SF6 photon echo polarization

W. M. Gutman, C. V. Heer

J. Meckley, C. V. Heer

L. S. Vasilenko, Н. Н. Рубцова, Хворостов Евгений Борисович

Stimulated photon echo technique with specially chosen linear polarizations of pumping pulses of exciting radiation is applied to investigation of depolarizing collisions in molecular gas SF6 and its mixtures with buffer gases He and Xe. For the first time, the collisional decay rates of population, orientation and alignment of SF6 levels are determined simultaneously. Translational velocity dependence of orientation and alignment collisional decay rates was under investigation. This velocity dependence proved to be negligible within the frames of experimental accuracy both in pure SF6 and in mixtures, which is in agreement with standard theoretical approach accepted for depolarizing collisions. Decay rates of orientation and alignment in pure SF6 have proved lower than velocity changing (elastic) collisions relaxation rate, which allows to conclude, that only some part of elastic collisions participates in destruction of multipole polarization moments of resonant levels. The evidence is obtained for j-dependence of multipole moments relaxation rates SF6.

Osama M. Raisuddin, Suvranu De

Н. Н. Рубцова, L. S. Vasilenko, Хворостов Евгений Борисович

Collisional relaxation in SF6 gas and its mixtures with He and Xe is studied by photon echo and stimulated photon echo methods from the standpoint of the possibility of identifying the contributions of different types of collisions. The nonexponential nature of the kinetic curve of the photon echo is clearly observed for pure SF6, it is weaker in the mixture SF6+Xe, and it is virtually completely absent for high degrees of dilution of SF6 with helium. These features can be explained on the basis of estimates, made from experimental data, of the critical delay between the exciting pulses (for which the nonexponential behavior should be most strongly manifested). In pure SF6 it is possible to distinguish the contribution of the inelastic channel (rotational relaxation) and the contribution of weak collisions. To distinguish successfully the relaxation channels in mixtures with buffer gases a heavier buffer gas and a much better time resolution must be used. It is shown that data obtained on the orientation and alignment relaxation rates by the stimulated photon echo method can serve as an upper limit for the rates of inelastic processes which cannot be measured by the photon echo method. The combined use of photon echo and stimulated photon echo methods made it possible to obtain data on the cross sections for elastic and inelastic scattering of the collisional pairs SF6–SF6, SF6–Xe, and SF6–He.

C. V. Heer, Ronald H. Kohl