Symmetry Selection Rules of Electric-Dipole Transitions of Eu3+ and Sm2+ in Crystals: A Solid-State Infrared Quantum Counter-Amplifier
Francis K. Fong, Lawrence A. Vredevoe, Roger E. De Wames
A practical scheme for a 10-\ensuremath{\mu} infrared quantum counter-amplifier is proposed, where the infrared frequency is converted into an easily detectable optical frequency. Detailed analysis of the electric-dipole transitions within the $4{f}^{6}$ ground configuration of ${\mathrm{Eu}}^{3+}$ and ${\mathrm{Sm}}^{2+}$ ions in various symmetries reveals that these ions have selection rules in ${C}_{3h}$, ${D}_{3h}$, and ${D}_{3}$ symmetries which allow for significant amplification. This scheme could provide a means of detecting the 10-\ensuremath{\mu} photons generated by the C${\mathrm{O}}_{2}$ laser.
Physical Review•Jun 10, 1968•14 citations