Pulse Protocols for Quantum Computing with Electron Spins as Qubits

YIN-ZHONG WU, Wei-Min Zhang, Chopin Soo

Kazunobu Sato, Shigeaki Nakazawa, Robabeh Rahimi +15 more

Pulse-based Electron–Nuclear and ELectron–electron DOuble Resonance (ENDOR/ELDOR) techniques have been applied to molecular spins in order to implement ensemble electron spin-qubit based quantum computers/computing (QC) and quantum information processing (QIP) in the solid state. Pulsed ENDOR-based QC/QIP experiments for super dense coding (SDC) have for the first time been carried out by the use of molecular electron- and nuclear-spin entities such as the stable malonyl radical as matter spin-qubits. The spin-qubit manipulation technology for quantum gate operations in this work is based on the time-proportional-phase-increment (TPPI) technique, enabling us to distinguish between the phases of spin-qubit based entangled states. The TPPI technique, as firstly applied by Mehring et al. (M. Mehring, J. Mende and W. Scherer, Phys. Rev. Lett., 2003, 90, 153001), has illustrated the establishment of quantum entanglement between electron- and nuclear-spin states and mutual interconversion between the electron–nuclear Bell states. The electron-spin 4π-periodicity in phase shows up in the QC/QIP experiments, explicitly and experimentally illustrating the electron-spin spinor nature for the first time. Tripartite QC experiments have been made, showing the occurrence of separable states. Also, the development of novel electron-spin technology to manipulate multi-electron spin-qubits is described. In this work, the pulsed coherent-dual ELDOR for QC/QIP has for the first time been implemented by invoking a novel microwave dual phase-rotation technique. Thus, applications of the coherent-dual ELDOR to molecular electron spin-qubit systems are also discussed, emphasising designing the molecular two electron-qubit systems appropriate for QC/QIP. g- and/or hyperfine A-tensor engineering approaches give us the two- and multi-electron-qubit systems, which have been a materials challenge to implement matter spin-qubit based QC/QIP. The targeted matter spin-qubits can be used to facilitate selective resonant microwave excitations achieved by the pulsed ELDOR technique. In addition to DiVincenzo's five criteria, general requisites for scalable electron spin-qubit systems as 1D periodic robust spin structures are described. According to the requisites, double- or triple-stranded helicates embedding open-shell metal cations are proposed instead of organic molecular spin-qubits.

Klaus Mølmer, Arzhang Ardavan, Andrew D. Briggs +4 more

G. P. Berman, Brown, G. W., M. E. Hawley +2 more

We describe how to implement quantum logic operations in a silicon-based quantum computer with phosphorus atoms serving as qubits. The information is stored in the states of nuclear spins and the conditional logic operations are implemented through the electron spins using nuclear-electron hyperfine and electron-electron exchange interactions. The electrons in our computer should stay coherent only during implementation of one Control-Not gate. The exchange interaction is constant and selective excitations are provided by a magnetic field gradient. The quantum logic operations are implemented by rectangular radio-frequency pulses. This architecture is scalable and does not require manufacturing nanoscale electronic gates. As shown in this paper parameters of a quantum protocol can be derived analytically even for a computer with a large number of qubits using our perturbation approach. We present the protocol for initialization of the nuclear spins and the protocol for creation of entanglement. All analytical results are tested numerically using a two-qubit system.

Fattah Sakuldee, Mehdi Abdi

Due to its localized nature and controllability, the negatively charged boron vacancy centers (V$_\text{B}^-$) in hexagonal boron nitride (hBN) are a promising spin platform for accessing its neighboring nuclei with potential for performing quantum computational tasks. However, the methods of utilizing and manipulating the nuclear spins are still lacking. In this work, we propose a protocol for the preparation of single- and multi-qubit gates on the nuclear spins, utilizing the electron spin as an auxiliary qubit. By applying a background magnetic field and a multi-tone continuous drive, we show that the electron spin coupling to the nuclei can be efficiently engineered. This allows for suppressing the undesired electron-nuclear interactions through the Hahn echo pulse sequence. The target gates are then implemented by employing proper RF drives. Our numerical results for realistic parameters show gate fidelities as high as $99\%$ for single-qubit and $95\%$ for multi-qubit gates. With the gate execution durations being less than $300$ ns, our protocol evades electron spin decoherence effects. Therefore, our scheme sets the stage for the practical application of V$_\text{B}^-$ in hBN for quantum computation purposes.

G. P. Berman, Geoffrey W. Brown, M. E. Hawley +2 more

We describe how to implement quantum logic operations in a silicon-based quantum computer with phosphorus atoms serving as qubits. The information is stored in the states of nuclear spins and the conditional logic operations are implemented through the electron spins using nuclear–electron hyperfine and electron–electron exchange interactions. The electrons in our computer should stay coherent only during implementation of one Controlled-NOT gate. The exchange interaction is constant, and selective excitations are provided by a magnetic field gradient. The quantum logic operations are implemented by rectangular radio-frequency pulses. This architecture is scalable and does not require manufacturing nanoscale electronic gates. As shown in this paper, parameters of a quantum protocol can be derived analytically even for a computer with a large number of qubits using our perturbation approach. We present the protocol for initialization of the nuclear spins and the protocol for creation of entanglement. All analytical results are tested numerically using a two-qubit system.