We discuss the question of the dynamical meaning of the second law of thermodynamics in the framework of quantum mechanics. Previous discussion of the problem in the framework of classical dynamics has shown that the second law can be given a dynamical meaning in terms of the existence of so-called Lyapounov variables-i.e., dynamical variables varying monotonically in time without becoming contradictory. It has been found that such variables can exist in an extended framework of classical dynamics, provided that the dynamical motion is suitably unstable. In this paper we begin to extend these results to quantum mechanics. It is found that no dynamical variable with the characteristic properties of nonequilibrium entropy can be defined in the standard formulation of quantum mechanics. However, if the Hamiltonian has certain well-defined spectral properties, such variables can be defined but only as a nonfactorizable superoperator. Necessary nonfactorizability of such entropy operators M has the consequence that they cannot preserve the class of pure states. Physically, this means that the distinguishability between pure states and corresponding mixtures must be lost in the case of a quantal system for which the algebra of observables can be extended to include a new dynamical variable representing nonequilibrium entropy. We discuss how this result leads to a solution of the quantum measurement problem. It is also found that the question of existence of entropy of superoperators M is closely linked to the problem of defining an operator of time in quantum mechanics.
We discuss the question of the dynamical meaning of the second law of thermodynamics in the framework of quantum mechanics. Previous discussion of the problem in the framework of classical dynamics has shown that the second law can be given a dynamical meaning in terms of the existence of so-called Lyapounov variables-i.e., dynamical variables varying monotonically in time without becoming contradictory. It has been found that such variables can exist in an extended framework of classical dynamics, provided that the dynamical motion is suitably unstable. In this paper we begin to extend these results to quantum mechanics. It is found that no dynamical variable with the characteristic properties of nonequilibrium entropy can be defined in the standard formulation of quantum mechanics. However, if the Hamiltonian has certain well-defined spectral properties, such variables can be defined but only as a nonfactorizable superoperator. Necessary nonfactorizability of such entropy operators M has the consequence that they cannot preserve the class of pure states. Physically, this means that the distinguishability between pure states and corresponding mixtures must be lost in the case of a quantal system for which the algebra of observables can be extended to include a new dynamical variable representing nonequilibrium entropy. We discuss how this result leads to a solution of the quantum measurement problem. It is also found that the question of existence of entropy of superoperators M is closely linked to the problem of defining an operator of time in quantum mechanics.
The theory of (classical and) quantum mechanical microscopic irreversibility developed by B. Misra, I. Prigogine and M. Courbage (MPC) and various other contributors is based on the central notion of a Lyapounov variable - i.e., a dynamical variable whose value varies monotonically as time increases. Incompatibility between certain assumed properties of a Lyapounov variable and semiboundedness of the spectrum of the Hamiltonian generating the quantum dynamics led MPC to formulate their theory in Liouville space. In the present paper it is proved, in a constructive way, that a Lyapounov variable can be found within the standard Hilbert space formulation of quantum mechanics and, hence, the MPC assumptions are more restrictive than necessary for the construction of such a quantity. Moreover, as in the MPC theory, the existence of a Lyapounov variable implies the existence of a transformation mapping the original quantum mechanical problem to an equivalent irreversible representation. In addition, it is proved that in the irreversible representation there exists a natural time observable splitting the Hilbert space at each t>0 into past and future subspaces.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
In this paper, we discuss the importance of measurement in quantum mechanics and the so-called measurement problem. Any quantum system can be described as a linear combination of eigenstates of an operator representing a physical quantity; this means that the system can be in a superposition of states that corresponds to different eigenvalues, i.e., different physical outcomes, each one incompatible with the others. The measurement process converts a state of superposition (not macroscopically defined) in a well-defined state. We show that, if we describe the measurement by the standard laws of quantum mechanics, the system would preserve its state of superposition even on a macroscopic scale. Since this is not the case, we assume that a measurement does not obey to standard quantum mechanics, but to a new set of laws that form a “quantum measurement theory”.
In this manuscript, we study discrete-time dynamics of systems that arise in physics and information theory, and the measure of disorder in these systems known as dy- namical entropy. The study of dynamics in classical systems is done from two distinct viewpoints: random walks and dynamical systems. Random walks are probabilistic in nature and are described by stochastic processes. On the other hand, dynami- cal systems are described algebraically and deterministic in nature. The measure of disorder from either viewpoint is known as dynamical entropy. Entropy is an essential notion in physics and information theory. Motivated by the study of disorder for the positions and velocities of gas molecules, the notion of entropy was first introduced mathematically by Boltzmann near the end of the 19th Century and gives rise to the second law of thermodynamics. Almost eighty years after Boltzmann, Shannon became the father of the new field of information theory when he produced his groundbreaking works where he used entropy as a measure of information transfer between two sources. In the last two years of the 1950’s, Kolmogorov and Sinai extended the notions of Boltzmann to a dynamical entropy. The Kolmogorov-Sinai dynamical entropy gives a measure for the disorder of a system of particles (e.g. gas molecules) averaged over time, quantifying the uncertainty in the dynamics of a system. The advent of quantum mechanics and its pervasiveness in nature has required the development of non-commutative generalizations of dynamics and dynamical entropy to the quantum regime. Many of each have been proposed. In particular, we recall the definitions of quantum random walks, dynamical systems and Markov chains. We motivate each generalization by relating to its classical counterpart. Quantum dynamical entropy (QDE) is a generalization of the Kolmogorov-Sinai dynamical entropy to quantum mechanics. There have been numerous definitions for QDE beginning with that of Connes, Narnhofer and Thirring in 1987. We focus on the semi- classical approach given by Słomczyński and Życzkowski in 1994 and the quantum Markov chain approach which started with Accardi, Ohya and Watanabe in 1997. Linearity of a dynamical entropy means that the dynamical entropy of the n-fold composition of a dynamical map with itself is equal to n times the dynamical entropy of the map for every positive integer n. We show that the quantum dynamical entropy introduced by Słomczyński and Życzkowski is nonlinear in the time interval between successive measurements of a quantum dynamical system. This is in contrast to Kolmogorov-Sinai dynamical entropy for classical dynamical systems, which is linear in time. We also compute the exact values of quantum dynamical entropy for the Hadamard walk with varying Lüders-von Neumann instruments and partitions. In 1948, Shannon proved the Source Coding Theorem which gives upper and lower bounds on the minimal expected codeword length in terms of the entropy of a ran- dom variable. This theorem can be leveraged to give the minimal expected average codeword length for a string of symbols in terms of entropy rate, which can be in- terpreted as the dynamical entropy of a stochastic process. In 1994, Schumacher defined indeterminate-length quantum codes and proved a Quantum Source Coding Theorem. We introduce the notion of stochastic ensembles of pure states and give a novel representation in terms of quantum Markov chains. Moreover, this representa- tion allows us to extend the Quantum Source Coding Theorem, giving the minimal expected average codeword length of an indeterminate-length quantum code in terms of quantum dynamical entropy. This manuscript includes joint work with Dr. George Androulakis (Mathematics, University of South Carolina).
The rather new field of quantum thermodynamics intends to derive thermodynamics from quantum mechanics, as well as to study thermodynamical behavior of quantum systems. It turns out that, indeed, thermalization can be obtained even for very small quantum systems due to the interaction with an appropriate environment. The consideration of an ensemble, as in statistical mechanics, is not necessary. However, the total system - consisting of system and environment - in quantum thermodynamics is usually considered to be closed. In particular, there exists no interaction with an external observer. Since quantum measurements typically influence the measured system, one may wonder which influence such an observation will have in the quantum thermodynamical setting. In this thesis, we study this influence of measurements in quantum thermodynamical systems. It turns out that various concepts known from statistical mechanics arise from such a "quantum thermodynamics under observation", although they do not have any meaning in the isolated quantum thermodynamical setting. The model discussed in the first part consists of a two-level system coupled to a large spin environment, the magnetization of which is measured periodically. This leads to quasi-classical trajectories for the system and - as in statistical mechanics - thermalization and temperature only have a meaning in terms of an ensemble average or a long-time average. Calculating these averages, we prove the ergodicity of the system. Interestingly, the entropy of the obtained attractor state depends on the time between the measurements and can be shown to be connected with the subjective lack of knowledge of the observer. In case of optimal measurements, the ensemble averaged state of the system under periodic measurements equals the state of the system in the quantum thermodynamical model without measurements. Introducing a detuning between system and environment, we find that the system can be prepared in almost arbitrary thermal states due to the periodic measurements. Even the creation of inversion becomes possible. As shown in numerical simulations, our results, which were analytically obtained for large environments, are even applicable to describe the behavior of the system coupled to small environments consisting of only a few spins. Besides measurements of the environment, we also study direct projective measurements of the system, as well as measurements with finite duration, obtaining that the dynamics of the system is almost independent of the concrete realization of the measurements. In the second part of the thesis, we discuss the meaning of temperature fluctuations in quantum thermodynamical systems. In statistical mechanics, there exist different approaches to the problem of temperature fluctuations, which lead to the well-known temperature fluctuation formula. The nature and operational accessibility of these fluctuations, however, remains rather unclear. We argue that according to quantum thermodynamics a system relaxes into a quasi-stationary thermal state and therefore the temperature does not fluctuate. However, since temperature is not an observable, it can only be determined indirectly. For modular systems, we show that the fluctuations of the temperature estimate obtained from a single energy measurement, indeed, are given by the temperature fluctuation formula derived in statistical mechanics, but only within a certain temperature range. The validity range of this formula increases with increasing size of the system. Thus, one can conclude that these "temperature fluctuations" can be interpreted as representing a fundamental limit for the instantaneous determination of temperature.
We extend classical coarse-grained entropy, commonly used in many branches of physics, to the quantum realm. We find two coarse grainings, one using measurements of local particle numbers and then total energy, and the second using local energy measurements, which lead to an entropy that is defined outside of equilibrium, is in accord with the thermodynamic entropy for equilibrium systems, and reaches the thermodynamic entropy in the long-time limit, even in genuinely isolated quantum systems. This answers the long-standing conceptual problem, as to which entropy is relevant for the formulation of the second thermodynamic law in closed quantum systems. This entropy could be in principle measured, especially now that experiments on such systems are becoming feasible.