Bose-Einstein condensation (BEC) of a noninteracting Bose gas of N particles in a two-dimensional box with Dirichlet boundary conditions is studied. Confirming previous work, we find that BEC occurs at finite N at low temperatures T without the occurrence of a phase transition. The conventionally-defined transition temperature T(E) for an infinite three-dimensional (3D) system is shown to correspond in a 2D system with finite N to a crossover temperature between a slow and rapid increase in the fractional boson occupation N(0)/N of the ground state with decreasing T. We further show that T(E)∼1/logN at fixed area per boson, so in the thermodynamic limit there is no significant BEC in 2D at finite T. Thus, paradoxically, BEC only occurs in 2D at finite N with no phase transition associated with it. Calculations of thermodynamic properties versus T and area A are presented, including Helmholtz free energy, entropy S, pressure p, ratio of p to the energy density U/A, heat capacity at constant volume (area) C(V) and at constant pressure C(p), isothermal compressibility κ(T) and thermal expansion coefficient α(p), obtained using both the grand-canonical ensemble (GCE) and canonical ensemble (CE) formalisms. The GCE formalism gives acceptable predictions for S, p, p/(U/A), κ(T) and α(p) at large N, T and A but fails for smaller values of these three parameters for which BEC becomes significant, whereas the CE formalism gives accurate results for all thermodynamic properties of finite systems even at low T and/or A where BEC occurs.
We present a correlated many-body approach to calculate the distribution function and fluctuations for a Bose-Einstein condensate with
N interacting atoms in the harmonic confinement. The present formulation uses the recursion relation for the canonical ensemble partition function
(Z).
Z is calculated from the energy spectrum of the many-body effective potential, which keeps all possible two-body correlations and uses the realistic interatomic interaction. The condensate statistics are in very good agreement with earlier results of an ideal gas for which exact statistical moments for all temperature are known. We also present the numerical results of condensate statistics for real experimental situations. The calculated moments nicely exhibit the mesoscopic effect for a few hundred atoms, whereas the sharp fall in the variance for the large condensate near the critical temperature shows the possibility of phase transition. We also calculate the critical temperature for the mesoscopic regime. Our present calculation mimics the JILA experiment with
87Rb atoms.
The thermodynamic properties of an ideal gas of bosons moving freely within layered planes and having a finite amplitude for jumping between neighbouring planes, are derived. As long as this coupling is non-zero, the system becomes effectively two-dimensional at sufficiently high temperatures. At a correspondingly low temperature it undergoes a Bose-Einstein transition into a condensed phase as in three dimensions. Below the critical temperature the specific heat is a universal function of only one dimensionless system variable. The phase transition becomes weaker as the coupling between the planes decreases and eventually disappears when the planes decouple.
Using techniques developed by Greenspoon and Pathria, a rigorous, asymptotic analysis of the onset of Bose-Einstein condensation in a finite two-dimensional system at constant pressure is carried out. Some of the results obtained by Imry, Bergman, and Gunther, who first considered this problem, are upheld while others get modified. In particular, a macroscopic occupation of the single-particle ground state at finite temperatures is indeed possible. As the critical region, $T\ensuremath{\simeq}{T}_{c}$, is approached from above, the volume of the system becomes subextensive,
Vc=O(lnNN), which is both necessary and sufficient for the onset of Bose-Einstein condensation in the system. For instance, if the system is now cooled even at constant volume
V(=Vc), the condensate fraction gradually builds up and becomes nonnegligible as
T approaches ${T}_{0}\ensuremath{\simeq}\frac{({T}_{c})}{2}$; below
T0, it grows steadily as $(1\ensuremath{-}\frac{T}{{T}_{0}})$. On the other hand, if we continued to cool the system at constant
P its volume, over a thermodynamically negligible range of temperatures, would reduce to values
O(N21) which, in turn, would be accompanied by an abrupt accumulation of practically all the particles of the system into the single-particle ground state ${\ensuremath{\epsilon}}_{0}$. The specific heat
CP, after having passed through a maximum, would also finally reduce to subextensive values. Phase transitions of this kind may be of relevance to the physical behavior of thin helium films and helium submonolayers.
It is well known that Bose–Einstein condensation cannot occur in a free two-dimensional (2D) system. Recently, several studies have showed that BEC can occur on the surface of a sphere. We investigate BEC on the surface of cylinder on both sides of which atoms are confined in a one-dimensional (1D) harmonic potential. In this work, only the non-interacting Bose gas is considered. We determine the critical temperature and the condensate fraction in the geometry using the semi-classical approximation. Moreover, the thermodynamic properties of ideal bosons are also studied using the grand canonical partition function.