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Physical Review A

Radiative transition processes between initial and final channels

Cheng Zhu, Jianguo Wang, Yi-Zhi Qu, Jiaming Li

Published Mar 1, 1998• 9 citations
Publisher

Abstract

Based on multichannel quantum-defect theory, a method to calculate and compile radiative transition processes for atoms (including highly ionized high-$Z$ atoms) is proposed. Through defining the renormalized transition matrix elements from initial eigenchannels to final eigenchannels, the transition processes between infinitely many initial states and infinitely many final states can be treated conveniently. As illustrative examples, we study the alkali-metal atoms in detail.

DOI
10.1103/physreva.57.1747

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Based on multichannel quantum-defect theory, a method to calculate and compile radiative transition processes for atoms (including highly ionized high-ZZZ atoms) is proposed. Through defining the renormalized transition matrix elements from initial eigenchannels to final eigenchannels, the transition processes between infinitely many initial states and infinitely many final states can be treated conveniently. As illustrative examples, we study the alkali-metal atoms in detail.
We present a general method for calculating two-photon processes in real atoms by a variant of the usual multichannel quantum-defect theory (MQDT). Most notably, this method enables us to describe processes in which a single photon has enough energy to ionize the atom (above-threshold processes). All effects of intermediate Rydberg series, continua, or autoionizing series are treated on an equal footing and with the same ease; the final state is also treated properly by standard MQDT. This method should also work for many three- or four-photon processes.
By combining the quantum theory of radiative transition with multichannel quantum-defect theory, we have derived a general formula to calculate the lifetimes of highly excited states for atoms. As an example, we have evaluated the lifetimes for the perturbed 6snd 1D2^{1}D_{2}1D2​ (n=8--40) and 6snd 3D2^{3}D_{2}3D2​ (n=10--26) Rydberg levels, and the perturbers of the ytterbium atom. We have not only obtained results that are in perfect agreement with the recent measurements, but also predicted the lifetimes of 18 other highly excited states. The results indicate that the dramatic variation for lifetimes of Rydberg states in the vicinity of perturbing states is due to the strong channel interaction.
Radiative processes, where a photon/neutrino is emitted as a result of a collision or decay of a particle, play a central role in atomic, nuclear, and particle physics. Their rate is determined by certain off-diagonal matrix elements between different initial and final states. We propose a method to compute them using quantum computers. It relies on a single extra qubit that, in a certain sense, represents the photon/neutrino. The generic formula relating this matrix element to the amplitude and frequency of oscillations of the extra qubit is derived for the near-resonance case. We demonstrate the feasibility of the method by using it in actual quantum computations and simulations of simple systems.
The radial electric dipole moments of bound-bound, bound-free, and free-free transitions of high-lying (n>15)(n>15)(n>15) Rydberg states and low-lying continuum states $(\ensuremath{\epsilon}<400$ ${\mathrm{cm}}^{\ensuremath{-}1})$ are calculated for hydrogen and the alkali-metal atoms. All dipole matrix elements for the transitions between low-lll (s(s(s, ppp, ddd, and f)f)f) states of H, Li, and Rb are presented. Results of similar calculations for the other alkali-metal atoms (Na, K, and Cs) are summarized. These numerical results, using quantum defect theory, are compared with semiclassical approximations. The dipole matrix elements cross zero at certain combinations of initial and final states. The matrix elements at these so-called Cooper minima in Li, K, Rb, and Cs are presented in detail.