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Chemical Physics Letters

Time-to-energy transform of wavepackets using absorbing potentials. Time-independent wavepacket-Schrödinger and wavepacket-Lippmann—Schwinger equations

Donald Jack Kouri, Mark Arnold, David K. Hoffman

Published Feb 1, 1993• 72 citations
Publisher
DOI
10.1016/0009-2614(93)85382-x

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Time-independent wave-packet forms of the Schr\"odinger equation (TIWSE) and Lippmann-Schwinger equation (TIWLSB) have been derived by a partial time-to-energy Fourier transform of L2{\mathit{L}}^{2}L2 wave-packet solutions to the time-dependent Schr\"odinger equation. The new equations retain the initial wave packet \ensuremath{\chi}(t0{\mathit{t}}_{0}t0​) as a ``universal source'' of scattered waves, which applies for all collision energies E contained in the initial wave packet. The relationship between the solution ${\mathrm{\ensuremath{\Psi}}}_{\mathit{t}0}$(E) of the TIWSE or TIWLSE and the scattering solution ${\mathrm{\ensuremath{\Psi}}}^{(+)}$(E) of the standard time-independent Lippmann-Schwinger or Schr\"odinger equation is given and the method illustrated by a computational application.