Canonical-ensemble approach to condensed boson systems

В. А. Алексеев

Condensation of the ideal Bose gas in a closed volume having the shape of a rectangular parallel-epiped of length L with a square base of side length l ( L ≫ l ) is theoretically studied within the framework of the Bose-Einstein statistics (grand canonical ensemble) and within the statistics of a canonical ensemble of bosons. Under the condition N ( l/L ) 4 ≪ l, where N is the total number of gas particles, dependence of the average number of particles in the condensate on the temperature T in both statistics is expressed as a function of the ratio t = T/T 1 , where T 1 is a certain characteristic temperature depending only on the longitudinal size L . Therefore, the condensation process exhibits a one-dimensional (1D) character. In the 1D regime, the average numbers of particles in condensates of the grand canonical and canonical ensembles coincide only in the limiting cases of t → 0 and t → ∞. The distribution function of the number of particles in the condensate of a canonical ensemble of bosons at t ≤1 has a resonance shape and qualitatively differs from the Bose-Einstein distribution. The former distribution begins to change in the region of t ∼ 1 and acquires the shape of the Bose-Einstein distribution for t ≫ 1. This transformation proceeds gradually that is, the 1D condensation process exhibits no features characteristic of the phase transition in a 3D system. For N ( l/L ) 4 ≫ 1, the process acquires a 3D character with respect to the average number of particles in the condensate, but the 1D character of the distribution function of the number of particles in the condensate of a canonical ensemble of bosons is retained at all N values.

Richard David Etters

Richard David Etters

D. K. Sunko

A simple description of Bose-Einstein condensation for non-interacting bosons is provided, based on an easily derived quantum correction to the canonical partition function. It is distinguished by the explicit appearance of the factor N !, which enhances the classical probability of finding bosons in the same state, and an elementary demonstration, that the transition should be sharper in temperature as the number of particles in the system increases. The reasoning is made explicit for the usual example of the ideal-gas dispersion.

Alfredo M. Ozorio de Almeida, Gert‐Ludwig Ingold, Olivier Brodier

Ming‐Tsung Lee

We present a canonical ensemble approach for weakly interacting composite boson systems, which is confined with a finite number of particles. Composite bosons, made of fermion pairs, correlate to each other through the Coulomb interaction associated with the fermion exchange, and are treated perturbatively. We study Bose–Einstein condensation of composite bosons according to the specific heat capacity, the composite-boson distribution function, and the condensate fraction up to the first-order perturbations. As an example, we investigate two-dimensional confined excitons. The study shows that the fermion exchange tends to assist the exciton condensation by raising the temperature. This stabilization of the exciton condensation owing to the fermion exchange is characterized by a small trough in the specific heat capacity profile. As the temperature becomes higher than the transition temperature, the effective Coulomb interaction reduces the thermal fluctuation of excitons, leading to a negative correction to the specific heat capacity in the normal phase. Weakly interacting excitons stay in a more stable thermodynamic state in comparison with ideal exciton gases.