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Physical Review

Condensation in a Two-Dimensional Hartree-Fock Boson Gas

Warren D. Grobman

Published Jun 5, 1969• 1 citation
Publisher

Abstract

The behavior of a two-dimensional gas of interacting bosons is studied in the Hartree-Fock approximation in the low-temperature strong-interaction regime. It is shown that the thermodynamic state of lowest free energy possesses a Bose-Einstein condensation. We discuss the fact that the occurrence of long-range order in this two-dimensional system is a consequence of the nonlocality of the Hartree-Fock interaction.

DOI
10.1103/physrev.182.297

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The behavior of a two-dimensional gas of interacting bosons is studied in the Hartree-Fock approximation in the low-temperature strong-interaction regime. It is shown that the thermodynamic state of lowest free energy possesses a Bose-Einstein condensation. We discuss the fact that the occurrence of long-range order in this two-dimensional system is a consequence of the nonlocality of the Hartree-Fock interaction.
Abstract We consider a Bose gas with two-body Kac-like scaled interactions where is a given repulsive and integrable potential, while is a positive parameter which controls the range of the interactions and their amplitude at a distance r. Using the Hartree–Fock (HF) approximation we find that, at finite non-zero temperatures, the Bose–Einstein (BE) condensation is destroyed by the repulsive interactions when they are sufficiently long-range. More precisely, we show that for sufficiently small but finite the off-diagonal part of the one-body density matrix always vanishes at large distances. Our analysis sheds light on the coupling between critical correlations and long-range interactions, which might lead to the breakdown of the off-diagonal long-range order even beyond the HF approximation. Furthermore, our HF analysis shows the existence of a threshold value above which the BE condensation is restored. Since is an unbounded increasing function of the temperature this implies for a fixed , namely for a fixed scaled potential, that a condensate cannot form above some critical temperature whatever the value of the density.
The fact that two-dimensional interacting trapped systems do not undergo Bose-Einstein Condensation (BEC) in the thermodynamic limit, though rigorously proved, is somewhat mysterious because all relevant limiting cases (zero temperature, small atom numbers, noninteracting particles) suggest otherwise. We study the possibility of condensation in finite trapped two-dimensional systems. We first consider the ideal gas, which incorporates the inhomogeneity and finite size of experimental systems and can be solved exactly. A semiclassical self-consistent approximation gives us a feel for the temperature scales; diagonalization of the one-body density matrix confirms that the condensation is into a single state. We squeeze a three-dimensional system and see how it crosses over into two dimensions. Mean-field theory, our main tool for the study of interacting systems, prescribes coupled equations for the condensate and the thermal cloud: the condensate receives a full quantum-mechanical treatment, while the noncondensate is described by different schemes of varying sophistication. We analyze the T = 0 case and its approach to the thermodynamic limit, finding a criterion for the dimensionality crossover and obtaining the coupling constant of the two-dimensional system that results from squeezing a three-dimensional trap. We next apply a semiclassical Hartree-Fock approximation to purely two-dimensional finite gases and find that they can be described either with or without a condensate; this continues to be true in the thermodynamic limit. The condensed solutions have a lower free energy at all temperatures but neglect the presence of phonons within the system and cease to exist when we allow for this possibility. The uncondensed solutions, in turn, are valid under a more rigorous scheme but have consistency problems of their own. Path-integral Monte Carlo simulations provide an essentially exact description of finite interacting gases and enable us to study highly anisotropic systems at finite temperature. We find that our two-dimensional Hartree-Fock solutions accurately mimic the surface density profile and predict the condensate fraction of these systems; the equivalent interaction parameter is smaller than that dictated by the T = 0 analysis. We conclude that, in two-dimensional isotropic finite trapped systems and in highly compressed three-dimensional gases, there is a phenomenon resembling a condensation into a single state.
The phase transition of the one-dimensional Bose gas, interacting weakly with a repulsive potential and trapped in an external parabolic potential, is studied in a mean field approximation. The Bose–Einstein condensed (BEC) state is identified by the non-vanishing thermal average of a bose field. Free energies between the BEC state and normal state are compared. A crossing of the free energies occurring at low temperature suggests the first order phase transition in an interacting one-dimensional bose system. From fitting of numerical results, the relation among the transition temperature T c , the total number of bosons N and the interaction V is also provided as a simple power law, T c ∝( N 2 V ) 2/3 .
This colloquium surveys a number of theoretical problems and open questions in the field of two-dimensional dilute Bose gases with weak repulsive interactions. In contrast to three dimensions, in two dimensions the formation of long-range order is prohibited by the Bogoliubov-Hohenberg theorem, and Bose-Einstein condensation is not expected to occur. Nevertheless, experimental indications supporting the formation of a condensate in low-dimensional systems have recently been obtained. This unexpected behavior appears to be due to the nonuniformity introduced into a system by the external trapping potential. Theoretical predictions, made for homogeneous systems, require therefore careful reexamination. A number of popular theoretical treatments of the dilute weakly interacting Bose gas are presented and their regions of applicability are discussed. The possibility of Bose-Einstein condensation in a two-dimensional gas, the validity of the perturbative ttt-matrix approximation, and the diluteness condition are issues also discussed in detail.