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Journal of Physics B Atomic Molecular and Optical Physics

Scattering by a time-dependent target

R. Lefèbvre, Osman Atabek

Published Jun 15, 2005• 8 citations
Publisher

Abstract

The scattering of a particle by a target with periodic time dependence is usually formulated in Floquet extended space. This leads to time-independent transition probabilities which correspond to the scattering of wave packets that are close to being monoenergetic. Because of the wide space extension of such packets, many oscillations take place during the time particle and target interact. The purpose of this study consists in showing that the scattering amplitudes can also be used to describe the way the particle feels the instantaneous configuration of the target at the time of the collision. The application is made to an oscillating barrier in one dimension. Several tests of the formalism validate the analysis, by changing either the initial position of the wave packet, or the phase of the particle–target interaction. Two equivalent necessary conditions can be formulated to recover the results of standard scattering theory. One is that no energies differing by at least one quantum are present in the energy range effectively covered by the initial wave packet. The other is that there is appreciable self-overlapping of the wave packet after one period of oscillation.

DOI
10.1088/0953-4075/38/13/007

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The scattering of a particle by a target with periodic time dependence is usually formulated in Floquet extended space. This leads to time-independent transition probabilities which correspond to the scattering of wave packets that are close to being monoenergetic. Because of the wide space extension of such packets, many oscillations take place during the time particle and target interact. The purpose of this study consists in showing that the scattering amplitudes can also be used to describe the way the particle feels the instantaneous configuration of the target at the time of the collision. The application is made to an oscillating barrier in one dimension. Several tests of the formalism validate the analysis, by changing either the initial position of the wave packet, or the phase of the particle–target interaction. Two equivalent necessary conditions can be formulated to recover the results of standard scattering theory. One is that no energies differing by at least one quantum are present in the energy range effectively covered by the initial wave packet. The other is that there is appreciable self-overlapping of the wave packet after one period of oscillation.
We derive and explain the key ideas behind a time-dependent formulation of quantum scattering theory, applicable generally to systems with a finite-range scattering potential. The scattering is initiated and probed by plane wave packets, which are localized just outside the range of the potential. The asymptotic limits of conventional scattering theory (initiation in the remote past; detection in the remote future) are not taken. Instead, the differential cross section (DCS) is obtained by projecting the scattered wave packet onto the probe plane wave packets. The projection also yields a time-dependent version of the DCS. Cuts through the wave packet, just as it exits the scattering potential, yield time-dependent and time-independent angular distributions that give a close-up picture of the scattering which complements the DCS. We have previously applied the theory to interpret experimental cross sections of chemical reactions [e.g., S. C. Althorpe, F. Fern\'andez-Alonso, B. D. Bean, J. D. Ayers, A. E. Pomerantz, R. N. Zare, and E. Wrede, Nature (London) 416, 67 (2002)]. This paper gives the derivation of the theory, and explains its relation to conventional scattering theory. For clarity, the derivation is restricted to spherical-particle scattering, though it may readily be extended to general multichannel systems. We illustrate the theory using a simple application to hard-sphere scattering.
We consider the scattering of a particle by an oscillating rectangular barrier at energies matching with the above barrier resonances. A resonance associated with the barrier has an energy which oscillates in time. With appropriately defined parameters it is possible, using a calculation entirely based on the time-independent scattering amplitudes, to show that the transmission probability is enhanced when the wave packet describing the particle arrives on the device at a time when the resonance energy matches the energy of the particle.
Two different formulations of the problem of time-delay caused by scattering from an oscillating center of force are studied. In the first one, appropriate for local interactions, a semi-classical time-dependent solution of the Schrödinger equation is obtained by writing the wave function as a solution of two coupled equations one of which is the Hamilton–Jacobi equation. These equations are then solved using the narrow wave packet approximation. The classical motion of the center of this wave packet is found for two specific cases, a square well and a Morse potential. In the second formulation a time-independent many-channel solution of the Schrödinger equation is obtained for an exactly solvable quantum-mechanical problem with a potential consisting of a separable attractive part which oscillates and a fixed rigid wall. The results show that the time-delay is extremely sensitive to the values of the amplitude and the frequency of oscillations, and also to the energy of the incident particle.
We discuss a solution of the time-dependent Schrödinger equation that incorporates absorbing boundary conditions and a method for extracting the reflection and transmission probabilities for wave packets interacting with time-dependent potential barriers. We apply the method to a rectangular barrier that moves with constant velocity, an oscillating rectangular barrier, a locally periodic barrier with an amplitude modulated by a traveling wave, and a locally periodic potential with an amplitude modulated by a standing wave. Visualizations of the reflection phenomena are presented with an emphasis on understanding these systems from their dynamics. Applications to non-stationary neutron optics experiments are discussed briefly.
Two-body scattering is analyzed using a time-dependent formalism and wave packets of arbitrary shape as the initial wavefunctions. In particular, the case of single-channel resonant scattering is discussed in some detail. In addition to the usual amplitudes resulting from the potential term and the resonant term, a third amplitude is found which interferes with the other two. Another interesting result is that in this formalism the final state is not necessarily represented by spherical outgoing waves, but can be interpreted instead as two separate outgoing wave packets whose shape is different from the initial packets. The Wigner time delay is obtained as a natural consequence of the analysis, and the resonant cross sections are expressed as density matrices constructed from the wave packets.
We consider the quantum scattering off a time dependent barrier in one dimension. Our initial state is a right going eigenstate of the Hamiltonian at time t=0. It consists of a plane wave incoming from the left, a reflected plane wave on the left of the barrier and a transmitted wave on its right. We find that at later times, the evolving wave function has a finite overlap with left going eigenstates of the Hamiltonian at time t=0. For simplicity we present an exact result for a time dependent delta function potential. Then we show that our result is not an artifact of that specific choice of the potential. This surprising result does not agree with our interpretation of the eigenstates of the Hamiltonian at time t=0. A numerical study of evolving wave packets, does not find any corresponding real effect. Namely, we do not see on the right hand side of the barrier any evidence for a left going packet. Our conclusion is thus that the intriguing result mentioned above is intriguing only due to the semantics of the interpretation.