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Applied Physics B

AC Stark shift of the ground state of atomic hydrogen

Erna Karule, A. Gailītis

Published Mar 25, 2004• 2 citations
Publisher
DOI
10.1007/s00340-004-1457-y

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We present a theoretical study of transient absorption spectra of laser-dressed hydrogen atoms, based on numerical solutions of the time-dependent Schr\"odinger equation. The timing of absorption is controlled by the delay between an extreme ultra violet (XUV) pulse and an infrared (IR) laser field. The XUV pulse is isolated and several hundred attoseconds in duration, which acts as a pump to drive the ground-state electron to excited $p$ states. The subsequent interaction with the IR field produces dressed states, which manifest as sidebands between the 1s-$np$ absorption spectra separated by one IR-photon energy. We demonstrate that the population of dressed states is maximized when the timing of the XUV pulse coincides with the zero crossing of the IR field, and that their energies can be manipulated in a subcycle time scale by adding a chirp to the IR field. An alternative perspective to the problem is to think of the XUV pulse as a probe to detect the dynamical ac Stark shifts. Our results indicate that the accidental degeneracy of the hydrogen excited states is removed while they are dressed by the IR field, leading to large ac Stark shifts. Furthermore, we observe the Autler-Townes doublets for the $n=2$ and 3 levels using the 656 nm dressing field, but their separation does not agree with the prediction by the conventional three-level model that neglects the dynamical ac Stark shifts.

Physical Review A•Oct 28, 2013•12 citations
Recently, we studied the magic wavelength for the atomic hydrogen $1S\text{\ensuremath{-}}2S$ transition [A. Kawasaki, Phys. Rev. A 92, 042507 (2015)]. An explicit summation over virtual atomic states of the discrete part of the hydrogen spectrum was performed to evaluate the atomic polarizability. In this paper, we supplement the contribution of the continuum part of the spectrum and add the reduced-mass correction. The magic wavelength, at which the lowest-order ac Stark shifts of the 1S1S1S and 2S2S2S states are equal, is found to be 514.6 nm. The ac Stark shift at the magic wavelength is $\ensuremath{-}221.6\phantom{\rule{0.28em}{0ex}}\mathrm{Hz}/(\mathrm{kW}/{\mathrm{cm}}^{2})$, and the slope of the ac Stark shift at the magic wavelength under a change of the driving laser frequency is $\ensuremath{-}0.2157\phantom{\rule{0.28em}{0ex}}\mathrm{Hz}/[\mathrm{GHz}\phantom{\rule{0.28em}{0ex}}(\mathrm{kW}/{\mathrm{cm}}^{2})]$.
Recently, we studied the magic wavelength for the atomic hydrogen 1S−2S transition [A. Kawasaki, Phys. Rev. A 92, 042507 (2015)]. An explicit summation over virtual atomic states of the discrete part of the hydrogen spectrum was performed to evaluate the atomic polarizability. In this paper, we supplement the contribution of the continuum part of the spectrum and add the reduced-mass correction. The magic wavelength, at which the lowest-order ac Stark shifts of the 1S and 2S states are equal, is found to be 514.6 nm. The ac Stark shift at the magic wavelength is −221.6Hz/(kW/cm[superscript 2]), and the slope of the ac Stark shift at the magic wavelength under a change of the driving laser frequency is −0.2157Hz/[GHz(kW/cm[superscipt 2])].
We present a theoretical study of transient absorption spectra of laser-dressed hydrogen atoms, based on numerical solutions of the time-dependent Schr\"odinger equation. The timing of absorption is controlled by the delay between an extreme ultra violet (XUV) pulse and an infrared (IR) laser field. The XUV pulse is isolated and several hundred attoseconds in duration, which acts as a pump to drive the ground-state electron to excited ppp states. The subsequent interaction with the IR field produces dressed states, which manifest as sidebands between the 1s-npnpnp absorption spectra separated by one IR-photon energy. We demonstrate that the population of dressed states is maximized when the timing of the XUV pulse coincides with the zero crossing of the IR field, and that their energies can be manipulated in a subcycle time scale by adding a chirp to the IR field. An alternative perspective to the problem is to think of the XUV pulse as a probe to detect the dynamical ac Stark shifts. Our results indicate that the accidental degeneracy of the hydrogen excited states is removed while they are dressed by the IR field, leading to large ac Stark shifts. Furthermore, we observe the Autler-Townes doublets for the n=2n=2n=2 and 3 levels using the 656 nm dressing field, but their separation does not agree with the prediction by the conventional three-level model that neglects the dynamical ac Stark shifts.