Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Accessible information in molecular-scale systems: physical limits at small sampling volumes (Invited Paper)

Neal G. Anderson

Published May 23, 2005• 1 citation
Publisher

Abstract

We consider fundamental limits on information acquisition from localized regions of molecular-scale electronic systems. Our approach is based on a quantitative measure we call the volume accessible information, defined as the (Shannon) mutual information associated with the best possible quantum measurement that can access a system through a specified readout volume. Using results and techniques from quantum measurement theory, we obtain a general expression for an upper bound on the volume accessible information that depends only on the manner in which information is encoded in electron states and specification of the readout volume. An illustrative study of a model tight-binding system indeed reveals that the volume accessible information is sharply reduced at small sampling volumes, where the state distinguishability required for reliable information extraction is diminished.

DOI
10.1117/12.609459

Related papers

Accessible information from molecular-scale volumes in electronic systems: Fundamental physical limits

Neal G. Anderson

We consider fundamental limits on accessible information from molecular-scale volumes in electronic systems. Our approach is based on a quantitative measure—the volume accessible information—which we define as the Shannon mutual information associated with the best possible quantum measurement that can access a system through a specified readout volume. Specifically, we obtain a general expression for an upper bound on the volume accessible information that depends only on the manner in which information is encoded in electron states and specification of the readout volume. This bound is obtained within a tight-binding framework for simplicity and compatibility with atomistic descriptions of molecular-scale electronic systems. As an illustration, we study the volume accessible information bound for measurements accessing finite segments of long polyparaphenylene (PPP) molecules with binary information encoded in the states of electrons in the lowest unoccupied molecular orbital band. Evaluation of this bound reveals severe limits on the amount of information accessible from measurements on short PPP chain segments, where the state distinguishability required for reliable information extraction is diminished.

Journal of Applied Physics•Feb 15, 2006•5 citations

Information Acquisition at the Nanoscale: Fundamental Considerations

Neal G. Anderson

Reliable extraction of information from a physical system requires some combination of redundancy, state distinguishable, and access time. This has obvious implications for any prospective nanoelectronic technology that would require rapid extraction of information from small numbers of electrons through nanoscale access volumes. In this paper, we explore this issue through consideration of fundamental physical limits on information acquisition from electronic systems. We outline our general approach, obtain the required accessible information bounds for multipartitie information-bearing systems, and present model calculations that illustrate loss of accessible information at nanoscale access volumes and low particle densities in a simple tight-binding molecular wire. This approach, fully developed, could provide both useful physical insight and practical tools for the assessment of emerging electronic information processing technologies.

IEEE Transactions on Nanotechnology•Sep 1, 2008•4 citations

Tight bounds on accessible information and informational power

Michele Dall’Arno, Francesco Buscemi, Masanao Ozawa

The accessible information quantifies the amount of classical information that can be extracted from an ensemble of quantum states. Analogously, the informational power quantifies the amount of classical information that can be extracted by a quantum measurement. For both quantities, we provide upper and lower bounds that depend only on the dimension of the system, and we prove their tightness. In the case of symmetric informationally complete (SIC) ensembles and measurements, stronger bounds are provided and their tightness proved for qubits and qutrits. From our upper bounds, we notice, perhaps surprisingly, that the statistics generated by SIC ensembles or measurements in arbitrary dimension, though optimal for tomographic purposes, in fact never contain more than just one bit of information, the rest being constituted by completely random bits. On the other hand, from our lower bounds, we obtain an explicit strategy beating the so-called pretty-good one for the extraction of mutual information in the case of SIC ensembles and measurements.

arXiv:1402.0602•Journal of Physics A Mathematical and Theoretical•May 20, 2014•18 citations

Distinguishability and Accessible Information in Quantum Theory

Christopher A. Fuchs

This document focuses on translating various information-theoretic measures of distinguishability for probability distributions into measures of distin- guishability for quantum states. These measures should have important appli- cations in quantum cryptography and quantum computation theory. The results reported include the following. An exact expression for the quantum fidelity between two mixed states is derived. The optimal measurement that gives rise to it is studied in detail. Several upper and lower bounds on the quantum mutual information are derived via similar techniques and compared to each other. Of note is a simple derivation of the important upper bound first proved by Holevo and an explicit expression for another (tighter) upper bound that appears implicitly in the same derivation. Several upper and lower bounds to the quan- tum Kullback relative information are derived. The measures developed are also applied to ferreting out the extent to which quantum systems must be disturbed by information gathering measurements. This is tackled in two ways. The first is in setting up a general formalism for describing the tradeoff between inference and disturbance. The main point of this is that it gives a way of expressing the problem so that it appears as algebraic as that of the problem of finding quantum distinguishability measures. The second result on this theme is a theorem that prohibits "broadcasting" an unknown (mixed) quantum state. That is to say, there is no way to replicate an unknown quantum state onto two separate quantum systems when each system is considered without regard to the other. This includes the possibility of correlation or quantum entanglement between the systems. This result is a significant extension and generalization of the standard "no-cloning" theorem for pure states.

arXiv:quant-ph/9601020•Jan 23, 1996•196 citations

Observer-Capacity Limits on Information Extraction During Quantum Decoherence

Samuel Richards

Preprint: This paper derives quantitative bounds on measurement windows for finite-capacity observers extracting information from decohering quantum systems, extending standard decoherence theory to realistic experimental constraints. Main Result: For Gaussian-Markovian decoherence with exponential information decay I(t) = I₀ exp(-2Γt), bounded-capacity observers lose access to system distinctions when mutual information drops below detection threshold ε, yielding measurement window: τ_c = (1/2Γ) log(α C_A / ε) where Γ is decoherence rate [s⁻¹], C_A is observer capacity [bits] defined via Shannon formula (bandwidth × log₂(SNR) × integration time), ε is detection threshold [bits], and α ~ 0.1-1 is a model-dependent constant from spectral decomposition of environmental information. This establishes logarithmic capacity-scaling: doubling detector quality extends measurement windows by only ~0.35/Γ seconds, implying diminishing returns from capacity improvements. Experimental Predictions: For state-of-the-art circuit QED (superconducting transmon qubits, T₁ = 100 μs, bandwidth Δf = 10 MHz, SNR = 10), the framework predicts τ_c ~ 4-10 μs. Varying bandwidth from 1-30 MHz (capacity C_A ∈ [3, 90] bits) produces measurable Δτ_c ≈ 1.7 μs variation (5-10% of coherence time). Five experimental tests discriminate capacity-scaling from standard decoherence: ∙ Tests 1-3: Verify logarithmic capacity-scaling, inverse rate-dependence, threshold-dependence ∙ Test 4: Multi-observer non-redundancy (at most one narrowband detector succeeds) ∙ Test 5: Capacity-dependent redundancy buildup (primary discriminating signature) Key Contributions: ∙ First quantitative analysis of Zurek's pre-objective phase under explicit finite-resource constraints ∙ Capacity-scaling law connecting Shannon information theory to quantum measurement dynamics ∙ Operational definitions ensuring falsifiability (capacity, threshold, mutual information defined via measurement protocols) ∙ Concrete numerical predictions for three platforms (circuit QED, spin qubits, optomechanics) with resource estimates ∙ Design principle: environmental shielding (linear benefit in τ_c) outperforms detector improvement (logarithmic benefit) when both options available Technical Approach: The bound follows from threshold-crossing analysis of exponential decay with capacity-limited initial information I₀ = α C_A, justified via spectral decomposition of environmental information under flat-spectrum approximation for narrowband observation. All parameters (Γ, C_A, ε) are operationally defined and independently measurable, avoiding circularity. Extensions to non-Markovian dynamics (memory kernels), scrambling systems (black holes, many-body chaos), and non-Gaussian noise (Lévy flights, 1/f noise) are discussed with conjectured scaling laws. Scope: The bound applies specifically to Gaussian-Markovian systems (harmonic oscillators, qubits in dispersive limit, weak continuous measurement with memoryless baths). Circuit QED provides optimal testbed due to tunable Purcell filters (bandwidth control), high coherence times (T₁ > 300 μs achieved), and multiplexed readout infrastructure (5+ independent detectors demonstrated). Validity requires α C_A > ε (initial information exceeds threshold); domain violations occur when capacity too small, threshold too high, or coupling too weak. Relation to Prior Work: Zurek's Quantum Darwinism (2003-2009) explains asymptotic objectivity emergence through environmental redundancy but assumes unbounded observers (C_A → ∞, t → ∞). This work analyzes the complementary finite-resource regime (C_A < ∞, t ~ τ_c), providing first capacity-parameterized bound on pre-objective phase duration. Framework is interpretation-neutral—compatible with Copenhagen, Many-Worlds, Bohmian mechanics, and relational quantum mechanics. Philosophical implications (process ontology, observer-dependent reality, impermanence) are explored but clearly separated from testable predictions. Methods: Open quantum systems theory, Shannon information theory, operational quantum measurement, circuit QED experimental physics, numerical prediction for realistic parameters. Content: Complete 90-page manuscript with axiomatic framework (§2), narrowband observation model (§3), main theorem with proof (§4), numerical predictions (§5), five experimental falsification tests (§6), detailed Quantum Darwinism comparison (§7), extensions and limitations (§8), interpretive options (§9), and honest assessment (§10). Includes 77 references and operational definitions for all information-theoretic quantities. Target Audience: Quantum foundations researchers, experimental quantum physicists (circuit QED, trapped ions, quantum dots), quantum information theorists, philosophers of physics interested in measurement and objectivity.

•Jan 22, 2026•0 citations

Entanglement and Mutual Information in Molecules: Comparing Localized and Delocalized Orbitals

Lorenzo Tenti, Stefan Peeters, Emmanuel Giner +1 more

The use of the mutual information (MI) as a measure of the entanglement in quantum systems has gained a consensus in recent years, even if there is an ongoing effort to distinguish the classical and quantum contributions contained therein. This quantity has been first introduced in condensed matter physics, in particular, in studies based on the density matrix renormalization group method. This method has been successfully adapted to quantum chemistry problems, opening the way to compute MI also in molecular systems. A key aspect of this quantity is its dependence on the one-electron (orbital) basis set, even for wave functions that are invariant under unitary transformation of the orbitals. In this work, we investigate the role of the orbital basis set (delocalized or localized, following different strategies) for wave functions expressed as linear combinations of Slater determinants and we give the analytic expression for the MI for a few special cases. This study aims to improve the knowledge of the relationship between the characteristics of the chemical bond (considering a few paradigmatic molecules, H 2, F 2, N 2, and short linear polyenes) and the properties of interest in the field of quantum information theory.

Journal of Chemical Theory and Computation•Dec 4, 2024•4 citations
We consider fundamental limits on information acquisition from localized regions of molecular-scale electronic systems. Our approach is based on a quantitative measure we call the volume accessible information, defined as the (Shannon) mutual information associated with the best possible quantum measurement that can access a system through a specified readout volume. Using results and techniques from quantum measurement theory, we obtain a general expression for an upper bound on the volume accessible information that depends only on the manner in which information is encoded in electron states and specification of the readout volume. An illustrative study of a model tight-binding system indeed reveals that the volume accessible information is sharply reduced at small sampling volumes, where the state distinguishability required for reliable information extraction is diminished.
We consider fundamental limits on accessible information from molecular-scale volumes in electronic systems. Our approach is based on a quantitative measure—the volume accessible information—which we define as the Shannon mutual information associated with the best possible quantum measurement that can access a system through a specified readout volume. Specifically, we obtain a general expression for an upper bound on the volume accessible information that depends only on the manner in which information is encoded in electron states and specification of the readout volume. This bound is obtained within a tight-binding framework for simplicity and compatibility with atomistic descriptions of molecular-scale electronic systems. As an illustration, we study the volume accessible information bound for measurements accessing finite segments of long polyparaphenylene (PPP) molecules with binary information encoded in the states of electrons in the lowest unoccupied molecular orbital band. Evaluation of this bound reveals severe limits on the amount of information accessible from measurements on short PPP chain segments, where the state distinguishability required for reliable information extraction is diminished.
Reliable extraction of information from a physical system requires some combination of redundancy, state distinguishable, and access time. This has obvious implications for any prospective nanoelectronic technology that would require rapid extraction of information from small numbers of electrons through nanoscale access volumes. In this paper, we explore this issue through consideration of fundamental physical limits on information acquisition from electronic systems. We outline our general approach, obtain the required accessible information bounds for multipartitie information-bearing systems, and present model calculations that illustrate loss of accessible information at nanoscale access volumes and low particle densities in a simple tight-binding molecular wire. This approach, fully developed, could provide both useful physical insight and practical tools for the assessment of emerging electronic information processing technologies.
The accessible information quantifies the amount of classical information that can be extracted from an ensemble of quantum states. Analogously, the informational power quantifies the amount of classical information that can be extracted by a quantum measurement. For both quantities, we provide upper and lower bounds that depend only on the dimension of the system, and we prove their tightness. In the case of symmetric informationally complete (SIC) ensembles and measurements, stronger bounds are provided and their tightness proved for qubits and qutrits. From our upper bounds, we notice, perhaps surprisingly, that the statistics generated by SIC ensembles or measurements in arbitrary dimension, though optimal for tomographic purposes, in fact never contain more than just one bit of information, the rest being constituted by completely random bits. On the other hand, from our lower bounds, we obtain an explicit strategy beating the so-called pretty-good one for the extraction of mutual information in the case of SIC ensembles and measurements.
This document focuses on translating various information-theoretic measures of distinguishability for probability distributions into measures of distin- guishability for quantum states. These measures should have important appli- cations in quantum cryptography and quantum computation theory. The results reported include the following. An exact expression for the quantum fidelity between two mixed states is derived. The optimal measurement that gives rise to it is studied in detail. Several upper and lower bounds on the quantum mutual information are derived via similar techniques and compared to each other. Of note is a simple derivation of the important upper bound first proved by Holevo and an explicit expression for another (tighter) upper bound that appears implicitly in the same derivation. Several upper and lower bounds to the quan- tum Kullback relative information are derived. The measures developed are also applied to ferreting out the extent to which quantum systems must be disturbed by information gathering measurements. This is tackled in two ways. The first is in setting up a general formalism for describing the tradeoff between inference and disturbance. The main point of this is that it gives a way of expressing the problem so that it appears as algebraic as that of the problem of finding quantum distinguishability measures. The second result on this theme is a theorem that prohibits "broadcasting" an unknown (mixed) quantum state. That is to say, there is no way to replicate an unknown quantum state onto two separate quantum systems when each system is considered without regard to the other. This includes the possibility of correlation or quantum entanglement between the systems. This result is a significant extension and generalization of the standard "no-cloning" theorem for pure states.
Preprint: This paper derives quantitative bounds on measurement windows for finite-capacity observers extracting information from decohering quantum systems, extending standard decoherence theory to realistic experimental constraints. Main Result: For Gaussian-Markovian decoherence with exponential information decay I(t) = I₀ exp(-2Γt), bounded-capacity observers lose access to system distinctions when mutual information drops below detection threshold ε, yielding measurement window: τ_c = (1/2Γ) log(α C_A / ε) where Γ is decoherence rate [s⁻¹], C_A is observer capacity [bits] defined via Shannon formula (bandwidth × log₂(SNR) × integration time), ε is detection threshold [bits], and α ~ 0.1-1 is a model-dependent constant from spectral decomposition of environmental information. This establishes logarithmic capacity-scaling: doubling detector quality extends measurement windows by only ~0.35/Γ seconds, implying diminishing returns from capacity improvements. Experimental Predictions: For state-of-the-art circuit QED (superconducting transmon qubits, T₁ = 100 μs, bandwidth Δf = 10 MHz, SNR = 10), the framework predicts τ_c ~ 4-10 μs. Varying bandwidth from 1-30 MHz (capacity C_A ∈ [3, 90] bits) produces measurable Δτ_c ≈ 1.7 μs variation (5-10% of coherence time). Five experimental tests discriminate capacity-scaling from standard decoherence: ∙ Tests 1-3: Verify logarithmic capacity-scaling, inverse rate-dependence, threshold-dependence ∙ Test 4: Multi-observer non-redundancy (at most one narrowband detector succeeds) ∙ Test 5: Capacity-dependent redundancy buildup (primary discriminating signature) Key Contributions: ∙ First quantitative analysis of Zurek's pre-objective phase under explicit finite-resource constraints ∙ Capacity-scaling law connecting Shannon information theory to quantum measurement dynamics ∙ Operational definitions ensuring falsifiability (capacity, threshold, mutual information defined via measurement protocols) ∙ Concrete numerical predictions for three platforms (circuit QED, spin qubits, optomechanics) with resource estimates ∙ Design principle: environmental shielding (linear benefit in τ_c) outperforms detector improvement (logarithmic benefit) when both options available Technical Approach: The bound follows from threshold-crossing analysis of exponential decay with capacity-limited initial information I₀ = α C_A, justified via spectral decomposition of environmental information under flat-spectrum approximation for narrowband observation. All parameters (Γ, C_A, ε) are operationally defined and independently measurable, avoiding circularity. Extensions to non-Markovian dynamics (memory kernels), scrambling systems (black holes, many-body chaos), and non-Gaussian noise (Lévy flights, 1/f noise) are discussed with conjectured scaling laws. Scope: The bound applies specifically to Gaussian-Markovian systems (harmonic oscillators, qubits in dispersive limit, weak continuous measurement with memoryless baths). Circuit QED provides optimal testbed due to tunable Purcell filters (bandwidth control), high coherence times (T₁ > 300 μs achieved), and multiplexed readout infrastructure (5+ independent detectors demonstrated). Validity requires α C_A > ε (initial information exceeds threshold); domain violations occur when capacity too small, threshold too high, or coupling too weak. Relation to Prior Work: Zurek's Quantum Darwinism (2003-2009) explains asymptotic objectivity emergence through environmental redundancy but assumes unbounded observers (C_A → ∞, t → ∞). This work analyzes the complementary finite-resource regime (C_A < ∞, t ~ τ_c), providing first capacity-parameterized bound on pre-objective phase duration. Framework is interpretation-neutral—compatible with Copenhagen, Many-Worlds, Bohmian mechanics, and relational quantum mechanics. Philosophical implications (process ontology, observer-dependent reality, impermanence) are explored but clearly separated from testable predictions. Methods: Open quantum systems theory, Shannon information theory, operational quantum measurement, circuit QED experimental physics, numerical prediction for realistic parameters. Content: Complete 90-page manuscript with axiomatic framework (§2), narrowband observation model (§3), main theorem with proof (§4), numerical predictions (§5), five experimental falsification tests (§6), detailed Quantum Darwinism comparison (§7), extensions and limitations (§8), interpretive options (§9), and honest assessment (§10). Includes 77 references and operational definitions for all information-theoretic quantities. Target Audience: Quantum foundations researchers, experimental quantum physicists (circuit QED, trapped ions, quantum dots), quantum information theorists, philosophers of physics interested in measurement and objectivity.
The use of the mutual information (MI) as a measure of the entanglement in quantum systems has gained a consensus in recent years, even if there is an ongoing effort to distinguish the classical and quantum contributions contained therein. This quantity has been first introduced in condensed matter physics, in particular, in studies based on the density matrix renormalization group method. This method has been successfully adapted to quantum chemistry problems, opening the way to compute MI also in molecular systems. A key aspect of this quantity is its dependence on the one-electron (orbital) basis set, even for wave functions that are invariant under unitary transformation of the orbitals. In this work, we investigate the role of the orbital basis set (delocalized or localized, following different strategies) for wave functions expressed as linear combinations of Slater determinants and we give the analytic expression for the MI for a few special cases. This study aims to improve the knowledge of the relationship between the characteristics of the chemical bond (considering a few paradigmatic molecules, H 2, F 2, N 2, and short linear polyenes) and the properties of interest in the field of quantum information theory.