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Journal of Mathematical Physics

Physical applications of multiplicative stochastic processes. III. Nonequilibrium entropy

Ronald F. Fox

Published Jun 1, 1975• 1 citation
Publisher

Abstract

It is argued that the expression − KB Trace [〈ρ (t) 〉 ln〈ρ (t) 〉], which appears in a stochastic treatment of the dynamics of the density matrix is indeed the nonequilibrium entropy. The reasoning involves consideration of the time evolution of the free energy for a relaxing magnetic moment in a fluctuating magnetic environment. It is shown that the H theorem, and the monotonic decrease of the free energy, as described by Pauli’s master equation can be generalized to the full density matrix, at least for the case of magnetic relaxation, which requires the presence of off-diagonal density matrix elements.

DOI
10.1063/1.522670

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It is argued that the expression − KB Trace [〈ρ (t) 〉 ln〈ρ (t) 〉], which appears in a stochastic treatment of the dynamics of the density matrix is indeed the nonequilibrium entropy. The reasoning involves consideration of the time evolution of the free energy for a relaxing magnetic moment in a fluctuating magnetic environment. It is shown that the H theorem, and the monotonic decrease of the free energy, as described by Pauli’s master equation can be generalized to the full density matrix, at least for the case of magnetic relaxation, which requires the presence of off-diagonal density matrix elements.
The multiplicative stochastic process treatment of the time development of the density matrix for a subsystem in contact with a heat reservoir is applied to the specific problem of the relaxation of a nuclear magnetic moment which is interacting with a fluctuating magnetic environment. A model for the fluctuating interaction Hamiltonian, appropriate for the magnetic moment case, is presented, and the Bloch equations for nuclear magnetic relaxation are constructed as a consequence. Agreement with empirical observations is noted.
We propose a new representation for several quantum master equations in so-called quasithermodynamic form. This representation (when it exists) let one to write down dynamical equations both for diagonal and non-diagonal elements of density matrix of the quantum system of interest in unified form by means of nonequilibrium potential ("entropy") that is a certain quadratic function depending on all variables describing the state. We prove that above representation exists for the general Pauli master equation and for the Lindblad master equation ( at least in simple cases ) as well. We discuss also advantages of the representation proposed in the study of kinetic properties of open quantum systems particularly of its relaxation to the stationary state.
Stochastic methods are ubiquitous to a variety of fields, ranging from physics to economics and mathematics. In many cases, in the investigation of natural processes, stochasticity arises every time one considers the dynamics of a system in contact with a somewhat bigger system, an environment with which it is considered in thermal equilibrium. Any small fluctuation of the environment has some random effect on the system. In physics, stochastic methods have been applied to the investigation of phase transitions, thermal and electrical noise, thermal relaxation, quantum information, Brownian motion and so on. In this review, we will focus on the so-called stochastic Schrödinger equation. This is useful as a starting point to investigate the dynamics of open quantum systems capable of exchanging energy and momentum with an external environment. We discuss in some detail the general derivation of a stochastic Schrödinger equation and some of its recent applications to spin thermal transport, thermal relaxation, and Bose-Einstein condensation. We thoroughly discuss the advantages of this formalism with respect to the more common approach in terms of the reduced density matrix. The applications discussed here constitute only a few examples of a much wider range of applicability.
The integrable system is constrained strictly by the conservation law during the time evolution, and the nearly integrable system or nonintegrable system is also constrained by the conserved parameters (like the constants of motion) with corresponding generalized Gibbs ensemble (GGE) which is indubitability a powerful tool in the prediction of thr relaxation dynamics. For stochastic evolution dynamic with considerable noise, the obviously quantum or thermal correlations which don't exhibit the thermal behavior, (like the density of kinks or transverse magnetization correlators), display a asymptotic nonthermalization, and in fact it's a asymptotic quasisteady state with a infinte temperature, therefore the required distance to the nonthermal steady state is in a infinite time average. In this paper, we unambiguously investigate the relaxation of a nonequilibrium system in a canonical ensemble for integrable system or nonintegrable system, and the temporal behavior of many-body quantum system and the macroscopic system, as well as the corresponding linear-coupling between harmonic oscillators. Matrix-method in entropy ensemble is also utilized to discuss the boundary and the important diagonalization, the approximation by the perturbation theory is also obtained.
Von Neumann defined the informational entropy of a density matrix ρ by the expression S(ρ)=−tr(ρ ln ρ). [J. Von Neumann, Die Mathematischen Grundlagen der Quantummechanik (Springer-Verlag, Berlin, 1932)]. Here, starting from the definitions of Shannon entropy and of Renyi entropy of random variables, and using some (reasonable) rules of inference, two expressions are obtained for the quantum entropy of a given square (deterministic) matrix, irrespective of any probabilistic framework and/or any randomization technique. These definitions apply directly to linear operators on Hilbert spaces even when they are not of positive trace class, and they contain Von Neumann entropy as a special case. These new measures of uncertainty could provide new approaches to some problems related to structure complexity.