Statistical reformulation of quantum mechanics in terms of phase-space distribution functions as given by Moyal using Weyl's correspondence rule between classical functions and operators has been extended to various different correspondence rules. The dynamical bracket in the Weyl correspondence (the ``Moyal'' or the ``sine'' bracket) is shown to be a Lie bracket. It is further shown that if the theory is restricted to Lie brackets of the form [u(p, q),υ(p, q)]={f(∂2∂q1 ∂p2−∂2∂q2 ∂p1)u(p1, q1)υ(p2, q2)},evaluated for p1 = p2 = p; q1 = q2 = q after differentiation, then the only admissible functional form of f is f(x) = β[(sin αx)/α], where α and β are constants. A law of multiplication which is associative and distributive with respect to addition is also introduced in each case. It gives a correct correspondence between operator multiplication and the multiplication of classical functions. The dynamical brackets obtained in each case are also found to be Lie brackets. Conditions on the phase-space distribution functions to describe pure states are also given.
Statistical reformulation of quantum mechanics in terms of phase-space distribution functions as given by Moyal using Weyl's correspondence rule between classical functions and operators has been extended to various different correspondence rules. The dynamical bracket in the Weyl correspondence (the Moyal'' or the sine'' bracket) is shown to be a Lie bracket. It is further shown that if the theory is restricted to Lie brackets of the form [u(p, q),υ(p, q)]={f(∂2∂q1 ∂p2−∂2∂q2 ∂p1)u(p1, q1)υ(p2, q2)},evaluated for p1 = p2 = p; q1 = q2 = q after differentiation, then the only admissible functional form of f is f(x) = β[(sin αx)/α], where α and β are constants. A law of multiplication which is associative and distributive with respect to addition is also introduced in each case. It gives a correct correspondence between operator multiplication and the multiplication of classical functions. The dynamical brackets obtained in each case are also found to be Lie brackets. Conditions on the phase-space distribution functions to describe pure states are also given.
This thesis describes quantum mechanics in the phase space formulation. We introduce quantization and in particular the Weyl quantization. We study a general class of phase space distribution functions on phase space. The Wigner distribution function is one such distribution function. The Wigner distribution function in general attains negative values and thus can not be interpreted as a real probability density, as opposed to for example the Husimi distribution function. The Husimi distribution however does not yield the correct marginal distribution functions known from quantum mechanics. Properties of the Wigner and Husimi distribution function are studied to more extent. We calculate the Wigner and Husimi distribution function for the energy eigenstates of a particle trapped in a box. We then look at the semi classical limit for this example. The time evolution of Wigner functions are studied by making use of the Moyal bracket. The Moyal bracket and the Poisson bracket are compared in the classical limit. The phase space formulation of quantum mechanics has as advantage that classical concepts can be studied and compared to quantum mechanics. For certain quantum mechanical systems the time evolution of Wigner distribution functions becomes equivalent to the classical time evolution stated in the exact Egerov theorem. Another advantage of using Wigner functions is when one is interested in systems involving mixed states. A disadvantage of the phase space formulation is that for most problems it quickly loses its simplicity and becomes hard to calculate.
The Weyl transform is applied in quantum dynamics to derive and extend Moyal's statistical theory of phase-space distributions for noncommuting coordinate and momentum operators. The distinction is made between Weyl transforms in Schrödinger and Heisenberg pictures; the general case of time-dependent Hamiltonians is considered. The Wigner function for the probability distribution in a phase space of Cartesian coordinates Q and momenta K propagates according to a conditional probability P(t, Q, K | t0, Q0, K0), which is exhibited as a Feynman path integral in phase space. Properties of P(t, Q, K | t0, Q0, K0) are developed; it is expressed in terms of the quantum generalization of the classical Liouville operator. The Weyl transform of a Heisenberg operator propagates according to P(t, Q0, K0 | t0, Q, K) which is also given as a Feynman path integral. An equation for the time evolution of Weyl transforms of Heisenberg operators is obtained, according to which the transform of Heisenberg coordinate and momentum operators obey a quantum form of Hamilton's equations of motion. If the initial density operator of the system commutes with the coordinate operator, then the state of the system is a mixture of pure coordinate states; the spectrum of the density operator in this case is continuous. For a Heisenberg operator AH(t) with Weyl transform AH(t, Q, K), the function A(t,Q)=∫dKAH(t,Q,K) is the expectation at time t of the dynamical property for a quantum system initially in a pure state of coordinate Q; it is the quantum-mechanical generalization of the dynamical property of the system along the classical trajectory in configuration space at time t. The probability amplitude for the time dependence of A(t,Q) can be expressed as a Feynman path integral with a Heisenberg Lagrangian. The amplitude of the conditional probability P(t, Q | t0, Q0) considered by Feynman is expressed as a path integral with a Schrödinger Lagrangian. The velocity in the Heisenberg Lagrangian is the negative of that in the Schrödinger Lagrangian of Feynman, but it agrees with the velocity appearing in the Hamiltonian equations. It is the Heisenberg Lagrangian that is the Lagrangian of classical dynamics. For a particle whose potential energy is a function of position, a quantum form of Newton's second law is obtained. An extension of the formalism to non-Cartesian coordinate systems is given.
The Moyal description of quantum mechanics, based on the Wigner-Weyl isomorphism between operators and symbols, provides a comprehensive phase space representation of dynamics. The Weyl symbol image of the Heisenberg picture evolution operator is regular in ħ and so presents a preferred foundation for semiclassical analysis. Its semiclassical expansion "coefficients," acting on symbols that represent observables, are simple, globally defined (phase space) differential operators constructed in terms of the classical flow. The first of two presented methods introduces a cluster-graph expansion for the symbol of an exponentiated operator, which extends Groenewold′s formula for the Weyl product of two symbols and has ħ as its natural small parameter. This Poisson bracket based cluster expansion determines the Jacobi equations for the semiclassical expansion of "quantum trajectories." Their Green function solutions construct the regular ħ ⇓ 0 asymptotic series for the Heisenberg-Weyl evolution map. The second method directly substitutes such a series into the Moyal equation of motion and determines the ħ coefficients recursively. In contrast to the WKB approximation for propagators, the Heisenberg-Weyl description of evolution involves no essential singularity in ħ, no Hamilton-Jacobi equation to solve for the action, and no multiple trajectories, caustics, or Maslov indices.
We investigate the possibility that the semiclassical limit of quantum mechanics might be correctly described by a classical dynamical theory, other than standard classical mechanics. Using a set of classicality criteria proposed in a related paper, we show that the time evolution of a set of quantum initial data satisfying these criteria is fully consistent with the predictions of a new theory of classical dynamics. The dynamical structure of the new theory is given by the Moyal bracket. This is a Lie bracket that was first derived as the dynamical structure of the Moyal-Weyl-Wigner formulation of quantum mechanics. We present a new derivation of the Moyal bracket, this time in the context of the semiclassical limit of quantum mechanics and thus prove that both classical and quantum dynamics can be formulated in terms of the same canonical structure.
The objective of this thesis is to describe the fundamental concepts relating to the reformulation of quantum mechanics in phase space. It is assumed that the interested reader is familiar with the principles and techniques of ordinary quantum mechanics. In classical statistical mechanics the expectation values of physical quantities are calculated as averages over phase space distribution functions. It is possible to obtain a similar procedure in quantum mechanics. However, phase space is a classical concept and thus has no quantum mechanical equivalent, owing to the non-commutability of the operators p and q. A sensible basic requirement for the formulation of quantum mechanics in phase space is a linear one-one mapping between quantum operators and classical functions. This was achieved by the pioneering work of Weyl, Wigner and Moyal. The phase space that they devised we shall call "pseudo phase space". It is completely quantum. The pseudo phase space variables are represented by commuting c-numbers of momentum, p, and position, q; they are the result of applying the Weyl correspondence rule to the operators p and q, respectively. In some ways the pseudo phase space formulation of quantum mechanics appears to return us to an "almost" classical arena, since we dispense with the calculus of non-commuting operators for purely algebraic methods. The pseudo phase space formulation of quantum mechanics is self-contained. That is, there is no need, in principle, to switch to the Schroedinger or Heisenberg pictures when solving physical problems, although it may often be convenient to do so. The classical appearance of the pseudo phase space scheme is especially useful when considering the semi-classical limit of quantum mechanics. In fact, for potentials up to and including the harmonic oscillator the equations represent classical motion. The structure of the thesis is such that it takes the reader steadily through the major concepts of pseudo phase space theory. The mathematical techniques that shall be needed are developed early in Chapter 1. These are used throughout the thesis. This presents the advantage that the reader is not faced with learning new mathematical methods as the thesis proceeds. The pseudo phase space formulation of quantum mechanics as found applications in all areas of mathematical physics. Hence, there is a considerable amount of specialist literature available on the subject. Itis hoped that this thesis serves has an introduction.
By making use of the Weyl-Wigner-Groenewold-Moyal association rules, a commutative product and a new quantum bracket are constructed in the ring of operators \cal{F}(H). In this way, an isomorphism between Lie algebra of classical observables (with Poisson bracket) and the Lie algebra of quantum observables with this new bracket is established. By these observations, a formulation of the classical mechanics in \cal{F}(H} is obtained and is shown to be \hbar\to 0 limit of the Heisenberg picture formulation of the quantum mechanics.