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Journal of Applied Spectroscopy

Investigation of stark broadening of nonlinear three-level resonances on bound Ar II transitions

Valentina V. Lebedeva, Anatoly I. Odintsov, N A Glavatskikh, L. E. Grin', Artem G. Shulga

Published Sep 1, 1984• 0 citations
Publisher
DOI
10.1007/bf00659706

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We have developed a computational framework for the study of the effects of field fluctuations on strongly driven nonlinear transitions. Nonlinearity may stem from cither the strong coupling (saturation) of a resonant transition or its multiphoton character, or it may stem from both in the most general case. Our approach is based on a Monte Carlo simulation of stochastic field fluctuations, which allows maximum flexibility in the stochastic nature of the field and in the type of process that is studied. Here, we report on a more general problem than has previously been considered in the interaction of atoms with stochastic fields, namely, the three-photon resonant five- photon ionization of xenon, 3 + 2 photoionization of xenon has been the subject of a fair number of experimental investigations. It involves nonlinearity in with a bound-bound and a bound-free transition as well as an ac-Stark shift. Consequently, there are correlations among three fluctuating parameters: the three-photon Rabi frequency, the two-photon ionization rate, and the intensity-dependent ac-Stark shift, and it is these correlations that make the stochastic-field problem almost intractable to traditional methods of analysis.
An experimental investigation was made of the dispersion of the cubic susceptibility of sodium vapor in the region of two- and three-photon resonances with the 3s-4s and 3s-7p transitions. A compensation of the contributions to the nonlinear susceptibility of two- and three-photon resonances was observed. A theory was developed for the generation of the third harmonic in a nonmonochromatic field under resonance conditions and this theory was found to be in good agreement with the experimental results. A reduction in the effective susceptibility occurred in a strong field and this was due to saturation and Stark shift of the levels.
We have investigated the dynamic Stark effect in a J=0\ensuremath{\rightarrow}1\ensuremath{\rightarrow}0 three-level ladder system in an atomic beam of natural barium. An intense, actively stabilized cw dye laser was tuned to resonance between the upper two levels, and a similar laser was scanned through resonance with the transition connecting the lower two levels. Fluorescence arising from transitions out of the middle and upper levels was separately recorded as a function of probe laser frequency. This is the third and final paper in a series, of which the first two papers investigated theoretically and experimentally the ``weak-probe'' case, where the intensity of the probe laser was sufficiently low for the interaction between the atoms and the probe laser to be linear. In this paper we present an experimental investigation of the ``strong-probe'' case, where both lasers interact nonlinearly with the atoms, and we compare the results with the predictions of a theoretical model based on the optical Bloch equations.