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Journal of Modern Physics

Bohr’s Spectrum of Quantum States in the Atomic Hydrogen Deduced from the Uncertainty Principle for Energy and Time

Stanisław Olszewski

Published Jan 1, 2014• 6 citations
Publisher

Abstract

A modified uncertainty principle coupling the intervals of energy and time can lead to the shortest distance attained in course of the excitation process, as well as the shortest possible time interval for that process. These lower bounds are much similar to the interval limits deduced on both the experimental and theoretical footing in the era when the Heisenberg uncertainty principle has been developed. In effect of the bounds existence, a maximal nuclear charge Ze acceptable for the Bohr atomic ion could be calculated. In the next step the velocity of electron transitions between the Bohr orbits is found to be close to the speed of light. This result provides us with the energy spectrum of transitions similar to that obtained in the Bohr’s model. A momentary force acting on the electrons in course of their transitions is estimated to be by many orders larger than a steady electrostatic force existent between the atomic electron and the nucleus.

DOI
10.4236/jmp.2014.514127

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A modified uncertainty principle coupling the intervals of energy and time can lead to the shortest distance attained in course of the excitation process, as well as the shortest possible time interval for that process. These lower bounds are much similar to the interval limits deduced on both the experimental and theoretical footing in the era when the Heisenberg uncertainty principle has been developed. In effect of the bounds existence, a maximal nuclear charge Ze acceptable for the Bohr atomic ion could be calculated. In the next step the velocity of electron transitions between the Bohr orbits is found to be close to the speed of light. This result provides us with the energy spectrum of transitions similar to that obtained in the Bohr’s model. A momentary force acting on the electrons in course of their transitions is estimated to be by many orders larger than a steady electrostatic force existent between the atomic electron and the nucleus.
Definitions of the mechanical parameters entering the Bohr model of the hydrogen atom allowed us to calculate the time intervals connected with the electron transitions between the nearest-neighbouring energy levels in the atom. This is done in a strictly non-probabilistic way. The time results are compared with those derived earlier on the basis of the classical Joule-Lenz law for the energy emission adapted to the case of the electron transfer in the quantum systems. A similar formalism has been next applied to the harmonic oscillator and a particle moving in the one-dimensional potential box.
The results of Bohr model can be used to explain the motion of macroscopic objects or big objects (like orbiting planets and sun, falling stone etc.). These macroscopic objects have essentially a particle nature and Newtonian laws of motion can be applied on them. But it fails when applied to explain the motion of microscopic objects or small objects (like electrons, atoms, molecules etc.). This is because: According to Bohr model, an orbit is a well-defined path and this path can completely be defined only if both the position and velocity of the electron are known exactly at the same time. But this is not possible according to the Heisenberg’s uncertainty principle. Thus, Bohr model contradicts the Heisenberg’s uncertainty principle . According to Bohr model, an electron is regarded as a charged particle moving in well-defined circular orbits concentric about the nucleus. The wave character of the electron is not considered. Thus, Bohr model ignores the de-Broglie dual nature of matter .
The results of Bohr model can be used to explain the motion of macroscopic objects or big objects (like orbiting planets and sun, falling stone etc.). These macroscopic objects have essentially a particle nature and Newtonian laws of motion can be applied on them. But it fails when applied to explain the motion of microscopic objects or small objects (like electrons, atoms, molecules etc.). This is because: According to Bohr model, an orbit is a well-defined path and this path can completely be defined only if both the position and velocity of the electron are known exactly at the same time. But this is not possible according to the Heisenberg’s uncertainty principle. Thus, Bohr model contradicts the Heisenberg’s uncertainty principle . According to Bohr model, an electron is regarded as a charged particle moving in well-defined circular orbits concentric about the nucleus. The wave character of the electron is not considered. Thus, Bohr model ignores the de-Broglie dual nature of matter .
The atom model of Niels Bohr is commonly considered as antiquated even if it describes the atomic spectrum of hydrogen quite accurately. The later published relation of Louis De Broglie could arithmetically be implemented into Bohr’s formulation, leading to the concept of standing waves as the existence cause of excited electron states. However, at that time it was not possible to find well defined electron trajectories being classically describable. As a consequence, the »quantum mechanics« were developed by several authors, particularly by Schrodinger and by Heisenberg, but delivering a hardly under¬standable formalism where the classical physical laws appear being abrogated while abstract terms replace concrete and imaginable ones, abandoning the particle perception of mass points. In particular, Heisenberg’s »uncertainty principle« and the assumption of state probabilities seem to be in a striking variance to the idea of standing waves. In contrast, a formulation is given here which exactly describes the electron trajectories in the exited states solely by applying classical physical laws. Firstly, the original Bohr-model - in combination with De Broglie’s relation - is rolled up. From this formula system a vibration frequency - corresponding to the De-Broglie frequency – is deduced which is n-times larger than the rotation frequency of the Bohr-model. Furthermore, a direct coherence between that vibration-frequency of the electron and the frequency of the involved light is evident being explainable as a resonance effect. Then, a three-dimensional model is proposed where the electron oscillates and pulses perpendicularly to a virtual rotation plane i.e. rotating around a vertical axis, accompanied by a perpetual energy exchange between potential and kinetic energy. This leads at the excited, metastable energy states to well-defined, three-dimensional and wavy trajectories winding up on a surface similar to the one of a hyperboloid, whereas at the ground state the trajectory is planar and stable.
This chapter has provided an alternate method of solving simple problems in atomic physics under Bohr’s model to aid good mental picture of hydrogen atom to scientists. Two values of fundamental physical properties of an electron in the hydrogen atom has been identified. By limiting the orbiting electrons to a series of circular orbits having discrete radii, Bohr could account for the series of discrete wavelengths in the emission spectrum of hydrogen. Light, he proposed, radiated from hydrogen atoms only when an electron made a transition from an outer orbit to one closer to the nucleus. These physical properties (Ve = 174090.938ms-1& Pe = 1.585860888 × 10-25kgms-1) are constant in nature. The aim for the review was to contribute to the solution of disagreement between the Bohr’s wavelength (λ\lambdaλ0 = 91.12nm) and the Balmer’s experimental observation (λ\lambdaλ0 = 91.18nm) for the emission spectrum of hydrogen atom. There are two other constants δ\deltaδ = 7.199822 × 10-10 eVm and ζ\zetaζ = 1503796277m-1 that were identified in the Bohr’s equation of the hydrogen atom. The four fundamental physical constants can be applied to multi-electron systems because they are inherent characteristics of an electron. They can also be derived from the steady state hydrogen atom Schrodinger's equation. For a deeper understanding, these constants may be scrutinised for their determination. The study recommends that current quantum atomic models and equations governing quantum physics should be revisited for better applications and understanding of the physical world.
In 1913, Niels Bohr developed an accurate model for the hydrogen atom. The mathematics involved and the simplicity of this model is easily understood. The intention of the paper is not to replace Bohr's model, but to find a similar model for all atoms. The model discussed, which was developed on the same basis as Bohr's model for the hydrogen atom, calculates the radii and the energies of the orbits. The wavelength of an emitted photon when an electron makes a ‘jump’ from a higher state to a lower state can also be calculated from the model. Finally, the paper demonstrates that the model obeys the de Broglie's hypothesis that the moving electron exhibits both wave and particle properties.