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American Journal of Physics

Constructing Green functions of the Schrödinger equation by elementary transformations

Gin-yih Tsaur, Jyhpyng Wang

Published Jul 1, 2006• 11 citations
Publisher

Abstract

The initial value problem in quantum mechanics is most conveniently solved by the Green function method. Instead of the conventional methods of eigenfunction expansion and path integration, we present a new method for constructing the Green functions systematically. By using suitable elementary transformations, one of the conjugate variables in the Hamiltonian can be eliminated and the Green function for the simplified Hamiltonian can be easily derived. We then obtain the Green function for the original Hamiltonian by the reverse sequence of the elementary transformations. The method is illustrated for the linear potential, the harmonic oscillator, the centrifugal potential, and the centripetal barrier oscillator.

DOI
10.1119/1.2186688

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The initial value problem in quantum mechanics is most conveniently solved by the Green function method. Instead of the conventional methods of eigenfunction expansion and path integration, we present a new method for constructing the Green functions systematically. By using suitable elementary transformations, one of the conjugate variables in the Hamiltonian can be eliminated and the Green function for the simplified Hamiltonian can be easily derived. We then obtain the Green function for the original Hamiltonian by the reverse sequence of the elementary transformations. The method is illustrated for the linear potential, the harmonic oscillator, the centrifugal potential, and the centripetal barrier oscillator.
Abstract The Green function method is a powerful technique for solving the initial value problem in quantum mechanics. Once the Green function is solved the whole wavefunction evolution is represented in a concise form and can be evaluated conveniently by numerical integration. We present a method for constructing the Green functions systematically which is different from the conventional methods of eigenfunction expansion or path integration. By using variable changing, function substitution, and Fourier transforms, the time dependent Schrödinger equations can be simplified and the solutions for the simplified equations can be easily derived. We then obtain the Green functions for the original equations by the reverse transforms. The method is demonstrated for the linear potential, the harmonic oscillator, the centrifugal potential, and the centripetal barrier oscillator, where the Green function for the centripetal barrier oscillator has not been solved previously by conventional methods. The method and examples illustrated in this paper can be utilised to strengthen undergraduate courses on quantum mechanics and/or partial differential equation.
Owing to the operator nature of the quantum dynamical variables, classical canonical transformations for integrating the equations of motion cannot be extended to the quantum domain. In this paper, a general procedure is developed to construct the sequences of quantum canonical transformations for integrating the Schr\"odinger equations. The sequence is made of three elementary canonical transformations that constitute a much larger class than the unitary transformations. In conjunction with the procedure, we also developed a factorization technique that is analogous to the method of integration factor in classical integration. For demonstration, with the same procedure we integrate nine nontrivial models, including the centripetal barrier potential, the Kratzer's molecular potential, the Morse potential, the P\"oschl-Teller potential, the Hulth\'en potential, etc.
A new approach to finding the exact Green's function to the time-dependent Schr\"odinger equation is described. The approach is conceptually simple: one seeks an operator which when commuted through the Schr\"odinger operator transforms it into the Schr\"odinger operator of a soluble problem. This approach provides an alternative to both the eigenfunction expansion of the propagator and the path integral. The first example of an exact propagator represented as a ``sum over classical paths'' which is not equal to the Gaussian approximation of the path integral is found.
A direct procedure for determining the propagator associated with a quantum mechanical problem was given by the Path Integration Procedure of Feynman.The Green function, which is the Fourier Transform with respect to the time variable of the propagator, can be derived later.In our approach, with the help of a Laplace transform, a direct way to get the energy dependent Green function is presented, and the propagator can be obtained later with an inverse Laplace transform.The method is illustrated through simple one dimensional examples and for time independent potentials, though it can be generalized to the derivation of more complicated propagators.
Operator algebra techniques are employed to derive the quantum evolution operator for the harmonic oscillator. The derivation begins with the construction of the annihilation and creation operators and the determination of the wave function for the coherent state as well as its time-dependent evolution, and ends with the transformation of the propagator in a mixed position-coherent-state representation to the desired one in configuration space. Throughout the entire procedure, besides elementary operator manipulations, it is only necessary to solve linear differential equations and to calculate Gaussian integrals.