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European Journal of Physics

WKB approximation for abruptly varying potential wells

Attapon Amthong

Published Sep 3, 2014• 7 citations
Publisher

Abstract

We present an approach to obtain eigenfunctions and eigenenergies for abruptly varying potentials in the framework of the Wentzel–Kramers–Brillouin (WKB) approximation. To illustrate it, two examples of the potentials are studied. The first one is the combination of a step barrier and a harmonic oscillator potential, and the second one consists of a step barrier and a linear potential. The formulation of a WKB quantization rule is proposed. Our approach shows that WKB energies and those from numerical calculation are in good agreement. According to matching conditions used, WKB wavefunctions in this present work are violated at only one classical turning point, but they behave well at another point where the potentials are discontinuous.

DOI
10.1088/0143-0807/35/6/065009

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We present an approach to obtain eigenfunctions and eigenenergies for abruptly varying potentials in the framework of the Wentzel–Kramers–Brillouin (WKB) approximation. To illustrate it, two examples of the potentials are studied. The first one is the combination of a step barrier and a harmonic oscillator potential, and the second one consists of a step barrier and a linear potential. The formulation of a WKB quantization rule is proposed. Our approach shows that WKB energies and those from numerical calculation are in good agreement. According to matching conditions used, WKB wavefunctions in this present work are violated at only one classical turning point, but they behave well at another point where the potentials are discontinuous.
We extend the Wentzel–Kramers–Brillouin (WKB) approximation to the semi-relativistic spinless Salpeter equation. The Bohr–Sommerfeld quantization rule for a one-dimensional potential is derived by properly connecting the WKB wave functions. Since the latter diverges at the classical turning points (TPs), we develop a uniform WKB approach that yields an approximate wave function valid everywhere including the TPs, along with a modified quantization condition. The method is illustrated for the symmetric linear potential, and comparison with exact numerical results shows excellent agreement, significantly improving upon the standard WKB method.
The WKB approximation is a physically intuitive method and makes many connections with intuition about waves and classical mechanics as well as with results from the early days of quantum theory as it leads to the Bohr quantization condition. The WKB method is due to Gregor Wentzel, Hendrik Anthony Kramers and Leon Nicolas Brillouin. The method is applicable for slowly varying potentials, that is, the potentials that change not more than a few wavelengths. The WKB approximation is a physically intuitive method and makes many connections with intuition about waves and classical mechanics as well as with results from the early days of quantum theory as it leads to the Bohr quantization condition. The Schrödinger equation is solved to find the penetration of a square potential barrier. The WKB method is applied to obtain a transmission coefficient for penetration through a barrier.
We demonstrate that the Bargmann representation of quantum mechanics is ideally suited for semiclassical analysis, using as an example the WKB method applied to the bound-state problem in a single well of one degree of freedom. While the WKB expansion formulas are basically the usual ones, in this representation they describe approximations that are uniform and nonsingular in the classically allowed region of phase space because no turning points appear there. The quantization of energy levels relies on a complex contour integral that tests the eigenfunction for analyticity. For the harmonic oscillator, this WKB method trivially gives the exact eigenfunctions in addition to the exact eigenvalues. For an anharmonic well, a self-consistent variational choice of the representation greatly improves the accuracy of the semiclassical ground state. Also, a simple change of scale illuminates the relationship of semiclassical versus linear perturbative expansions, allowing a variety of multidimensional extensions. All in all, the Bargmann representation appears to combine the advantages of a linear description and of a phase-space representation of the quantum state vectors.
The single harmonic oscillator and double-well potentials are important systems in quantum mechanics. The single harmonic oscillator is the paradigm in physics and is taught in nearly all beginner undergraduate classes, while the double-well potential illustrates the two important principles of quantum tunneling and linear superposition. While exact analytical solutions of the Schrödinger equation exist for both of these potentials, they are also employed to benchmark the use of approximate techniques, which may be the only recourse for more complicated potentials. In this paper, we review the Wentzel–Kramers–Brillouin (WKB) approximation for both these potentials. While this approximation is known for its accurate energies, we will instead emphasize how poor the WKB wave functions are. The inaccuracy of the WKB wave functions will then motivate us to adopt the lesser-known Modified Airy Function (MAF) approximation, which alleviates the deficiencies of the WKB wave functions. We will review the MAF solution to the simple harmonic oscillator potential and then apply the MAF to the double-well potential. We find accurate eigenvalues and, more importantly, very accurate wave functions. We conclude with the suggestion that an introduction to the MAF should be included in undergraduate courses to complement the WKB.
We apply a many-body Wentzel-Kramers-Brillouin (WKB) approach to determine the leading quantum corrections to the semiclassical dynamics of the Josephson model, describing interacting bosons able to tunnel between two localized states. The semiclassical dynamics is known to divide between regular oscillations and self-trapped oscillations where the sign of the imbalance remains fixed. In both cases, the WKB wave functions are matched to Airy functions, yielding a modified Bohr-Sommerfeld quantization condition. At the critical energy dividing normal and self-trapped oscillations, the WKB wave functions should instead be matched to parabolic cylinder functions, leading to a quantization formula that is not just the Bohr-Sommerfeld formula, and recovering the known logarithmic quantum break times at this energy. This work thus provides another illustration of the usefulness of the WKB approach in certain many-body problems.