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Soviet Physics Uspekhi

Form of the Hamiltonian and the initial conditions in radiation problems

Vladimir P Bykov

Published Aug 31, 1984• 8 citations
Publisher

Abstract

The use of two of the most often employed forms of the Hamiltonian describing the interaction of atoms and molecules with an electromagnetic field is examined using the example of spontaneous emission. It is shown that formally the same initial state corresponds in the cases of different Hamiltonians to physically different initial conditions: a stationary Coulomb field exists in the initial state in one case and a nonstationary field, arising upon sudden excitation of the atom, exists in another. The differences in the initial conditions determine the differences in the photon spectra arising upon subsequent emission. The choice of initial conditions in real situations can be made by making a physical analysis of the excitation process. The Hamiltonian is transformed from one form to another. It is emphasized that the Hamiltonians are equivalent only if the states are correspondingly transformed. The Lamb-Retherford experiment is analyzed qualitatively.

DOI
10.1070/pu1984v027n08abeh004076

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•Oct 25, 2021•0 citations
The use of two of the most often employed forms of the Hamiltonian describing the interaction of atoms and molecules with an electromagnetic field is examined using the example of spontaneous emission. It is shown that formally the same initial state corresponds in the cases of different Hamiltonians to physically different initial conditions: a stationary Coulomb field exists in the initial state in one case and a nonstationary field, arising upon sudden excitation of the atom, exists in another. The differences in the initial conditions determine the differences in the photon spectra arising upon subsequent emission. The choice of initial conditions in real situations can be made by making a physical analysis of the excitation process. The Hamiltonian is transformed from one form to another. It is emphasized that the Hamiltonians are equivalent only if the states are correspondingly transformed. The Lamb-Retherford experiment is analyzed qualitatively.
Many dynamical processes of interest are either initiated or probed by light, and their understanding requires some knowledge of this subject. This chapter is included in order to make this text self contained by providing an overview of subjects that are used in various applications later in the text. In particular, it aims to supplement the elementary view of radiation–matter interaction as a time-dependent perturbation in the Hamiltonian, by describing some aspects of the quantum nature of the radiation field. This is done on two levels: The main body of this chapter is an essentially qualitative overview that ends with a treatment of spontaneous emission as an example. The Appendix gives some more details on the mathematical structure of the theory. In elementary treatments of the interaction of atoms and molecules with light, the radiation field is taken as a classical phenomenon.
A critical examination of the theory of resonance radiation has been carried through, employing the mathematical technique of Laplace and Stieltjes transforms. Particular attention has been devoted to the question of the temporal behavior of the excited state. With no restrictions on the interaction between atom and radiation field other than that it be real, and that processes of sufficiently high frequency contribute only negligible effects, one can prove that the probability amplitude of the excited state cannot decay according to the general law ${\ensuremath{\Sigma}}_{\ensuremath{\mu},\ensuremath{\nu}}{C}_{\ensuremath{\mu}\ensuremath{\nu}}{t}^{{\ensuremath{\lambda}}_{\ensuremath{\mu}}}{e}^{\ensuremath{-}{\ensuremath{\beta}}_{\ensuremath{\nu}}t},$ where the ${\ensuremath{\lambda}}_{\ensuremath{\mu}}$ and ${\ensuremath{\beta}}_{\ensuremath{\nu}}$ are complex constants lying in the right half-plane and the ${C}_{\ensuremath{\mu}\ensuremath{\nu}}$ are arbitrary complex coefficients. The deviation from the law just cited can be termed a straggling phenomenon since exact analysis shows that the probability amplitude, for sufficiently long times, is greater than that defined according to the radioactive decay law.Rigorous analysis of the source of this apparently anomalous behavior reveals the following explanation. Although the probability amplitude of the excited state is, strictly speaking, a functional of the interaction between the transition current in the atom and the photon states of the electromagnetic field, the essential features are determined principally by those states lying near the resonance frequency. Three elementary observations are immediately apparent. First, a particularly tractable analytical approximation for the interaction can be made such that the value of the actual interaction is reproduced at the resonance frequency and such that the behavior for high and low frequency photon states is at least qualitatively correct. Exact solutions in closed form can be obtained for this interaction. Second, in terms of the preceding representation it is possible to show that, associated with the transition between two atomic states, one is presented with a concomitant picture of a damped oscillation of charge describable in purely classical terms. Third, this classical motion can be interpreted as forming a source function for a continuous stochastic process in terms of which one finally derives the representation of the probability amplitude of the excited state. The straggling phenomenon previously cited is therefore that associated with all diffusion processes. The consideration of the exact interaction leads to more involved diffusion phenomena but does not in any case permit a radioactive decay law.
We investigate (non-relativistic) atomic systems interacting with quantum electromagnetic field (QEF). The resulting model describes spontaneous emission of light from a two-level atom surrounded by various initial states of the QEF. We assume that the quantum field interacts with the atom via the standard, minimal-coupling Hamiltonian, with the A2 term neglected. We also assume that there will appear at most single excitations (photons). By conducting the analysis on a general level we allow for an arbitrary initial state of the QEF (which can be for instance: the vacuum, the ground state in a cavity, or the squeezed state). We derive a Volterra-type equation which governs the time evolution of the amplitude of the excited state. The two-point function of the initial state of the QEF, integrated with a combination of atomic wavefunctions, forms the kernel of this equation.
In nonrelativistic quantum electrodynamics there is a class of equivalent Hamiltonians that describe a system of radiation and atoms or molecules in interaction. Three specific examples, namely, the minimal coupling, the multipolar, and the space-translated forms are analyzed here in detail. Their equivalence is demonstrated. The Lagrangian approach has also been examined to give further insight into the dynamics. The equations of motion are compared. Finally, the process of two-photon absorption by an atom is used as an application of the various interaction Hamiltonians in a discussion of their computational differences.
Abstract We develop the method of canonical quantisation for the case of the free electromagnetic field. We choose the Coulomb gauge, which has a simpler physical interpretation. We introduce the creation and annihilation operators in this framework. The formalism is applied to the problem of spontaneous emission of radiation from an excited atomic state at first order in the perturbation expansion. This allows us to obtain a concrete physical result, namely the computation of an excited state decay rate, and, at the same time, have a first look at abstract concepts, such as gauge invariance and renormalisation.