Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physical Review A

Engineering the Hamiltonian of a trapped atom

R. L. de Matos Filho, W. Vogel

Published Sep 1, 1998• 85 citations
Publisher

Abstract

We propose the engineering of the vibronic coupling of a trapped atom by appropriate laser excitations. This allows one to substantially generalize the available class of Hamiltonians, which are suited for many applications.
DOI
10.1103/physreva.58.r1661

Related papers

Engineering the vibronic coupling of a trapped atom

R. L. de Matos Filho, W. Vogel

Summary form only given.The recent progress in trapping and cooling of atoms allowed us to prepare and to measure various nonclassical states of atomic motion. These methods make use of the laser-assisted vibronic interaction of the trapped atom. The interaction Hamiltonian for the laser being resonant to the kth vibrational sideband.

Conference on Lasers and Electro-Optics•Nov 27, 2002•0 citations

Reconstruction of the two-mode vibronic quantum state of a trapped atom

Sascha Wallentowitz, R. L. de Matos Filho, Shih-Chuan Gou +1 more

The European Physical Journal D•Jun 1, 1999•13 citations

Vibronic coupling limits the use of high-lying electronic states in complex molecules for laser cooling

Haowen Zhou, Paweł Wójcik, Guo‐Zhu Zhu +7 more

Laser cooling of large, complex molecules is a long-standing goal, instrumental for enabling new quantum technology and precision measurements. A primary consideration for the feasibility of laser cooling, which determines the efficiency and technical requirements of the process, is the number of excited-state decay pathways leading to vibrational excitations. Therefore, the assessment of the laser-cooling potential of a molecule begins with estimate of the vibrational branching ratios of the first few electronic excited states theoretically to find the optimum cooling scheme. Such calculations, typically done within the Born-Oppenheimer and harmonic approximations, have suggested that one leading candidate for large, polyatomic molecule laser cooling, alkaline earth phenoxides, can most efficiently be laser cooled via the third electronically excited ( C ̃ ) state. Here, we report the first detailed spectroscopic characterization of the C ̃ state in CaOPh and SrOPh. We find that nonadiabatic couplings between the A ̃ , B ̃ , and C ̃ states lead to substantial mixing, giving rise to vibronic states that enable additional decay pathways. Based on the intensity ratio of these extra decay channels, we estimate a nonadiabatic coupling strength of ∼ 0.1 cm − 1 . While this coupling strength is small, the large density of vibrational states available at photonic energy scales in a polyatomic molecule leads to significant mixing. Only the lowest excited state A ̃ is exempt from this coupling because it is highly separated from the ground state. Thus, this result is expected to be general for large molecules and implies that only the lowest electronic excited state should be considered when judging the suitability of a molecule for laser cooling.

arXiv:2510.22367•Physical Review Research•Nov 19, 2025•2 citations

A generalized Hamiltonian approach for designing simple single-photon-based optical quantum devices

R. Ramaseshan, Vimlesh Kumar, Adith Rajeev +4 more

The Journal of Supercomputing•Oct 1, 2025•1 citation

Realizing the Harper Hamiltonian and Spin-Orbit Coupling with Laser-Assisted Tunneling in an Optical Lattice

Colin J. Kennedy, Hirokazu Miyake, William Cody Burton +3 more

Bulletin of the American Physical Society•Jun 5, 2014•0 citations

Bichromatic state-insensitive trapping of caesium atoms

M.M. Metbulut, Ferruccio Renzoni

State-insensitive dipole trapping of multilevel atoms can be achieved by an appropriate choice of the wavelength of the trapping laser, so that the interaction with the different transitions results in equal AC Stark shifts for the ground and excited states of interest. However, this approach is severely limited by the availability of coherent sources at the required wavelength and of appropriate power. This work investigates state-insensitive trapping of caesium atoms for which the required wavelength of 935.6 nm is inconvenient in terms of experimental realization. Bichromatic state-insensitive trapping is proposed to overcome the lack of suitable laser sources. We first consider pairs of laser wavelengths in the ratio 1:2 and 1:3, as obtained via second- and third-harmonic generation. We found that the wavelength combinations 931.8–1863.6 nm and 927.5–2782.5 nm are suitable for state-insensitive trapping of caesium atoms. In addition, we examine bichromatic state-insensitive trapping produced by pairs of laser wavelengths corresponding to currently available high-power lasers. These wavelength pairs were found to be in the range of 585–588 nm and 623–629 for one laser and 1064–1080 nm for the other.

arXiv:1507.01190•Journal of Modern Optics•Aug 12, 2015•1 citation
Laser cooling of large, complex molecules is a long-standing goal, instrumental for enabling new quantum technology and precision measurements. A primary consideration for the feasibility of laser cooling, which determines the efficiency and technical requirements of the process, is the number of excited-state decay pathways leading to vibrational excitations. Therefore, the assessment of the laser-cooling potential of a molecule begins with estimate of the vibrational branching ratios of the first few electronic excited states theoretically to find the optimum cooling scheme. Such calculations, typically done within the Born-Oppenheimer and harmonic approximations, have suggested that one leading candidate for large, polyatomic molecule laser cooling, alkaline earth phenoxides, can most efficiently be laser cooled via the third electronically excited ( C ̃ ) state. Here, we report the first detailed spectroscopic characterization of the C ̃ state in CaOPh and SrOPh. We find that nonadiabatic couplings between the A ̃ , B ̃ , and C ̃ states lead to substantial mixing, giving rise to vibronic states that enable additional decay pathways. Based on the intensity ratio of these extra decay channels, we estimate a nonadiabatic coupling strength of ∼ 0.1 cm − 1 . While this coupling strength is small, the large density of vibrational states available at photonic energy scales in a polyatomic molecule leads to significant mixing. Only the lowest excited state A ̃ is exempt from this coupling because it is highly separated from the ground state. Thus, this result is expected to be general for large molecules and implies that only the lowest electronic excited state should be considered when judging the suitability of a molecule for laser cooling.
State-insensitive dipole trapping of multilevel atoms can be achieved by an appropriate choice of the wavelength of the trapping laser, so that the interaction with the different transitions results in equal AC Stark shifts for the ground and excited states of interest. However, this approach is severely limited by the availability of coherent sources at the required wavelength and of appropriate power. This work investigates state-insensitive trapping of caesium atoms for which the required wavelength of 935.6 nm is inconvenient in terms of experimental realization. Bichromatic state-insensitive trapping is proposed to overcome the lack of suitable laser sources. We first consider pairs of laser wavelengths in the ratio 1:2 and 1:3, as obtained via second- and third-harmonic generation. We found that the wavelength combinations 931.8–1863.6 nm and 927.5–2782.5 nm are suitable for state-insensitive trapping of caesium atoms. In addition, we examine bichromatic state-insensitive trapping produced by pairs of laser wavelengths corresponding to currently available high-power lasers. These wavelength pairs were found to be in the range of 585–588 nm and 623–629 for one laser and 1064–1080 nm for the other.