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Journal of Mathematical Chemistry

Probabilistic evolution approach to the expectation value dynamics of quantum mechanical operators, part I: integral representation of Kronecker power series and multivariate Hausdorff moment problems

Muzaffer Ayvaz, Metin Demіralp

Published Jun 10, 2014• 5 citations
Publisher
DOI
10.1007/s10910-014-0371-8

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The problem of expanding a density operator $\ensuremath{\rho}$ in forms that simplify the evaluation of important classes of quantum-mechanical expectation values is studied. The weight function $P(\ensuremath{\alpha})$ of the PPP representation, the Wigner distribution $W(\ensuremath{\alpha})$, and the function $〈\ensuremath{\alpha}|\ensuremath{\rho}|\ensuremath{\alpha}〉$, where $|\ensuremath{\alpha}〉$ is a coherent state, are discussed from a unified point of view. Each of these quasiprobability distributions is examined as the expectation value of a Hermitian operator, as the weight function of an integral representation for the density operator and as the function associated with the density operator by one of the operator-function correspondences defined in the preceding paper. The weight function $P(\ensuremath{\alpha})$ of the PPP representation is shown to be the expectation value of a Hermitian operator all of whose eigenvalues are infinite. The existence of the function $P(\ensuremath{\alpha})$ as an infinitely differentiable function is found to be equivalent to the existence of a well-defined antinormally ordered series expansion for the density operator in powers of the annihilation and creation operators aaa and ${a}^{\ifmmode\dagger\else\textdagger\fi{}}$. The Wigner distribution $W(\ensuremath{\alpha})$ is shown to be a continuous, uniformly bounded, square-integrable weight function for an integral expansion of the density operator and to be the function associated with the symmetrically ordered power-series expansion of the density operator. The function $〈\ensuremath{\alpha}|\ensuremath{\rho}|\ensuremath{\alpha}〉$, which is infinitely differentiable, corresponds to the normally ordered form of the density operator. Its use as a weight function in an integral expansion of the density operator is shown to involve singularities that are closely related to those which occur in the PPP representation. A parametrized integral expansion of the density operator is introduced in which the weight function $W(\ensuremath{\alpha},s)$ may be identified with the weight function $P(\ensuremath{\alpha})$ of the PPP representation, with the Wigner distribution $W(\ensuremath{\alpha})$, and with the function $〈\ensuremath{\alpha}|\ensuremath{\rho}|\ensuremath{\alpha}〉$ when the order parameter sss assumes the values $s=+1, 0, \ensuremath{-}1$, respectively. The function $W(\ensuremath{\alpha},s)$ is shown to be the expectation value of the ordered operator analog of the $\ensuremath{\delta}$ function defined in the preceding paper. This operator is in the trace class for Res<0\mathrm{Res}<0Res<0, has bounded eigenvalues for Res=0\mathrm{Res}=0Res=0, and has infinite eigenvalues for s=1s=1s=1. Marked changes in the properties of the quasiprobability distribution $W(\ensuremath{\alpha},s)$ are exhibited as the order parameter sss is varied continuously from $s=\ensuremath{-}1$, corresponding to the function $〈\ensuremath{\alpha}|\ensuremath{\rho}|\ensuremath{\alpha}〉$, to s=+1s=+1s=+1, corresponding to the function $P(\ensuremath{\alpha})$. Methods for constructing these functions and for using them to compute expectation values are presented and illustrated with several examples. One of these examples leads to a physical characterization of the density operators for which the PPP representation is appropriate.
This paper proposes an approach to interpreting quantum expectation values that may help address the quantum measurement problem. Quantum expectation values are usually calculated via Hilbert space inner products and, thereby, differently from expectation values in classical mechanics, which are weighted phase-space integrals. It is shown that, by using Anti-Wick quantization to associate dynamical variables with self-adjoint linear operators, quantum expectation values can be interpreted as genuine weighted averages over phase space, paralleling their classical counterparts. This interpretation arises naturally in the Segal-Bargmann space, where creation and annihilation operators act as simple multiplication and differentiation operators. In this setting, the Husimi Q-function - the coherent-state representation of the quantum state - can be seen as a true probability density in phase space. Unlike Bohmian mechanics, the present approach retains the standard correspondence between dynamical variables and self-adjoint operators while paving the way for a classical-like probabilistic interpretation of quantum statistics.
This paper is about the Quantum Evolver Dynamics which is based  on the Poisson Bracket algebra over the basic quantum operators for a univariate system whose potential function is analytic or  at most having polar singularity with a finite multiplicity in  the position operator. Paper is devoted to the formulation of  the evolver (temporally varying operator describing the evolution of a given operator) dynamics. The basic aim is to expand any given evolver to a fluctuation expansion with respect to the fluctuation in the Hamiltonian of the system. We reveal the relation of this (energetic) fluctuation expansion coefficient operators with the probabilistic evolution theoretical telescopic Kronecker power series which have been quite recently extended pretty much, for the isolated systems. Paper does not contain any illustration because of the concreteness in what we have developed here.