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Physical Review Letters

Theory of Scanning Tunneling Microscopy Measurement of Single Spin Decoherence in a Superconductor

Jurij Šmakov, Ivar Martin, Alexander V. Balatsky

Published Jan 2, 2002• 8 citations
Publisher

Abstract

Localized spin states in conventional superconductors at low temperatures are expected to have a long decoherence time due to the strong suppression of spin relaxation channels. We propose a scanning tunneling microscopy (STM) experiment allowing the direct measurement of the decoherence time of a single spin in a conventional superconductor. The experimental setup can be readily applied to general-purpose spin-polarized STM and to local spin relaxation spectroscopy. A possible extension of the setup to a quantum information processing scheme is discussed.

DOI
10.1103/physrevlett.88.037003

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Localized spin states in conventional superconductors at low temperatures are expected to have a long decoherence time due to the strong suppression of spin relaxation channels. We propose a scanning tunneling microscopy (STM) experiment allowing the direct measurement of the decoherence time of a single spin in a conventional superconductor. The experimental setup can be readily applied to general-purpose spin-polarized STM and to local spin relaxation spectroscopy. A possible extension of the setup to a quantum information processing scheme is discussed.
Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545(Printed February 1, 2008)Localized spin states in conventional superconductors at low temperatures are expected to havelong decoherence time due to the strong suppression of spin relaxation channels. We propose ascanning tunneling microscopy (STM) experiment allowing the direct measurement of the decoher-ence time of a single spin in a conventional superconductor. The experimental setup can be readilyapplied to general-purpose spin-polarized STM and to local spin relaxation spectroscopy. A possibleextension of the setup to a quantum information processing scheme is discussed.
Electron spin resonance in scanning tunneling microscopy enabled the study of electronic transitions of magnetic impurities on surfaces at the atomic scale. This ESR-STM technique allows to spectroscopically probe and coherently manipulate spins using an all-electrical method without oscillating external magnetic driving fields. Here, we aim to review recent advancements in ESR-STM. We will discuss possible fundamental mechanisms by which the electric field drives spin resonance based on Heisenberg exchange, Kondo scattering, and Anderson impurity models. We validate theoretical predictions against experimental observations, to understand how electronic correlations, spin exchange, and many-body effects manifest in ESR-STM signals. After reviewing coherent spin control in the STM junction, we discuss potential applications of the ESR-STM method for coherent multi-spin control which enables multiple-qubit operations. Finally, we address recent developments in coupled electron-nuclear spin systems, including hyperfine-resolved ESR spectroscopy, and the driving and polarization of nuclear spins in ESR-STM.
Electron spin resonance scanning tunneling microscopy (ESR-STM) has become a powerful tool for probing spin dynamics and coherence of individual atoms and molecules on surfaces. In this work, we perform Rabi oscillation and Hahn echo pulse protocols on individual iron phthalocyanine (FePc) molecules on MgO/Ag(001) using ESR-STM. While Hahn echo protocols are widely used to extract spin coherence times, we show that in ESR-STM they are particularly susceptible to misinterpretation due to tunneling electrons generated by the applied radio-frequency (RF) voltage. The RF voltage not only drives the spin, but simultaneously probes and relaxes it, which consequently leads to an exponential decay that reflects spin relaxation rather than intrinsic phase coherence. We moreover show that varying both delay times in the refocusing pulse sequence is a reliable way to ensure a coherent nature of the echo signal. The extracted decay for the latter protocol suggests that T2 is approximately 30 ns and is thus closer to the decoherence time observed in Rabi oscillation measurements. This is significantly shorter than values reported in previous echo measurements. Our findings underscore the need for caution in interpreting T2 times from Hahn echo and Carr-Purcell protocols in ESR-STM and provide practical criteria for distinguishing true spin echoes from tunneling-induced relaxometry signals.
Certifying quantum entanglement is a critical step towards realizing quantum-coherent applications of surface spin systems. In this work, we show that entanglement can be unambiguously shown in a scanning tunneling microscope (STM) with electron spin resonance by exploiting the fact that entangled states undergo a free time evolution with a distinct characteristic time constant that clearly distinguishes it from any other time evolution in the system. By implementing a suitable phase control scheme, the phase of this time evolution can be mapped back onto the population of one entangled spin in a pair, which can then be read out reliably using a weakly coupled sensor spin in the junction of the scanning tunneling microscope. We demonstrate through open quantum system simulations with realistic spin systems, which are currently available with spin coherence times of T2≈T_2\approxT2​≈ 300 ns, that a signal directly correlated with the degree of entanglement can be measured at a temperature range of 100$-$400 mK accessible in sub-Kelvin cryogenic STM systems.