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Physical Review

Space-Time Representation in Wave Mechanics

Emil J. Hellund, Malcolm K. Brachman

Published Nov 1, 1953• 2 citations
Publisher

Abstract

A Newtonian-like basis for describing the dynamical behavior of a system is presented. The nature of the correspondence with a Boltzmann type statistical mechanics is shown. Application of elementary transformation theory is used to effect the results.
DOI
10.1103/physrev.92.822

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We review a non-relativistic current algebra symmetry approach to constructing the Bogolubov generating functional of many-particle distribution functions and apply it to description of invariantly reduced Hamiltonian systems of the Boltzmann type kinetic equations, related to naturally imposed constraints on many-particle correlation functions. As an interesting example of deriving Vlasov type kinetic equations, we considered a quantum-mechanical model of spinless particles with delta-type interaction, having applications for describing so called Benney-type hydrodynamical praticle flows. We also review new results on a special class of dynamical systems of Boltzmann–Bogolubov and Boltzmann–Vlasov type on infinite dimensional functional manifolds modeling kinetic processes in many-particle media. Based on algebraic properties of the canonical quantum symmetry current algebra and its functional representations, we succeeded in dual analysis of the infinite Bogolubov hierarchy of many-particle distribution functions and their Hamiltonian structure. Moreover, we proposed a new approach to invariant reduction of the Bogolubov hierarchy on a suitably chosen correlation function constraint and deduction of the related modified Boltzmann–Bogolubov kinetic equations on a finite set of multi-particle distribution functions. There are also presented results of application of devised methods to describing kinetic properties of a many-particle system with an adsorbent surface, in particular, the corresponding kinetic equation for the occupation density distribution function is derived.
A new, very different physical model of the universe is proposed. Its virtues include unifying relativity and quantum mechanics, and particles with de Broglie waves. It also appears to provide a truly unified physical basis for electromagnetic, gravitational and nuclear forces. The basic system is a four-dimensional Euclidean space, containing an array of nonlinear "flow" waves. These repeat in one dimension, called [phi]. As in Newtonian mechanics, time is treated as an additional, unidirectional parameter describing the evolution of the system. Nevertheless, this wave system is shown be inherently relativistic. Further self-organizing patterns arise within the overall wave structure. Called "wavicles," these have intrinsic quantized fields, "spin," and rest energy, and represent elementary particles. Relativistic expressions are derived for particle behavior in scalar, vector and gravitational potentials. Proper representations of these potentials, based on the wave fields and associated [phi] flows of wavicles, are also obtained. As in the causal quantum mechanics of de Broglie and Bohm, wavicles exist continuously and follow definite, stochastic trajectories. Although experimentally equivalent to Einstein's special relativity, this theory differs fundamentally from his general relativity and the associated Big Bang model. According to Linde, the latter predict a large-scale space-time curvature roughly 60 orders of magnitude greater than observed values. Here a flat large-scale geometry is predicted, in agreement with the observed distribution of galaxies. This theory is also consistent with recent observations pertaining to the age of the universe.
The reaction rate constant is defined as the rate at which a reactant annihilates or a product creates in a chemical reaction. The Hamiltonian of the reaction system describing elementary reactions has already been formulated by Miller et al（J. Chem. Phys. 1980, 72, 99-112） In addition, the reaction coordinates representing the progress of the reaction are also formulated by Fukui.（J. Phys. Chem. 1970, 74, 4161-4163） In the present paper, on the basis of these two theories, we first formulated the reaction rate constants of elementary reactions using classical statistical mechanics. Then we rewrited the rate constans quantum-mechanically according to the method of Wigner representations. By this rewriting, a correction term representing the quantum effect of the reaction rate constant was naturally derived.