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ChemPhysChem

Bose–Einstein Condensation in a Dilute Gas: The First 70 Years and some Recent Experiments (Nobel Lecture)

Eric Cornell, Carl Wieman

Published Jun 17, 2002• 26 citations
Publisher

Abstract

Bose-Einstein condensates of dilute gases offer a rich field to study fundamental quantum-mechanical processes, manipulation of the speed at which light propogates, observation of atomic pair-formation and superfluidity, or even simulating white dwarf stars. Still more radical applications are on the horizon. However, their initial creation was a masterpiece of experimental physics. After an initial process of laser cooling (which itself won its developers the 1997 Nobel Prize), atoms in a magnetic-optical trap must be safely transferred into a purely magnetic trap, where the condensation process begins at 170 nK and 20 nK a pure condensate of 2000 atoms could be created. More astonishingly, Wieman and Cornell showed these low temperatures could be achieved in "bench scale" equipment rather than the massive pieces normally demanded by cryoscience. For their 1995 discovery of this new state of matter, they were awarded the 2001 Nobel Prize in Physics.

DOI
10.1002/1439-7641(20020617)3:6<476::aid-cphc476>3.0.co;2-v

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Bose-Einstein condensation, or BEC, has a long and rich history dating from the early 1920s. In this article we will trace briefly over this history and some of the developments in physics that made possible our successful pursuit of BEC in a gas. We will then discuss what was involved in this quest. In this discussion we will go beyond the usual technical description to try and address certain questions that we now hear frequently, but are not covered in our past research papers. These are questions along the lines of: How did you get the idea and decide to pursue it? Did you know it was going to work? How long did it take you and why? We will review some our favorites from among the experiments we have carried out with BEC. There will then be a brief encore on why we are optimistic that BEC can be created with nearly any species of magnetically trappable atom. Throughout this article we will try to explain what makes BEC in a dilute gas so interesting, unique, and experimentally ${\mathrm{challenging}.}^{1}$

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The experimental realization in 1995 of Bose–Einstein condensation in dilute atomic gases marked the beginning of a very rapid development in the study of quantum gases. The initial experiments were performed on vapours of rubidium, sodium, and lithium. So far, the atoms 1 H, 7 Li, 23 Na, 39 K, 41 K, 52 Cr, 85 Rb, 87 Rb, 133 Cs, 170 Yb, 174 Yb and 4 He * (the helium atom in an excited state) have been demonstrated to undergo Bose–Einstein condensation. In related developments, atomic Fermi gases have been cooled to well below the degeneracy temperature, and a superfluid state with correlated pairs of fermions has been observed. Also molecules consisting of pairs of fermionic atoms such as 6 Li or 40 K have been observed to undergo Bose–Einstein condensation. Atoms have been put into optical lattices, thereby allowing the study of many-body systems that are realizations of models used in condensed matter physics. Although the gases are very dilute, the atoms can be made to interact strongly, thus providing new challenges for the description of strongly correlated many-body systems. In a period of less than ten years the study of dilute quantum gases has changed from an esoteric topic to an integral part of contemporary physics, with strong ties to molecular, atomic, subatomic and condensed matter physics. The dilute quantum gases differ from ordinary gases, liquids and solids in a number of ways, as we shall now illustrate by giving values of physical quantities.

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Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in $L^2$-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. $\textit{Full-text embargoed until: 2026-01-01}$

•Dec 9, 2025•0 citations
Bose-Einstein condensates of dilute gases offer a rich field to study fundamental quantum-mechanical processes, manipulation of the speed at which light propogates, observation of atomic pair-formation and superfluidity, or even simulating white dwarf stars. Still more radical applications are on the horizon. However, their initial creation was a masterpiece of experimental physics. After an initial process of laser cooling (which itself won its developers the 1997 Nobel Prize), atoms in a magnetic-optical trap must be safely transferred into a purely magnetic trap, where the condensation process begins at 170 nK and 20 nK a pure condensate of 2000 atoms could be created. More astonishingly, Wieman and Cornell showed these low temperatures could be achieved in "bench scale" equipment rather than the massive pieces normally demanded by cryoscience. For their 1995 discovery of this new state of matter, they were awarded the 2001 Nobel Prize in Physics.
Bose-Einstein condensation (BEC), first predicted by Einstein in 1925, has been realized experimentally in 1995 in alkali gases. The award of the 2001 Nobel Prize in Physics to E. Cornell, C. Wieman, and W. Ketterle acknowledged the importance of the achievement. In this new state of matter, which is very dilute and at very low temperature, a macroscopic fraction of the atoms occupy the same quantum level, and behave as a coherent matter wave similar to the coherent light wave produced by a laser. In the dilute limit, the condensate is well described by a mean-field theory and a macroscopic wave function. The properties of these gaseous quantum fluids have been the focus of international interest in physics, both experimentally and theoretically, and many applications are envisioned. An important issue is the relationship between BEC and superfluidity, in particular through the existence of vortices. The focus of this book is the mathematical properties of vortices, observed in very recent experiments on rotating condensates These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
WHEN the 2001 Nobel Prize for Physics was awarded to Eric Cornell and Carl Wieman from JILA in Boulder, Colorado, and to Wolfgang Ketterle from the Massachusetts Institute of Technology, they were recognized for creating and studying Bose–Einstein condensates – dilute gases of atoms that are all in the same quantum state. Their remarkable achievement enabled "quantum gases" to be studied experimentally for the first time, and jump-started new sub-fields of research, including gaseous superfluidity, atom lasers and matter–wave optics.
Bose-Einstein condensation, or BEC, has a long and rich history dating from the early 1920s. In this article we will trace briefly over this history and some of the developments in physics that made possible our successful pursuit of BEC in a gas. We will then discuss what was involved in this quest. In this discussion we will go beyond the usual technical description to try and address certain questions that we now hear frequently, but are not covered in our past research papers. These are questions along the lines of: How did you get the idea and decide to pursue it? Did you know it was going to work? How long did it take you and why? We will review some our favorites from among the experiments we have carried out with BEC. There will then be a brief encore on why we are optimistic that BEC can be created with nearly any species of magnetically trappable atom. Throughout this article we will try to explain what makes BEC in a dilute gas so interesting, unique, and experimentally challenging.1{\mathrm{challenging}.}^{1}challenging.1
The experimental realization in 1995 of Bose–Einstein condensation in dilute atomic gases marked the beginning of a very rapid development in the study of quantum gases. The initial experiments were performed on vapours of rubidium, sodium, and lithium. So far, the atoms 1 H, 7 Li, 23 Na, 39 K, 41 K, 52 Cr, 85 Rb, 87 Rb, 133 Cs, 170 Yb, 174 Yb and 4 He * (the helium atom in an excited state) have been demonstrated to undergo Bose–Einstein condensation. In related developments, atomic Fermi gases have been cooled to well below the degeneracy temperature, and a superfluid state with correlated pairs of fermions has been observed. Also molecules consisting of pairs of fermionic atoms such as 6 Li or 40 K have been observed to undergo Bose–Einstein condensation. Atoms have been put into optical lattices, thereby allowing the study of many-body systems that are realizations of models used in condensed matter physics. Although the gases are very dilute, the atoms can be made to interact strongly, thus providing new challenges for the description of strongly correlated many-body systems. In a period of less than ten years the study of dilute quantum gases has changed from an esoteric topic to an integral part of contemporary physics, with strong ties to molecular, atomic, subatomic and condensed matter physics. The dilute quantum gases differ from ordinary gases, liquids and solids in a number of ways, as we shall now illustrate by giving values of physical quantities.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2L^2L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01\textit{Full-text embargoed until: 2026-01-01}Full-text embargoed until: 2026-01-01