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Journal of Applied Spectroscopy

Energy transfer in strong incoherent interactions

A. S. Agabekyan

Published Apr 1, 1981• 1 citation
Publisher
DOI
10.1007/bf00614235

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The rate of energy transfer in donor-acceptor systems can be manipulated via the common interaction with the confined electromagnetic modes of a micro-cavity. We analyze the competition between the near-field short range dipole-dipole energy exchange processes and the cavity mediated long-range interactions in a simplified model consisting of effective two-level quantum emitters that could be relevant for molecules in experiments under cryogenic conditions. We find that free-space collective incoherent interactions, typically associated with sub-and superradiance, can modify the traditional resonant energy transfer scaling with distance. The same holds true for cavity-mediated collective incoherent interactions in a weak-coupling but strong-cooperativity regime. In the strong coupling regime, we elucidate the effect of pumping into cavity polaritons and analytically identify an optimal energy flow regime characterized by equal donor/acceptor Hopfield coefficients in the middle polariton. Finally we quantify the build-up of quantum correlations in the donor-acceptor system via the two-qubit concurrence as a measure of entanglement.
The rate of energy transfer in donor-acceptor systems can be manipulated via the common interaction with the confined electromagnetic modes of a micro-cavity. We analyze the competition between the near-field short range dipole-dipole energy exchange processes and the cavity mediated long-range interactions in a simplified model consisting of effective two-level quantum emitters that could be relevant for molecules in experiments under cryogenic conditions. We find that free-space collective incoherent interactions, typically associated with sub- and superradiance, can modify the traditional resonant energy transfer scaling with distance. The same holds true for cavity-mediated collective incoherent interactions in a weak-coupling but strong-cooperativity regime. In the strong coupling regime, we elucidate the effect of pumping into cavity polaritons and analytically identify an optimal energy flow regime characterized by equal donor/acceptor Hopfield coefficients in the middle polariton. Finally we quantify the build-up of quantum correlations in the donor-acceptor system via the two-qubit concurrence as a measure of entanglement.
Recently the properties of one-dimensional (1D) strongly interacting, very low-density electrons in the spin-incoherent regime have been under intense study. For sufficiently low densities the potential energy dominates the kinetic energy, making the electrons form a Wigner crystal with an exponentially small spin exchange energy. One can then easily reach the spin-incoherent regime where\nthe exchange energy is much smaller than the temperature. The physics of the spin-incoherent regime has been addressed using Bethe's Ansatz and a bosonized path integral approach, revealing that the spin incoherence dramatically influences the correlations of charge excitations. We here introduce a bosonization scheme for strongly interacting electrons, allowing us to generalize the description to account for the presence of a boundary. By calculating the exact single-electron Green's function we find that the charge sector power-law scaling is highly sensitive to the bound-\nary, strongly modifying the tunneling of electrons close to it. Our approach also allows for a detailed description of the crossover between boundary and bulk regimes.