To investigate the effects of electron correlation in narrow energy bands, a general formula of static spin susceptibility for interacting electron systems is derived. It is expressed in terms of the one-particle Green's function and its derivative with respect to the average number of the opposite spin electrons, the existence of the latter being the characteristic of electron correlation. The formula is applied to the case of Hubbard's improved approximation (Hubbard III), and gross feature of both the correlation and temperature dependences of the susceptibility is investigated in the insulating and metallic regions. The correlation in the metallic region is reduced for the Hubbard III case so that there occurs no ferromagnetism in a half-filled band.
Assuming that, in the narrow-band region, the exact Green's function of the Hubbard model essentially retains the two-peak structure proposed by Hubbard, we derive its consequences as rigorously as possible. When a quasielectron is added to the ground state of
N electrons in the narrow-band region of the Hubbard model, the whole system is shown to relax due to the strong interaction
I, thus yielding a relaxation energy $\ensuremath{\Delta}E$ between the quasielectron and the original
N electrons. This explains the conclusion in the preceding paper that a gap $\ensuremath{\Delta}E$ analogous to the energy gap in superconductivity appears between the quasielectron spectrum and the chemical potential for any occupation
n regardless of whether the lower band is exactly filled or not and that the system cannot be a normal metal. We further found that the ground state is, in fact, a bound state, and electrons involved do not obey the Landau theory of quasiparticles. However, the electron Green's function describes the motion of an electron added to this
N-electron ground state without the relaxation of the original
N electrons, and hence this added electron behaves exactly like a Landau quasiparticle and can be represented by the quasiparticle operator ${\mathrm{A}}_{k\ensuremath{\sigma}}^{\ifmmode\dagger\else\textdagger\fi{}}$ introduced by Luttinger and Nozi\`eres. Only if the original
N electrons are allowed to relax is the energy of the system reduced by $\ensuremath{\Delta}E$, yielding the energy gap $\ensuremath{\Delta}E$. When a quasielectron is removed from the system of
N+1 electrons, the same relaxation energy $\ensuremath{\Delta}E$ is removed, and again the gap $\ensuremath{\Delta}E$ is introduced between the chemical potential $\ensuremath{\mu}$ and the quasihole spectrum, thus creating a gap $2\ensuremath{\Delta}E$ between the quasielectron and quasihole spectra for any occupation
n. The Fermi level, lying at the center of the gap, never intersects the quasiparticle spectra and therefore, Luttinger's theorem that the volume within the Fermi surface is independent of interactions and equal to the value in the noninteracting limit does not apply to the Hubbard model in the narrow-band region. However, this conclusion does not immediately imply that the system is an insulator. Instead, it is shown that a current-carrying state analogous to the condensate state found by Fr\"ohlich appears under certain conditions. When the number of electrons
N is nearly or exactly equal to the number of atoms
Na, quasiparticlelike behavior disappears completely, making the system insulating. The only exception is the pathological limit $I=\ensuremath{\infty}$, where a metallic state with a Fermi volume twice that in the noninteracting limit is found.
A model to describe electronic correlations in energy bands is considered. The model is a generalization of the conventional Hubbard model that allows for the fact that the wave function for two electrons occupying the same Wannier orbital is different from the product of single-electron wave functions. We diagonalize the Hamiltonian exactly on a four-site cluster and study its properties as a function of band filling. The quasiparticle weight is found to decrease and the quasiparticle effective mass to increase as the electronic band filling increases, and spectral weight in one- and two-particle spectral functions is transferred from low to high frequencies as the band filling increases. Quasiparticles at the Fermi energy are found to be more ``dressed'' when the Fermi level is in the upper half of the band (hole carriers) than when it is in the lower half of the band (electron carriers). The effective interaction between carriers is found to be strongly dependent on band filling becoming less repulsive as the band filling increases and attractive near the top of the band in certain parameter ranges. The effective interaction is most attractive when the single-hole carriers are most heavily dressed, and in the parameter regime where the effective interaction is attractive, hole carriers are found to ``undress,'' hence become more like electrons, when they pair. It is proposed that these are generic properties of electronic energy bands in solids that reflect a fundamental electron-hole asymmetry of condensed matter. The relation of these results to the understanding of superconductivity in solids is discussed.
In the general frame of a modified many-body perturbation theory, the single-band Hubbard model is treated in the limit of weak electron-electron interaction. In this modification the decomposition of the Hamiltonian into an effective free system and an effective perturbation is rearranged iteratively in each order of the formalism, resulting in a successive reduction of the interaction part. In comparison with conventional perturbation techniques, this means an extended range of validity. Imposing thermodynamic self-consistency, we calculate the wave-vector-dependent electronic self-energy up to second order and analyze the influence of the Coulomb correlations. Several well-known physical properties of the Hubbard model are recovered in characteristic single-particle quantities. Therefore, the effect of the band occupation n and the electron-electron repulsion U on spectral densities, band structures, densities of states, magnetization, etc. is investigated in detail. Some of the most remarkable results are: first, a splitting of the free Bloch band into two quasiparticle subbands when the coupling strength reaches moderate values. These subbands are linked by a small damping-induced background in the density of states and are separated roughly by an energy of the order of U. In addition, the upper subband is shifted to higher energies in the spectrum proportionally to U while the lower one is nearly fixed. Second, we found a paramagnetic-ferromagnetic phase diagram that has a critical coupling strength
Uc and exhibits strong indications of a lower critical occupation number
nc. There is no spontaneous magnetization in the system for parameters smaller than these values. Compared with the Stoner model, one thus obtains striking improvements. In many cases our conclusions for the weak-coupling limit are qualitatively in good agreement with well-known results in the strong-correlation regime.
We study the quasiparticle spectrum of the Hubbard model by using a projection-operator formalism of the Green's function. In the weak-electron-correlation regime, we obtain the exact results up to second order in the intra-atomic interaction. For strong electron correlations, the quasiparticle spectrum consists of two bands. For each band, the quasiparticle energy is obtained exactly up to the first order in the transfer integral. We also propose a semiclassical approximation which gives the above-mentioned exact results in proper limits.