Physical Review A
Atomic density and light intensity dependences of the Rb2 molecule formation rate constant in a magneto-optical trap
Anderson R. L. Caires, Valter Aragão do Nascimento, D. C. J. Rezende, Vanderlei Salvador Bagnato, Luís Gustavo Marcassa
Abstract
In this paper, we report the measurement of molecular formation rate constant of ${\mathrm{Rb}}_{2}$ directly in a magneto-optical trap (MOT). The ground state molecules are detected by two-photon ionization, resonantly enhanced through the intermediate ${a}^{3}{\ensuremath{\Sigma}}_{u}^{+}\ensuremath{\rightarrow}{2}^{3}{\ensuremath{\Pi}}_{g}$ molecular band. We have measured the rate constant as a function of atomic density to conclude that the molecules ${\mathrm{Rb}}_{2}$ are formed in the MOT by a photoassociation process caused by the trapping laser beams. We also measured the rate constant as a function of the trapping laser intensity. The results here presented are of importance to future experiments involving trapping of cold molecules.