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Journal of Physics A Mathematical and General

Critical behaviour of spin-s Heisenberg antiferromagnetic chains: analytic and numerical results

Ian K. Affleck, Doron Gepner, Heinz J. Schulz, Timothy A. L. Ziman

Published Mar 7, 1989• 433 citations
Publisher

Abstract

A general phase diagram for isotropic antiferromagnetic chains has been proposed recently, using conformal field theory. This is developed further to predict the spectrum of finite chains, including logarithmic corrections. These predictions are tested against Bethe ansatz and exact diagonalisation results for various Hamiltonians with s=1/2, 1 and 3/2. Logarithmic corrections to correlation functions and the scaling of gaps for infinite systems are also given.

DOI
10.1088/0305-4470/22/5/015

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A general phase diagram for isotropic antiferromagnetic chains has been proposed recently, using conformal field theory. This is developed further to predict the spectrum of finite chains, including logarithmic corrections. These predictions are tested against Bethe ansatz and exact diagonalisation results for various Hamiltonians with s=1/2, 1 and 3/2. Logarithmic corrections to correlation functions and the scaling of gaps for infinite systems are also given.
Since the Heisenberg spin chain can be considered the simplest realistic model of magnetism, surprise and some degree of controversy have resulted from recent work of Haldane. The prediction is that quantum spin chains with half-integer spin should all display T=0 phase behavior equivalent to that of the Bethe Ansatz integrable (solvable) spin-1/2 quantum chain. More remarkably, the class of integer spin chains is predicted to show very different phase behavior. In particular, a gap should be present in the spectrum of a Heisenberg antiferromagnetic chain. This remarkable feature is counterintuitive in terms of accepted wisdom in magnetism (spin-wave theory, spin-Peierls theory) and critical phenomena. Consequently the vertification of the prediction is of great interest. A considerable amount of numerical work has been done, involving finite-chain, finite-size scaling, variational, Monte Carlo and other calculations, which will be reviewed here. The present consensus is that the weight of numerical evidence supports the prediction, although puzzling features still remain. Adding additional interactions to the basic Heisenberg Hamiltonian such as spin (XXZ) anisotropy, single-ion anisotropy, biquadratic exchange, and an applied magnetic field, generates a rich and complicated phase diagram for chains with spin >1/2, particularly for the case of integer spin. The s=1 phase diagram seems to display critical behavior of a type not previously encountered. A theoretical appraisal of the Haldane phenomenon will include a discussion of the possible role of nonintegrability. Mention will also be made of current progress in experimental investigation of the phenomenon, including problems that might be encountered. More recent work of Affleck has greatly generalized the field-theoretic mappings which underlay the original work of Haldane. A number of interesting problems have been mapped into quantum spin chains of various types, including field theoretic phenomena and the localization problem of the quantum Hall effect.
Various numerical estimates of critical exponents for antiferromagnetic chains are compared with conformal field-theory predictions. Field theory allows the explicit calculation of logarithmic corrections, and hence the value of the effective exponent that is expected to be observed numerically. Comparison is made with numerically obtained exponent values, and agreement is found to be very good, even when logarithmic corrections are as large as 70%. Logarithmic corrections can lead to misleading results, for example an incorrect phase diagram, and examples in the literature where this seems to have occurred are discussed.
A recently developed numerical method, entanglement perturbation theory (EPT), is used to study the antiferromagnetic Heisenberg spin chains with z-axis anisotropy λλλ and magnetic field B. To demonstrate the accuracy, we first apply EPT to the isotropic spin-1/2 antiferromagnetic Heisenberg model, and find that EPT successfully reproduces the exact Bethe Ansatz results for the ground state energy, the local magnetization, and the spin correlation functions (Bethe ansatz result is available for the first 7 lattice separations). In particular, EPT confirms for the first time the asymptotic behavior of the spin correlation functions predicted by the conformal field theory, which realizes only for lattice separations larger than 1000. Next, turning on the z-axis anisotropy and the magnetic field, the 2-spin and 4-spin correlation functions are calculated, and the results are compared with those obtained by Bosonization and density matrix renormalization group methods. Finally, for the spin-1 antiferromagnetic Heisenberg model, the ground state phase diagram in λλλ space is determined with help of the Roomany-Wyld RG finite-size-scaling. The results are in good agreement with those obtained by the level-spectroscopy method.
A recently developed numerical method, entanglement perturbation theory (EPT), is used to study the antiferromagnetic Heisenberg spin chains with z-axis anisotropy λ and magnetic field B. To demonstrate the accuracy, we first apply EPT to the isotropic spin1 2 antiferromagnetic Heisenberg model, and find that EPT successfully reproduces the exact Bethe Ansatz results for the ground state energy, the local magnetization, and the spin correlation functions (Bethe ansatz result is available for the first 7 lattice separations). In particular, EPT confirms for the first time the asymptotic behavior of the spin correlation functions predicted by the conformal field theory, which realizes only for lattice separations larger than 1000. Next, turning on the z-axis anisotropy and the magnetic field, the 2-spin and 4-spin correlation functions are calculated, and the results are compared with those obtained by Bosonization and density matrix renormalization group methods. Finally, for the spin-1 antiferromagnetic Heisenberg model, the ground state phase diagram in λ space is determined with help of the Roomany-Wyld RG finite-size-scaling. The results are in good agreement with those obtained by the level-spectroscopy method.
There has recently been considerable interest in the numerical calculation of critical exponents for quantum spin chains with general spin s, stimulated by a remarkable prediction by Haldane and conformally invariant field theoretic calculations. In several instances numerical calculations have differed considerably from theoretical predictions, with misleading results. These discrepancies have generally been attributed to the presence of marginal operators resulting in logarithmic corrections which slow numerical convergence. Such phenomena seem to be ubiquitous in the area of quantum spin chains. However, until recently, no calculation was available for estimating quantitatively the expected shifts in exponent values obtained by numerical means. The purpose of this work is to call attention to such a calculation1 for the integrable Takhtajan–Babujian family of quantum spin chains, and make specific comparisons with a variety of spin chain exponents obtained numerically.2,3 Agreement with the analytic formulas is extremely good in all cases. This is an indication that finite-size scaling is a powerful tool for extracting critical exponents even in models with logarithmic corrections, provided that these corrections are taken into account in lowest order using the method of Ref. 1.
The critical behaviour of anisotropic Heisenberg models with two kinds of antiferromagnetically exchange-coupled centres are studied numerically by using finite-size calculations and conformal invariance. These models exhibit the interesting property of ferrimagnetism instead of antiferromagnetism. Most of our results are centred in the mixed Heisenberg chain where we have at even (odd) sites a spin- SU(2) operator interacting with a XXZ-like interaction (anisotropy ). Our results indicate universal properties for all these chains. The whole phase, , where the models change from ferromagnetic to ferrimagnetic behaviour is critical. Along this phase the critical fluctuations are ruled by a c = 1 conformal field theory of Gaussian type. The conformal dimensions and critical exponents, along this phase, are calculated by studying these models with several boundary conditions.