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Journal of Mathematical Physics

The limiting dynamics of an imperfect Bose gas

Jochen Hertle

Published Nov 1, 1993• 0 citations
Publisher

Abstract

For an imperfect Bose gas consisting of massive particles and interacting through a long-range pair potential in a mean-field approximation, both in equilibrium and far from equilibrium, the dynamics are derived in the thermodynamic limit. This is done in the framework of the operator algebraic quantum theory. The limiting dynamics is formulated in the Schrödinger picture as a group of affine transformations of certain folia of physical states. Similar to the mean-field models for spin lattices, the algebra of quasilocal observables is not invariant under the Heisenberg dynamics in the GNS representation of general time invariant states. It is known that above critical density the infinite system exhibits condensation, and the condensate is characterized by the classical parameters density and phase. For these parameters a classical nonlinear equation of motion is derived.

DOI
10.1063/1.530344

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For an imperfect Bose gas consisting of massive particles and interacting through a long-range pair potential in a mean-field approximation, both in equilibrium and far from equilibrium, the dynamics are derived in the thermodynamic limit. This is done in the framework of the operator algebraic quantum theory. The limiting dynamics is formulated in the Schrödinger picture as a group of affine transformations of certain folia of physical states. Similar to the mean-field models for spin lattices, the algebra of quasilocal observables is not invariant under the Heisenberg dynamics in the GNS representation of general time invariant states. It is known that above critical density the infinite system exhibits condensation, and the condensate is characterized by the classical parameters density and phase. For these parameters a classical nonlinear equation of motion is derived.
Following the work of P. Bona [J. Math. Phys. 29, 2223 (1988)], a class of infinite mean-field quantum lattice systems is considered within the framework of algebraic quantum mechanics, and the following question is discussed: Which are the possible dynamical descriptions of the system, i.e., in which representations π of the system’s quasilocal C*-algebra 𝒜 do the local time evolutions converge in the thermodynamic limit to an automorphism group of a certain enlarged C*-algebra 𝒞π containing π(𝒜) and (some of) the classical observables of the system in π. To this end we associate a ‘‘classical state space’’ Eπ to any representation π (which is a subset of the phase-space E⊇RL defined by Bona for the largest possible representation), and show how it is characterized by the π-normal states, thereby obtaining a way to determine Eπ explicitly in many cases. The answer to the question posed then reads: The limiting (Heisenberg) dynamics exists in π on 𝒞π if and only if the set Eπ is invariant under the flow φQt on E which describes the time evolution of classical observables. Conversely, to any invariant, closed subset B of E, there exists a dynamical description of the quantum system with classical state space B.
We study a system consisting of a heavy quantum particle, called tracer particle, coupled to an ideal gas of light Bose particles, the ratio of masses of the tracer particle and a gas particle being proportional to the gas density. All particles have non-relativistic kinematics. The tracer particle is driven by an external potential and couples to the gas particles through a pair potential. We compare the quantum dynamics of this system to an effective dynamics given by a Newtonian equation of motion for the tracer particle coupled to a classical wave equation for the Bose gas. We quantify the closeness of these two dynamics as the mean-field limit is approached (gas density →∞\to\infty→∞). Our estimates allow us to interchange the thermodynamic with the mean-field limit.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2L^2L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01\textit{Full-text embargoed until: 2026-01-01}Full-text embargoed until: 2026-01-01
We study a system consisting of a heavy quantum particle, called tracer particle, coupled to an ideal gas of light Bose particles, the ratio of masses of the tracer particle and a gas particle being proportional to the gas density. All particles have non-relativistic kinematics. The tracer particle is driven by an external potential and couples to the gas particles through a pair potential. We compare the quantum dynamics of this system to an effective dynamics given by a Newtonian equation of motion for the tracer particle coupled to a classical wave equation for the Bose gas. We quantify the closeness of these two dynamics as the mean-field limit is approached (gas density →∞\to\infty→∞). Our estimates allow us to interchange the thermodynamic with the mean-field limit.
Adding a gauge symmetry breaking field $\ensuremath{-}\ensuremath{\nu}\sqrt{V}({a}_{0}+{a}_{0}^{*})$ to the Hamiltonian of some simplified models of an interacting Bose gas we compute the condensate density and the symmetry breaking order parameter in the limit of infinite volume and prove Bogoliubov's asymptotic hypothesis ${\mathrm{lim}}_{V\ensuremath{\rightarrow}\ensuremath{\infty}}⟨{a}_{0}⟩∕\sqrt{V}=\mathrm{sgn}\phantom{\rule{0.2em}{0ex}}\ensuremath{\nu}\phantom{\rule{0.2em}{0ex}}{\mathrm{lim}}_{V\ensuremath{\rightarrow}\ensuremath{\infty}}\sqrt{⟨{a}_{0}^{*}{a}_{0}⟩∕V}$ where the averages are taken in the ground state or in thermal equilibrium states. Letting $\ensuremath{\nu}$ tend to zero in this equation we obtain that Bose-Einstein condensation occurs if and only if the gauge symmetry is spontaneously broken. The simplification consists in dropping the off-diagonal terms in the momentum representation of the pair interaction. The models include the mean field and the imperfect (Huang-Yang-Luttinger) Bose gas. An implication of the result is that the compressibility sum rule cannot hold true in the ground state of the one-dimensional mean-field Bose gas. Our method is based on a resolution of the Hamiltonian into a family of single-mode (k=0)(\mathbf{k}=0)(k=0) Hamiltonians and on the analysis of the associated microcanonical ensembles.
We present the description of thermodynamic properties of a Bose gas by considering the hierarchy of equations satisfied by imaginary-time Green functions. In the case of an ideal gas the appearance of the off-diagonal long-range order (presence of condensate) is derived in a particularly simple way. The simplicity of the analysis persists at the level of the mean-field theory. Using Kac's scaling of the repulsive binary potential we then determine asymptotic corrections to the mean-field theory for thermodynamic states far from the region of the mean-field condensation. Our predictions are in accordance with rigorous results obtained previously, whereas the Hartree-Fock approximation is shown to neglect a whole class of equally important contributions.