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Foundations of Physics

Mathematical theory of radiation

Volker Bach, Jürg Martin Fröhlich, Israel Michael Sigal

Published Feb 1, 1997• 4 citations
Publisher
DOI
10.1007/bf02550452

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In this chapter, we present the basic principles of the quantum mechanics of particle systems from a modern mathematical perspective. The proper study of quantum mechanics brings together several interesting mathematical ideas, ranging from group representations to the spectral theory of unbounded self-adjoint operators in Hilbert spaces and the theory of C * algebras. The facts from analysis of operators in Hilbert spaces and C * algebras needed in this chapter are presented in detail in the appendices at the end of the book. More on the mathematical foundations of quantum mechanics can be found in the books by L. Fadeev and O. Yakubovskii [FY], G. Mackey [M], and F. Strocchi [Str] listed in the bibliography. The birth of quantum theory The origins of quantum theory can be traced back to M. Planck's study, published in 1900, of so-called black-body radiation. It is well known that matter glows when heated, going from red-hot to white-hot as the temperature rises. The color (or frequency of radiation) of the radiating body is independent of its surface, and for a black body it is found to be a function of temperature alone. The behavior of the radiation energy as a function of temperature seemed quite different at high temperatures and low temperatures. In a desperate attempt to fit these different behaviors into a single law, Planck introduced the hypothesis that energy was not continuous, but came in discrete packets or quanta . At the beginning of the twentieth century, a number of experiments pointed to a breakdown of the laws of classical mechanics at very small (subatomic) scales.
Radiative transitions are quantum-state transitions in matter quantum systems (such as atoms, ions, and molecules) caused by their interaction with the electromagnetic field, and accompanied by the emission or absorption of photons.Their theoretical description involves physical theories including quantum mechanics and quantum electrodynamics, as well as mathematical tools such as spherical tensors and group theory.Focusing on radiative transitions of doped ions in solids, this paper summarizes earlier related theories and aims to concisely introduce fundamental theories and mathematical expressions while maintaining rigor, and to clearly describe the underlying physical pictures and mechanisms.The topics covered include atomic quantum states, the quantized electromagnetic field, multipole radiative transitions and selection rules, stimulated absorption, stimulated emission and spontaneous emission, transition probability and excited-state lifetimes.The article also discusses f-f and 4f-5d transitions of rare-earth ions and dd transitions of transition-metal ions, involving Judd -Ofelt theory, crystal-field theory, electronvibration coupling, and the Dorenbos model, as well as statistical analysis, machine learning, and firstprinciples methods.This work may provide a theoretical reference for the study of rare-earth-and transition-metaldoped luminescent materials.Keywords: radiative transition; theory; physical picture; f-f transition; d-d transition; 4f-5d transition 文章编号: 1000-7032(XXXX)XX