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Journal of the Physical Society of Japan

Second Quantization Operators for Spin Operators

Takehiko Oguchi

Published Aug 15, 1992• 0 citations
Publisher

Abstract

Based on the commutation relations of spin operators, the second quantization operators derived by Holstein-Primakoff and Dyson and its Hermitean conjugate operators are obtained. The matrix representations for a scalar product of two spins by the Dyson's operators are not in agreement with the rigorous one except for the case of spin 1/2, although their eigenvalues are correct.

DOI
10.1143/jpsj.61.2677

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Based on the commutation relations of spin operators, the second quantization operators derived by Holstein-Primakoff and Dyson and its Hermitean conjugate operators are obtained. The matrix representations for a scalar product of two spins by the Dyson's operators are not in agreement with the rigorous one except for the case of spin 1/2, although their eigenvalues are correct.
The formalism of the second quantization is developed entirely within the framework of the Dirac-Jordan representation theory. The equivalence of this formalism and the methods of ordinary coordinate-spin space is shown, and the equations of "connection" are fully developed. It is shown that the "creation" and "annihilation" operators, and indeed all operators which do not commute with the quantized Hamiltonian and hence whose representatives cannot be explicitly given in a configuration space of a fixed number of dimensions are easily treated in terms of the general representation theory and arise quite naturally. Both types of statistics are considered, and the Fock-Dirac density matrix and self-consistent field are treated as a simple illustration.
Second-quantized operators are derived algebraically from first-quantized counterparts, thus providing an alternative to all existing methods, most of which rely upon demonstrating the equivalence of matrix elements of the two operators. This derivation establishes an operator identity between a second-quantized operator and a first-quantized operator whose domain of definition is extended explicitly from an N-particle Hilbert space to Fock space. The existence of such an identity eliminates the need to address the issue of the representations used for the two operators, which often obscures the underlying simple relationship between them.
These lecture notes originate from a one-semester course on the mathematical foundations of second quantization, first given at the Department of Physics of the Friedrich-Alexander-Universität Erlangen-Nürnberg in the Winter Semester 2025/26 to a mixed audience of physics and mathematics students. Their guiding thread is a class of physical models: spin-boson models, describing a two-level system coupled to a boson field. After summarizing the necessary background on unbounded operators, up to the Kato-Rellich and KLMN theorems, and developing direct sums and tensor products of Hilbert spaces and of unbounded operators, we treat single-mode boson fields, constructing the ladder and number operators and characterizing their domains, before moving to Fock spaces, second quantization, bosonic and fermionic annihilation and creation operators, and the canonical (anti)commutation relations. Throughout, spin-boson models provide both the motivation and the test bench for the formalism: we rigorously establish their self-adjointness, solve the pure dephasing and Jaynes-Cummings models explicitly, deriving their spectra and the qubit channels they induce, show how their multimode counterparts display irreversible decoherence and decay, and, in an appendix, prove the rotating-wave approximation for the quantum Rabi model with an explicit error bound. Finally, we use the KLMN theorem to construct spin-boson models with non-normalizable form factors, and briefly discuss stronger ultraviolet divergences and the need for renormalization. Exercises with full solutions are included.
The relativistic second quantization of free bosons is extended to fermions. To know how relativistic creation and annihilation operators operate on bra and ket vectors, it is necessary to have a relativistic scalar product which in the case of free particles can be constructed. For particles interacting with each other or capable of emitting and absorbing particles of the same kind, it is pointed out that adequate wave equations for an indefinite number of particles each taking a separate time coordinate have not yet been found and so no scalar product can be found. Thus creation and annihilation operators can be defined only by their operation on a bra vector or a ket vector but not by both. With the help of these, the relativistic wave equations referred to above are proposed and their consistency conditions studied. For the particular case of scalar particles, an illustration is given that such a theory may admit certain expressions as probabilities.
A review of the second quantization formulation of quantum mechanics is given based on the idea of a graded Hilbert space whose elements are represented by column matrices containing zero, one, two, ···, particle functions. The creation and annihilation operators are defined in terms of intuitive ideas about adding a particle to or removing a particle from the system. The (anti)commutation relations are shown to follow from the (anti)symmetry of the wavefunctions. The field operators which describe the creation or annihilation of a particle at a point are then obtained and their properties discussed. These operators are then used to express general operators in second quantization. Finally, a basis is introduced and the equations of occupation-number space are obtained.
Second quantization in nonrelativistic quantum mechanics is given in a simplified way using eigenstates of the number operator. The field creation operator is shown to be the operator which adds a particle with a delta-function wave function to the system, while the field annihilation operator removes a particle with a delta-function wave function from the system. The field creation operator is proved to be the Hermitian conjugate of the annihilation operator. The commutation (anticommutation) relations for boson (fermion) field operators are proved from the symmetry (antisymmetry) of the many-particle wave function. The second quantized form of one- and two-particle operators is obtained from their form in wave mechanics using the definition of the field creation and annihilation operators.