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Journal of Physics B Atomic Molecular and Optical Physics

Hole-burning in atomic and ionic spectral lines

W. Bestgen, M. Elbel, Roman W. Lange, H Welp

Published Jul 14, 1995• 2 citations
Publisher

Abstract

Applying the momentum method, the Fokker-Planck equation is derived from the Boltzmann equation for the r -4 potential between atoms and ions. Two earlier attempts are revealed to be limiting cases of our more general equation, namely for very large and very small mass ratio of the collision partners. The Fokker-Planck equation, after being completed with a decay term and a source term, is solved by the Green's function method. The solution turns out to be composed of modes in the velocity space which decay independently towards a stationary spectrum. The amplitudes of the latter depend on the source term which we assume to be shaped like a delta -function if laser pumping is accounted for. Only for very long relaxation times does the lowest mode prevail in the spectrum which then merges into the Maxwell distribution. Several new lines for ion-atom pairs as well as atom-atom pairs have been measured. They are presented along with the fits using the aforementioned formula. As expected, the agreement is satisfactory only in the first case. In the second case the Fokker-Planck approximation no longer applies.

DOI
10.1088/0953-4075/28/13/011

Related papers

Legendre functions and the theory of hole burning

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Based on the momentum method the Fokker-Planck equation is derived for a velocity distribution perturbed by monomode laser excitation (hole burning). If the used collision kernel applies to marked forward scattering and if the collision partner is assumed to be infinitely heavy, the FPE degenerates into the Legendre equation. While a proportional term accounts for the decay of atoms, an inhomogeneity accounts for their creation. The considered species is metastable argon ions. These ions are probably created by electronic ionization, while both electronic deexcitation and metastability exchange interfere in their destruction. The laser keeps the solution of the FPE at zero level for any velocity whose component along the laser beam upsilon z,0 follows from the laser frequency by the Doppler condition. We treat this constraint as a boundary condition for the solution. The latter is put up as a superposition of the Legendre function which solves the homogeneous part, with a special solution of the inhomogeneous equation. Free parameters are adjusted to the boundary condition. The thus obtained solution is finally integrated over all the velocity groups of atoms which under our assumptions are not coupled collisionally, to yield the expected shape of the signal. The velocity groups were assumed to be distributed according to Maxwell. We devised two types of experiments to measure the shape of the hole. Both are suited to measure holes on the wings as well as on the centre of the line. Remarkable similarity of the measured and the calculated signals is found.

Journal of Physics B Atomic Molecular and Optical Physics•Oct 14, 1993•2 citations

Quantum Theory of a Gas Laser. II

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We generalize the method of deriving a kinetic equation for a gas laser developed in the first paper of this series to include radiation-matter correlations. As a consequence, we are able to show that the first Born approximation with asymptotic conditions which contain radiation-matter correlations is sufficient to explain the nonthermal photon distribution observed in photon-counting experiments. Our derivation includes the spatial and velocity effects of the motion of the gas atoms. After adiabatically eliminating the matter variables, we obtain a master equation for the radiation density matrix $R$ with nonlinear coefficients. Our radiation master equation for stationary atoms without spatial effects is the same as the generalized Fokker-Planck equation of the Langevin-noise-equation treatment of lasers. We show that the generalized Fokker-Planck equation is the result of the first-Born-approximation treatment of the j\ifmmode\cdot\else\textperiodcentered\fi{}A interaction and is not dependent upon the microscopic structure of the reservoirs. In the first Born approximation, the diagonal and off-diagonal matrix elements of $R$ do not interact with each other. Consequently, an initially diagonal radiation density matrix remains diagonal. However, we show that even though the stationary state is diagonal it is necessary to know the propagator of the off-diagonal part of $R$ to answer time-dependent questions about quantities, such as the line shape, that depend on phase.

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Temporal behavior of the velocity distribution function and the influence of collisions in laser cooling

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We present exact time-dependent solutions of the Fokker–Planck equation including the collisional term, which describes the influence of the laser field and collisions with the surrounding gas on the temporal behavior of the distribution function of cooled particles in the last stage of the cooling process. These solutions allow us to estimate the influence of collisions on the limiting temperature of free particles and trapped ions.

Journal of the Optical Society of America B•Sep 1, 1993•5 citations

Quantum-Mechanical, Microscopic Brownian Motion

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Recently, the Fokker-Planck (F-P) equation, satisfied by the phase-space distribution function of a Brownian (B) particle, has been derived from the Liouville equation, satisfied by the phase-space distribution function of the composite system, B particle plus fluid. We have started from a strictly quantum-mechanical formulation of the problem, using a density-matrix description of the composite system, and have shown that in an appropriate classical limit the F-P equation results. To lowest order in $\ensuremath{\hbar}$, our technique gives the same expression for the friction coefficient obtained earlier from the Liouville equation. In principle it yields corrections to the F-P equation to all orders in $\ensuremath{\hbar}$. We have shown that for a uniform fluid, the quantum corrections to the F-P equation to first order in $\ensuremath{\hbar}$ appear only as a shift in the friction coefficient. If the classical friction coefficient ${\ensuremath{\zeta}}_{0}$ is replaced by ${\ensuremath{\zeta}}_{0}+\ensuremath{\hbar}{\ensuremath{\zeta}}_{1}$, with an appropriate ${\ensuremath{\zeta}}_{1}$, then the F-P equation is given correctly to order $\ensuremath{\hbar}$. There is a difference in the mass dependence of ${\ensuremath{\zeta}}_{0}$ and ${\ensuremath{\zeta}}_{1}$ which suggests the existence of an isotope effect in the mobility of a particle moving through a quantum fluid. The technique employed in the derivation is to consider the expectation value of the density matrix of the system in a state in which the position and momentum of the particles are known with maximum accuracy (Kennard packet). This expectation value $\ensuremath{\mu}$ is an appropriate, positive, semiclassical phase-space distribution function. An appropriate equation is derived for $\ensuremath{\mu}$, which to lowest order in $\ensuremath{\hbar}$ is the Liouville equation. The remainder of the derivation is similar to the derivation in the classical case (a suitable projection technique is used).

Physical Review•May 6, 1966•38 citations

Schrodinger Equation from Fokker-Planck Equation and Contradiction Due To Interference? Part II

Francesco R. Ruggeri

Classical mechanics traces a particle’s movement through space and time through x(t). For example, one may consider the case of a particle moving at constant speed (momentum p) in one direction or a particle bouncing back and forth at constant speed in a box. These problems are described in time and have direction and position associated with time etc. It is possible to define a probability P(x,t) in the classical picture based on delta time, the amount of time a particle spends in a little region of space dx. P(x,t), by itself, loses much relevant information present in the x(t) scenario because a particle moving to the right, or to the left, or bouncing back and forth all have the same probability, 1/L, where L is length. Furthermore, this probability is the same for all p (momentum) values. Thus a probability description, without extra information, is a subset of the relevant information in the problem. As a result, to describe the classical picture fully, one might say that a particle has a probability of 1/L, but also a mass mo and velocity +v (i.e. momentum mov nonrelativistically). For the particle bouncing back and forth in a box with constant p, one needs to give the initial position at time=0 and then a subsequent time (as well as the initial velocity and mo) in order to fully describe the problem, even though probability = 1/L. In the literature (see (1)), there have been many attempts to derive the quantum Schrodinger equation from a classical Fockker-Planck equation or a continuity equation (which follows from the Fokker-Planck equation as shown in (1)). The continuity equation contains a probability P(x,t) and a velocity(x,t) and is generally argued to represent classical physics. It does, if one retains appropriate classical conditions such as the discontinuity of density for a particle in a box (i.e. density=0 outside the box, but 1/L inside) and the notion of differing directions within the box. In fact, one may write density=W*(x,t)W(x,t) where W(x,t) is an ad hoc complex function and still retain compatibility with classical physics. If one does not, however, retain the classical conditions completely, nonclassical physics is introduced, even if density(x,t)=1/L. For example, in quantum mechanics density(x) is considered to be continuous in all x. Thus for a particle moving in a box, density outside the box is 0 so at the box wall it must also be 0. In the classical case, the density is 1 inside the box and 0 outside. There is a discontinuity classically and this cannot be changed and this contradicts the quantum mechanical picture. Thus quantum mechanics does not follow form classical Fokker-Planck or continuity equations which retain classical conditions.. Furthermore, because time is completely removed in the FP-continuity approach as applied to quantum mechanics, one cannot distinguish between forwards and backwards motion. As seen by the velocity field given in (1), v is zero for a bound particle which completely removes the sense of time and violates the classical physics conditions. It is, however, not zero for a particle moving in one direction. Thus there seems to be no issue in describing a Fokker-Planck-continuity equation as describing classical physics. One may even introduce density(x,t)= W*(x,t)W(x,t) provided one retains classical conditions allowing for discontinuity in density and different W(x,t) values at different times i.e. a discontinuity in W(x,t) at a box wall. If these conditions, however, are not met, then one no longer describes classical physics, but a new kind of physics (quantum physics). Thus one cannot argue that quantum mechanics follows from classical statistical Fokker-Planck-continuity equations. It may follow from these if one adds a set of extra conditions. Given these extra conditions, however, one could derive quantum mechanics without starting with classical density.

•Apr 24, 2023•0 citations

Light-induced motion of trapped ions. III. Expansion around the recoilless solution

Juha Javanainen

For pt.II see ibid., vol.14, p.4191 (1981). The author derives a Fokker-Planck equation for the Wigner function describing the centre-of-mass motion of a harmonically trapped ion in a travelling wave of light, using an expansion in the recoil velocity around the exact time-dependent solution of the recoilless case. The practical calculations are reduced to the scheme presented in the earlier papers of this series. However, the final energy of the cooling differs from his earlier results, and agrees with more recent calculations employing for the centre of mass the representation in the harmonic oscillator states.

Journal of Physics B Atomic and Molecular Physics•Apr 28, 1985•18 citations
Applying the momentum method, the Fokker-Planck equation is derived from the Boltzmann equation for the r -4 potential between atoms and ions. Two earlier attempts are revealed to be limiting cases of our more general equation, namely for very large and very small mass ratio of the collision partners. The Fokker-Planck equation, after being completed with a decay term and a source term, is solved by the Green's function method. The solution turns out to be composed of modes in the velocity space which decay independently towards a stationary spectrum. The amplitudes of the latter depend on the source term which we assume to be shaped like a delta -function if laser pumping is accounted for. Only for very long relaxation times does the lowest mode prevail in the spectrum which then merges into the Maxwell distribution. Several new lines for ion-atom pairs as well as atom-atom pairs have been measured. They are presented along with the fits using the aforementioned formula. As expected, the agreement is satisfactory only in the first case. In the second case the Fokker-Planck approximation no longer applies.
Based on the momentum method the Fokker-Planck equation is derived for a velocity distribution perturbed by monomode laser excitation (hole burning). If the used collision kernel applies to marked forward scattering and if the collision partner is assumed to be infinitely heavy, the FPE degenerates into the Legendre equation. While a proportional term accounts for the decay of atoms, an inhomogeneity accounts for their creation. The considered species is metastable argon ions. These ions are probably created by electronic ionization, while both electronic deexcitation and metastability exchange interfere in their destruction. The laser keeps the solution of the FPE at zero level for any velocity whose component along the laser beam upsilon z,0 follows from the laser frequency by the Doppler condition. We treat this constraint as a boundary condition for the solution. The latter is put up as a superposition of the Legendre function which solves the homogeneous part, with a special solution of the inhomogeneous equation. Free parameters are adjusted to the boundary condition. The thus obtained solution is finally integrated over all the velocity groups of atoms which under our assumptions are not coupled collisionally, to yield the expected shape of the signal. The velocity groups were assumed to be distributed according to Maxwell. We devised two types of experiments to measure the shape of the hole. Both are suited to measure holes on the wings as well as on the centre of the line. Remarkable similarity of the measured and the calculated signals is found.
We generalize the method of deriving a kinetic equation for a gas laser developed in the first paper of this series to include radiation-matter correlations. As a consequence, we are able to show that the first Born approximation with asymptotic conditions which contain radiation-matter correlations is sufficient to explain the nonthermal photon distribution observed in photon-counting experiments. Our derivation includes the spatial and velocity effects of the motion of the gas atoms. After adiabatically eliminating the matter variables, we obtain a master equation for the radiation density matrix RRR with nonlinear coefficients. Our radiation master equation for stationary atoms without spatial effects is the same as the generalized Fokker-Planck equation of the Langevin-noise-equation treatment of lasers. We show that the generalized Fokker-Planck equation is the result of the first-Born-approximation treatment of the j\ifmmode\cdot\else\textperiodcentered\fi{}A interaction and is not dependent upon the microscopic structure of the reservoirs. In the first Born approximation, the diagonal and off-diagonal matrix elements of RRR do not interact with each other. Consequently, an initially diagonal radiation density matrix remains diagonal. However, we show that even though the stationary state is diagonal it is necessary to know the propagator of the off-diagonal part of RRR to answer time-dependent questions about quantities, such as the line shape, that depend on phase.
Recently, the Fokker-Planck (F-P) equation, satisfied by the phase-space distribution function of a Brownian (B) particle, has been derived from the Liouville equation, satisfied by the phase-space distribution function of the composite system, B particle plus fluid. We have started from a strictly quantum-mechanical formulation of the problem, using a density-matrix description of the composite system, and have shown that in an appropriate classical limit the F-P equation results. To lowest order in $\ensuremath{\hbar}$, our technique gives the same expression for the friction coefficient obtained earlier from the Liouville equation. In principle it yields corrections to the F-P equation to all orders in $\ensuremath{\hbar}$. We have shown that for a uniform fluid, the quantum corrections to the F-P equation to first order in $\ensuremath{\hbar}$ appear only as a shift in the friction coefficient. If the classical friction coefficient ${\ensuremath{\zeta}}_{0}$ is replaced by ${\ensuremath{\zeta}}_{0}+\ensuremath{\hbar}{\ensuremath{\zeta}}_{1}$, with an appropriate ${\ensuremath{\zeta}}_{1}$, then the F-P equation is given correctly to order $\ensuremath{\hbar}$. There is a difference in the mass dependence of ${\ensuremath{\zeta}}_{0}$ and ${\ensuremath{\zeta}}_{1}$ which suggests the existence of an isotope effect in the mobility of a particle moving through a quantum fluid. The technique employed in the derivation is to consider the expectation value of the density matrix of the system in a state in which the position and momentum of the particles are known with maximum accuracy (Kennard packet). This expectation value $\ensuremath{\mu}$ is an appropriate, positive, semiclassical phase-space distribution function. An appropriate equation is derived for $\ensuremath{\mu}$, which to lowest order in $\ensuremath{\hbar}$ is the Liouville equation. The remainder of the derivation is similar to the derivation in the classical case (a suitable projection technique is used).
Classical mechanics traces a particle’s movement through space and time through x(t). For example, one may consider the case of a particle moving at constant speed (momentum p) in one direction or a particle bouncing back and forth at constant speed in a box. These problems are described in time and have direction and position associated with time etc. It is possible to define a probability P(x,t) in the classical picture based on delta time, the amount of time a particle spends in a little region of space dx. P(x,t), by itself, loses much relevant information present in the x(t) scenario because a particle moving to the right, or to the left, or bouncing back and forth all have the same probability, 1/L, where L is length. Furthermore, this probability is the same for all p (momentum) values. Thus a probability description, without extra information, is a subset of the relevant information in the problem. As a result, to describe the classical picture fully, one might say that a particle has a probability of 1/L, but also a mass mo and velocity +v (i.e. momentum mov nonrelativistically). For the particle bouncing back and forth in a box with constant p, one needs to give the initial position at time=0 and then a subsequent time (as well as the initial velocity and mo) in order to fully describe the problem, even though probability = 1/L. In the literature (see (1)), there have been many attempts to derive the quantum Schrodinger equation from a classical Fockker-Planck equation or a continuity equation (which follows from the Fokker-Planck equation as shown in (1)). The continuity equation contains a probability P(x,t) and a velocity(x,t) and is generally argued to represent classical physics. It does, if one retains appropriate classical conditions such as the discontinuity of density for a particle in a box (i.e. density=0 outside the box, but 1/L inside) and the notion of differing directions within the box. In fact, one may write density=W*(x,t)W(x,t) where W(x,t) is an ad hoc complex function and still retain compatibility with classical physics. If one does not, however, retain the classical conditions completely, nonclassical physics is introduced, even if density(x,t)=1/L. For example, in quantum mechanics density(x) is considered to be continuous in all x. Thus for a particle moving in a box, density outside the box is 0 so at the box wall it must also be 0. In the classical case, the density is 1 inside the box and 0 outside. There is a discontinuity classically and this cannot be changed and this contradicts the quantum mechanical picture. Thus quantum mechanics does not follow form classical Fokker-Planck or continuity equations which retain classical conditions.. Furthermore, because time is completely removed in the FP-continuity approach as applied to quantum mechanics, one cannot distinguish between forwards and backwards motion. As seen by the velocity field given in (1), v is zero for a bound particle which completely removes the sense of time and violates the classical physics conditions. It is, however, not zero for a particle moving in one direction. Thus there seems to be no issue in describing a Fokker-Planck-continuity equation as describing classical physics. One may even introduce density(x,t)= W*(x,t)W(x,t) provided one retains classical conditions allowing for discontinuity in density and different W(x,t) values at different times i.e. a discontinuity in W(x,t) at a box wall. If these conditions, however, are not met, then one no longer describes classical physics, but a new kind of physics (quantum physics). Thus one cannot argue that quantum mechanics follows from classical statistical Fokker-Planck-continuity equations. It may follow from these if one adds a set of extra conditions. Given these extra conditions, however, one could derive quantum mechanics without starting with classical density.
For pt.II see ibid., vol.14, p.4191 (1981). The author derives a Fokker-Planck equation for the Wigner function describing the centre-of-mass motion of a harmonically trapped ion in a travelling wave of light, using an expansion in the recoil velocity around the exact time-dependent solution of the recoilless case. The practical calculations are reduced to the scheme presented in the earlier papers of this series. However, the final energy of the cooling differs from his earlier results, and agrees with more recent calculations employing for the centre of mass the representation in the harmonic oscillator states.