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Nature

Light Quanta and Photo-electric Emission

Charles Glover Barkla

Published Mar 27, 1926• 2 citations
Publisher
DOI
10.1038/117448a0

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LIGHT QUANTA; DE BROGLIE WAVES; DIFFRACTION OF LIGHT QUANTA; THE COMPTON EFFECT

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Light quanta The history of the corpuscular and wave controversy in optical theory is well known. At the end of the last century physicists had no doubt as to the wave character of light, and the acceptance of the wave theory meant the rejection of the corpuscular theory. The possibility of both being correct and helpful to one another had not been much thought about and still less explored. At about this time Planck's quantum theory appeared and was soon followed in 1905 by Einstein's theory of ‘light quanta’ to explain the photo-electric effect, for which the wave theory alone had utterly failed to account. Einstein assumed that radiation exists in discrete ‘quanta’ of energy hν , where ν is the frequency; thus a quantum is a separate thing, like a corpuscle, and has a frequency associated with it, like a wave. There was a blend of the two older theories involved. This idea has been generalised by the speculations of Louis de Broglie, who pointed out the important clue given by the theory of relativity, namely, that of the identity of mass and energy, so that the conservation of mass is therefore also the conservation of energy. This suggested to him that all forms of energy (including radiation) should have an atomic structure, like matter; and that the atoms of energy are grouped round certain singular points, forming electrons, light quanta, and the like.

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Quantification of Einstein's concept of the photon experimentally confirmed by the photo-electric effect

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Einstein explained the experimental characteristics of the photo-electric effect by the concept that the photon is a localized packet of electromagnetic radiation with the mechanism: photon + atom → emitted electron. A classical plane wave theory of light concluding that the photoelectric effect can be explained without localized photons is reexamined and found to have been flawed in predicting no time delay for photoelectron emission; this accords with Millikan's conclusion (based upon energy conservation) that a classical plane wave would entail a delay prior to emission of the order of hours. The quantification of Einstein's localized packet concept as a solitary wave one wavelength in length (one period long in time) predicts a delay of one period of the photon's oscillating field, which accords with the experimentally measured response time being a few femtoseconds.

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE•Sep 28, 2005•2 citations
Light quanta The history of the corpuscular and wave controversy in optical theory is well known. At the end of the last century physicists had no doubt as to the wave character of light, and the acceptance of the wave theory meant the rejection of the corpuscular theory. The possibility of both being correct and helpful to one another had not been much thought about and still less explored. At about this time Planck's quantum theory appeared and was soon followed in 1905 by Einstein's theory of ‘light quanta’ to explain the photo-electric effect, for which the wave theory alone had utterly failed to account. Einstein assumed that radiation exists in discrete ‘quanta’ of energy hν , where ν is the frequency; thus a quantum is a separate thing, like a corpuscle, and has a frequency associated with it, like a wave. There was a blend of the two older theories involved. This idea has been generalised by the speculations of Louis de Broglie, who pointed out the important clue given by the theory of relativity, namely, that of the identity of mass and energy, so that the conservation of mass is therefore also the conservation of energy. This suggested to him that all forms of energy (including radiation) should have an atomic structure, like matter; and that the atoms of energy are grouped round certain singular points, forming electrons, light quanta, and the like.
Einstein explained the experimental characteristics of the photo-electric effect by the concept that the photon is a localized packet of electromagnetic radiation with the mechanism: photon + atom → emitted electron. A classical plane wave theory of light concluding that the photoelectric effect can be explained without localized photons is reexamined and found to have been flawed in predicting no time delay for photoelectron emission; this accords with Millikan's conclusion (based upon energy conservation) that a classical plane wave would entail a delay prior to emission of the order of hours. The quantification of Einstein's localized packet concept as a solitary wave one wavelength in length (one period long in time) predicts a delay of one period of the photon's oscillating field, which accords with the experimentally measured response time being a few femtoseconds.