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Journal of Mathematical Physics

Non-Abelian Berry’s phase, accidental degeneracy, and angular momentum

Jan Segert

Published Sep 1, 1987• 28 citations

Abstract

The non-Abelian Berry’s phase effect for a family of operators H0+k⋅V is considered, where H0 is rotationally invariant, V is a vector operator, and k varies over the unit vectors in R3. The parameter space is the two-sphere. The time evolution in the adiabatic limit is given by a connnection on a fiber bundle over the two-sphere. All connections consistent with the rotational symmetry are classified, and the time evolution is explicitly calculated for a nondegenerate Hamiltonian, as well as for a Hamiltonian with a double degeneracy. In the nondegenerate case, the connection is uniquely determined by the symmetry. In the doubly degenerate case, the connection is in some instances not determined by the symmetry. The case of approximate degeneracy is also discussed. A possible experimental test of this effect using optical pumping is described elsewhere.

DOI: 10.1063/1.527422

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The non-Abelian Berry’s phase effect for a family of operators H0+k⋅V is considered, where H0 is rotationally invariant, V is a vector operator, and k varies over the unit vectors in R3. The parameter space is the two-sphere. The time evolution in the adiabatic limit is given by a connnection on a fiber bundle over the two-sphere. All connections consistent with the rotational symmetry are classified, and the time evolution is explicitly calculated for a nondegenerate Hamiltonian, as well as for a Hamiltonian with a double degeneracy. In the nondegenerate case, the connection is uniquely determined by the symmetry. In the doubly degenerate case, the connection is in some instances not determined by the symmetry. The case of approximate degeneracy is also discussed. A possible experimental test of this effect using optical pumping is described elsewhere.

The full effect of adiabatically varying Hamiltonians on systems prepared in eigenstates of the stationary Hamiltonian often includes geometric Berry's phases. For degenerate systems these effects may result in transitions between distinct degenerate eigenstates that can be described in terms of a non-Abelian gauge potential. I demonstrate the explicit dynamic origin of such transitions between degenerate angular-momentum sublevels in an atom that is subject to collinear electric and magnetic fields that rotate adiabatically. The origin of the effects becomes clear when eigenstates of the total Hamiltonian, which includes the rotating fields, are calculated. The total Hamiltonian removes the degeneracy, and the eigenstates are in some cases linear combinations of the angular-momentum sublevels. Thus a system prepared in a specific sublevel may not remain in that sublevel, and the transition probability is exactly that given by an analysis of the geometric phase.

A geometric interpretation of Berry’s phase, its Wilczek–Zee non-Abelian generalization, and Aharonov–Bohm effect is given in terms of connections on principal fiber bundles. It is shown that a principal fiber bundle in all cases can be trivial while the connection and its holonomy group are nontrivial. Therefore the main role is played not by topological effects but geometrical ones. The Berry phase is also shown not to be connected to the adiabatic changes of the Hamiltonian parameters. 1

For a molecular system with an odd number of electrons, the electronic Hamiltonian possesses a twofold Kramers degeneracy for all nuclear configurations. It is shown that this leads to a non-Abelian gauge-field term in the effective nuclear Hamiltonian, with permissible gauge transformations belonging to SU(2). This should lead to observable effects analogous to the Berry phase for the nondegenerate case. In particular, an atom in a slowly rotating electric field exhibits changes in its component of angular momentum along the field because of the non-Abelian phase factor.

In a nondegenerate syste, the abelian Berry's phase will never cause transitions among the Hamiltonian's eigenstate. However, in a degenerate syatem, it is well known that the state transition can be caused by the non-abelian Berry phase. Actually, in a such a system, the phase factor is not always nonabelian. Even in the case that the phase is a nondiagonal matrix, it still can be an abelian phase and can cause the state transitions. We then propose a simple scheme to detect such an effect of the Berry phase to the degenerate states by using the optical entangled pair state. In this scheme, we need not control any external parameters during the quantum state evolution.