While the geometry of equilibrium states and driven non-equilibrium processes is clearly understood, a geometric description for relaxation towards equilibrium is still lacking. Here, we propose a thermo-geometric measure based on the Rayleigh quotient, reformulating relaxation as a fundamental competition between entropic stiffness and frictional dissipation. Taking a van der Waals gas with two dissipation channels as an example, we explicitly demonstrate its relaxation landscape. Particularly, we find that upon approaching the critical temperature $T_c$ , the slow-mode relaxation rate vanishes linearly as $λ_s \propto (T-T_c)/T_c$ , indicating critical slowing down. This study completes the thermodynamic geometry framework, providing a general tool for characterizing the relaxation dynamics of complex systems.While the geometry of equilibrium states and driven non-equilibrium processes is clearly understood, a geometric description for relaxation towards equilibrium is still lacking. Here, we propose a thermo-geometric measure based on the Rayleigh quotient, reformulating relaxation as a fundamental competition between entropic stiffness and frictional dissipation. Taking a van der Waals gas with two dissipation channels as an example, we explicitly demonstrate its relaxation landscape. Particularly, we find that upon approaching the critical temperature $T_c$, the slow-mode relaxation rate vanishes linearly as $λ_s \propto (T-T_c)/T_c$, indicating critical slowing down. This study completes the thermodynamic geometry framework, providing a general tool for characterizing the relaxation dynamics of complex systems.

cond-mat.stat-mechCross-listedarXiv:2604.15000Apr 17, 2026

Relaxation to Thermodynamical Equilibrium from Simulations of Quantum Dynamics

Barbara Fresch

Feb 26, 20100 citations

Kibble–Zurek Scaling from Linear Response Theory

Pierre Nazé, Marcus V. S. Bonança, Sebastian Deffner

While quantum phase transitions share many characteristics with thermodynamic phase transitions, they are also markedly different as they occur at zero temperature. Hence, it is not immediately clear whether tools and frameworks that capture the properties of thermodynamic phase transitions also apply in the quantum case. Concerning the crossing of thermodynamic critical points and describing its non-equilibrium dynamics, the Kibble-Zurek mechanism and linear response theory have been demonstrated to be among the very successful approaches. In the present work, we show that these two approaches are also consistent in the description of quantum phase transitions, and that linear response theory can even inform arguments of the Kibble-Zurek mechanism. In particular, we show that the relaxation time provided by linear response theory gives a rigorous argument for why to identify the "gap" as a relaxation rate, and we verify that the excess work computed from linear response theory exhibits Kibble-Zurek scaling.While quantum phase transitions share many characteristics with thermodynamic phase transitions, they are also markedly different as they occur at zero temperature. Hence, it is not immediately clear whether tools and frameworks that capture the properties of thermodynamic phase transitions also apply in the quantum case. Concerning the crossing of thermodynamic critical points and describing its non-equilibrium dynamics, the Kibble-Zurek mechanism and linear response theory have been demonstrated to be among the very successful approaches. In the present work, we show that these two approaches are also consistent in the description of quantum phase transitions, and that linear response theory can even inform arguments of the Kibble-Zurek mechanism. In particular, we show that the relaxation time provided by linear response theory gives a rigorous argument for why to identify the "gap" as a relaxation rate, and we verify that the excess work computed from linear response theory exhibits Kibble-Zurek scaling.

arXiv:2203.12438EntropyMay 10, 20220 citations

Eigenvalue Crossing as a Phase Transition in Relaxation Dynamics

Gianluca Teza, Ran Yacoby, Oren Raz

When a system's parameter is abruptly changed, a relaxation toward the new equilibrium of the system follows. We show that a crossing between the second and third eigenvalues of the relaxation operator results in a singularity in the dynamics analogous to a first-order equilibrium phase transition. While dynamical phase transitions are intrinsically hard to detect in nature, here we show how this kind of transition can be observed in an experimentally feasible four-state colloidal system. Finally, analytical proof of survival in the thermodynamic limit of a many body (1D Ising) model is provided.When a system's parameter is abruptly changed, a relaxation toward the new equilibrium of the system follows. We show that a crossing between the second and third eigenvalues of the relaxation operator results in a singularity in the dynamics analogous to a first-order equilibrium phase transition. While dynamical phase transitions are intrinsically hard to detect in nature, here we show how this kind of transition can be observed in an experimentally feasible four-state colloidal system. Finally, analytical proof of survival in the thermodynamic limit of a many body (1D Ising) model is provided.

arXiv:2209.09307Physical Review LettersMay 18, 202337 citations

T_c

, the slow-mode relaxation rate vanishes linearly as

λ_s \propto (T-T_c)/T_c

, indicating critical slowing down. This study completes the thermodynamic geometry framework, providing a general tool for characterizing the relaxation dynamics of complex systems.