Macroscopic description of time evolution of quantum systems

Johannes Kofler

The descriptions of the quantum realm and the macroscopic classical world differ significantly not only in their mathematical formulations but also in their foundational concepts and philosophical consequences. When and how physical systems stop to behave quantum mechanically and begin to behave classically is still heavily debated in the physics community and subject to theoretical and experimental research. This dissertation puts forward an approach to the quantum-to-classical transition fully within quantum theory and conceptually different from already existing models: It neither needs to refer to the uncontrollable environment of a system (decoherence) nor to change the quantum laws itself (collapse models), but puts the stress on the limits of observability of quantum phenomena due to the imprecision of our measurement apparatuses. For a certain class of time evolutions it is this mere restriction to coarse-grained measurements which is sufficient to see the natural emergence of macroscopic realism and even the classical Newtonian laws out of the full quantum formalism. But there also exist "non-classical" Hamiltonians for which a classical spatiotemporal description of the system's time evolution remains impossible even under fuzzy measurements or decoherence. It is argued that such Hamiltonians are unlikely to be spontaneously realized in nature because of their high complexity. The last part addresses the question of the origin of quantum randomness and proposes a link with mathematical undecidability.

G. C. Ghirardi, A. Rimini, T. Weber

An explicit model allowing a unified description of microscopic and macroscopic systems is exhibited. First, a modified quantum dynamics for the description of macroscopic objects is constructed and it is shown that it forbids the occurrence of linear superpositions of states localized in far-away spatial regions and induces an evolution agreeing with classical mechanics. This dynamics also allows a description of the evolution in terms of trajectories. To set up a unified description of all physical phenomena, a modification of the dynamics, with respect to the standard Hamiltonian one, is then postulated also for microscopic systems. It is shown that one can consistently deduce from it the previously considered dynamics for the center of mass of macroscopic systems. Choosing in an appropriate way the parameters of the so-obtained model one can show that both the standard quantum theory for microscopic objects and the classical behavior for macroscopic objects can all be derived in a consistent way. In the case of a macroscopic system one can obtain, by means of appropriate approximations, a description of the evolution in terms of a phase-space density distribution obeying a Fokker-Planck diffusion equation. The model also provides the basis for a conceptually appealing description of quantum measurement.

Arno Böhm, Piotr Kielanowski, G. B. Mainland

Barbara Fresch, Giorgio J. Moro

Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e., the wavefunction, of an isolated system is determined to calculate molecular properties and their time evolution according to the unitary Schrödinger equation. On the other hand a mixed state, i.e., a statistical density matrix, is the standard formalism to account for thermal equilibrium, as postulated in the microcanonical quantum statistics. In the present paper an alternative treatment relying on a statistical analysis of the possible wavefunctions of an isolated system is presented. In analogy with the classical ergodic theory, the time evolution of the wavefunction determines the probability distribution in the phase space pertaining to an isolated system. However, this alone cannot account for a well defined thermodynamical description of the system in the macroscopic limit, unless a suitable probability distribution for the quantum constants of motion is introduced. We present a workable formalism assuring the emergence of typical values of thermodynamic functions, such as the internal energy and the entropy, in the large size limit of the system. This allows the identification of macroscopic properties independently of the specific realization of the quantum state. A description of material systems in agreement with equilibrium thermodynamics is then derived without constraints on the physical constituents and interactions of the system. Furthermore, the canonical statistics is recovered in all generality for the reduced density matrix of a subsystem.