS theory was originally proposed, attempts to justify the pairing correlations basic to the theory have proceeded along two lines. The first approach has been to apply the BCS theory to a wide variety of phenomena in superconductors and check the theoretical predictions of the pairing approximation against experiment. The second approach has been to treat by various approximate methods the residual interactions neglected within the pairing scheme, hoping to show that these residual interactions introduce no major change in the predicted properties of the system. The interaction Hamiltonian, being a one-body operator, can at most change the state of one electron. While the majority of the electron–phonon interaction has been accounted for in forming the wave functions for the normal and superconducting states, there remains the part corresponding to resonant phonon absorption and emission processes.
The principal purpose of this topical review is to single out some of the universal features of high-temperature (high-Tc) and related strongly-correlated systems, which can be compared with experiment in a quantitative manner. The description starts with the concept of exchange-interaction-mediated (real-space) pairing, combined with strong correlations among narrow band electrons, for which the reference state is that of the Mott–Hubbard insulator. The physical discussion of concrete properties relies on variational approach, starting from generalized renormalized mean-field theory (RMFT) in the form of statistically-consistent Gutzwiller approximation (SGA), and its subsequent generalization, i.e., a systematic Diagrammatic Expansion of the Variational (Gutzwiller-type) Wave Function (DE-GWF). The solution leads to the two energy scales, one involving unconventional quasiparticles close to the Fermi energy, and the other reflecting the fully correlated state, involving electrons deeper below the Fermi surface. Those two regimes are separated by a kink in the dispersion relation, which is observed in photoemission. As a result, one obtains both the doping dependent properties in the correlated state, and effective renormalized quasiparticles. The reviewed ground-state characteristics for high-Tc systems encompass high-Tc superconductivity, nematicity, charge- (and pair-) density-wave effects, as well as non-BCS kinetic energy gain in the paired state. The calculated dynamic properties are: the universal Fermi velocity, the Fermi wave-vector, the effective mass enhancement, the pseudogap; and the d-wave gap magnitude. We discuss that, within the variational approach, the minimal realistic model is represented by the so-called t-J-U Hamiltonian. Inadequacy of the t-J and Hubbard models, particularly of their RMFT versions, is discussed explicitly. For heavy fermion systems, modeled by the Anderson lattice model and with the DE-GWF approach, we discuss the phase diagram, encompassing superconducting, Kondo insulating, ferro- and anti-ferromagnetic states. The superconducting state is then a two-d-wave gap system. If the orbital degeneracy of f-electrons is included, the coexistent ferromagnetic- (spin–triplet) superconducting phases appear and match those observed for UGe2 in a semiquantitative manner. Finally, in the second part, we generalize our approach to the collective spin and charge fluctuations in high-Tc systems, starting from variational approach, defining the saddle-point state, and combining it with 1/N expansion. The present scheme differs essentially from that starting from the saddle-point Hartree–Fock approximation, and incorporating the fluctuations in the random phase approximation (RPA). The spectrum of collective spin and charge excitations is determined for the Hubbard and t-J-U models, and subsequently compared quantitatively with recent experiments. The Appendices provide formal details to make this review self-contained.
The two-particle spectrum in a dense Fermion system is treated using a thermodynamic Green function approach. A self-consistent description of possible bound states and a superfluid condensate in a correlated medium is given. A detailed understanding of superfluidity and superconductivity in correlated Fermion systems, especially the transition from the Cooper-paired state (weak-coupling limit) to the Bose condensed state of tightly bound pairs of Fermions (strong coupling limit) [1], is of great interest for very different physical systems. The problem of a unified treatment of Bose–Einstein condensation (BEC) and the Bardeen–Cooper–Schrieffer (BCS) phase arises not only in describing the electron structure of strongly correlated electron superfluids such as superconductors [2], the electronhole system in semiconductors [3], spin-polarized hydrogen and liquid He [4], but also in the theory of nuclear matter [5] and quark–gluon systems [6]. Recently, there have been several new approaches to this stimulating problem. A Monte-Carlo simulation of a finite He system at zero temperature has been performed in Ref. [7]. The microscopic theory of strongly coupled quantum fluids has been treated within the Jastrow approximation (cf. Ref. [8]) to obtain the ground state and low-lying excited states of strongly correlated boson quantum fluids. The crossover from weak to strong coupling superconductivity has been considered using a functional integral representation [2] (see also Ref. [7]).
We review Cooper pairing starting from its simplest, original 1956 version of two electrons interacting above the Fermi sea of an ideal Fermi gas (IFG). The two-electron interaction assumed extensively (if not exclusively), is the attractive two-parameter Cooper, and then BCS, model interactions. Hole Cooper pairs (CPs) and electron-hole CPs are then included along with the initial electron-CPs in terms of the single-fermion Green functions implied by the Bethe-Salpeter (BS) integral equation in the ladder approximation. A purely-imaginary CP energy "instability" is recovered that is well-documented in the literature at least since the late 1950's. A novel interpretation of this instability is that an unperturbed Hamiltonian different from the IFG one first used by Cooper suffices to obtain meaningful CPs. Instead of the IFG sea, a BCS-correlated Fermi "sea" used in the BS equation interpreted as the associated unperturbed Hamiltonian leads to real CP energies (with small imaginary terms implying damping). We survey how this has been achieved in 1D, 2D and 3D, and give a more detailed treatment in 2D. A vital distinction is that the original and generalized CPs are true bosons in contrast with BCS pairs that are not ordinary bosons but rather "hard-core bosons" as they do not obey strict Bose commutation rules. Another important common element of the original or generalized CPs (particularly in 2D where ordinary Bose-Einstein condensation (BEC) does not occur) is their linear dispersion relation in leading order in the total (or, center-of-mass) momentum power-series expansion of the CP energy. This theory encompasses, in principle, all empirically known superconductors including quasi-2D superconductors such as cuprates and the ET organic compounds, as well as quasi-1D ones such as the organometallic Bechgaard salts and nanotubes.