Physical Review A

Electronic spin-flipping collisions of hydrogen atoms

Bernard Zygelman

Published Mar 8, 2010• 7 citations

Abstract

We present a unified multichannel approach to calculate electron spin-exchange and spin-flipping transition cross sections for collisions of H with H, H with T, and T with T. We use the theory to calculate the hyperfine quenching cross sections for collision energies that range from $1$ mK to thermal temperatures. We show that spin-flipping transitions are induced by the splitting of the $b {}^{3}{\ensuremath{\Sigma}}_{u}$ Born-Oppenheimer potential via the long-range magnetic interactions among electrons. We find that the spin-flipping cross sections in the tritium dimer are about a magnitude larger than that predicted by mass scaling the H-H cross sections. For the former, we show that the spin-exchange cross sections are several magnitudes larger, at cold temperatures, than that of the hydrogen system. We compare the results of the multichannel approach with those obtained using approximate methods such as the degenerate internal-state, the elastic, and Born approximations and discuss their respective range of validity.

DOI: 10.1103/physreva.81.032506

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Physical Review AApr 10, 200315 citations

Physical Review A

Electronic spin-flipping collisions of hydrogen atoms

Bernard Zygelman

Published Mar 8, 2010• 7 citations

Publisher

Abstract

1

mK to thermal temperatures. We show that spin-flipping transitions are induced by the splitting of the

b {}^{3}{\ensuremath{\Sigma}}_{u}

Born-Oppenheimer potential via the long-range magnetic interactions among electrons. We find that the spin-flipping cross sections in the tritium dimer are about a magnitude larger than that predicted by mass scaling the H-H cross sections. For the former, we show that the spin-exchange cross sections are several magnitudes larger, at cold temperatures, than that of the hydrogen system. We compare the results of the multichannel approach with those obtained using approximate methods such as the degenerate internal-state, the elastic, and Born approximations and discuss their respective range of validity.

DOI: 10.1103/physreva.81.032506

Related papers

Elastic and spin-changing cross sections of spin-polarized atomic tritium

M. G. Elliott, B. J. P. Jones

The rates of elastic and inelastic scattering processes of spin-polarized atomic tritium are vital inputs for the design and operation of experiments using cold, magnetically trapped tritium atoms. Elastic scattering dominates the total cross section and dictates the thermophysical properties of the vapor, determining the efficiency of magnetic evaporative cooling and the fluid dynamical properties of the trapped atom cloud. Spin-changing cross sections in both exchange and dipolar channels determine the trap lifetime of the various hyperfine states, imposing constraints on the required atomic tritium supply rate to maintain a given trap density. Motivated by the needs of next-generation spectrometers that will study the tritium beta end point to infer the mass of the neutrino, we present new calculations of the elastic, spin-exchange, and dipolar cross sections for spin-polarized atomic tritium. Cross sections and rate constants are reported for magnetic field strengths of 0--10 T and temperatures from 0 to 100 K in all relevant Zeeman-hyperfine channels for both tritium and hydrogen. Results are benchmarked against past calculations for atomic hydrogen and the limited available results for tritium, and extend far into the regimes where past calculations have not been available.The rates of elastic and inelastic scattering processes of spin-polarized atomic tritium are vital inputs for the design and operation of experiments using cold, magnetically trapped tritium atoms. Elastic scattering dominates the total cross section and dictates the thermophysical properties of the vapor, determining the efficiency of magnetic evaporative cooling and the fluid dynamical properties of the trapped atom cloud. Spin-changing cross sections in both exchange and dipolar channels determine the trap lifetime of the various hyperfine states, imposing constraints on the required atomic tritium supply rate to maintain a given trap density. Motivated by the needs of next-generation spectrometers that will study the tritium beta end point to infer the mass of the neutrino, we present new calculations of the elastic, spin-exchange, and dipolar cross sections for spin-polarized atomic tritium. Cross sections and rate constants are reported for magnetic field strengths of 0--10 T and temperatures from 0 to 100 K in all relevant Zeeman-hyperfine channels for both tritium and hydrogen. Results are benchmarked against past calculations for atomic hydrogen and the limited available results for tritium, and extend far into the regimes where past calculations have not been available.

arXiv:2509.13426Physical Review ANov 20, 20251 citation

Spin-exchange cross sections for hydrogen-atom–alkali-metal-atom collisions

H. R. Cole, R. E. Olson

The pseudopotential molecular-structure method has been used to calculate the ${X}^{1}$ \ensuremath{\Sigma} and ${a}^{3}$ \ensuremath{\Sigma} interaction potentials for the alkali-metal-atom--hydrogen-atom systems. These potentials were then used in a quantum-mechanical calculation to determine the spin-exchange cross sections in the energy range from 2.5\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}4}$ eV to 2.5 eV. The cross sections follow the general form ${Q}^{1/2}$ =a-b lnv. However, abundant structure on the cross sections is present due to orbiting resonances induced by the deeply bound well of the ${X}^{1}$ \ensuremath{\Sigma} molecular state. The spin-exchange cross sections range from 17\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$ to 25\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$ ${\mathrm{cm}}^{2}$ at room temperature for H(F=1) transferring to H(F=0) in collision with unpolarized lithium and cesium, respectively.The pseudopotential molecular-structure method has been used to calculate the ${X}^{1}$\ensuremath{\Sigma} and ${a}^{3}$\ensuremath{\Sigma} interaction potentials for the alkali-metal-atom--hydrogen-atom systems. These potentials were then used in a quantum-mechanical calculation to determine the spin-exchange cross sections in the energy range from 2.5\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}4}$ eV to 2.5 eV. The cross sections follow the general form ${Q}^{1/2}$=a-b lnv. However, abundant structure on the cross sections is present due to orbiting resonances induced by the deeply bound well of the ${X}^{1}$\ensuremath{\Sigma} molecular state. The spin-exchange cross sections range from 17\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$ to 25\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$ ${\mathrm{cm}}^{2}$ at room temperature for H(F=1) transferring to H(F=0) in collision with unpolarized lithium and cesium, respectively.

Physical Review AApr 1, 198525 citations

Spin exchange in hydrogen–antihydrogen collisions

Alexei Yu. Voronin, Piotr Froelich

We consider the spin-exchange in ultracold collisions of hydrogen ( $H$ ) and antihydrogen ( $\bar{H}$ ) atoms. The cross sections for transitions between various hyperfine states are calculated. We show that the process of spin exchange in $\bar{H}-H$ collisions is basically driven by the strong force between proton and antiproton, that spin-exchange cross-sections are proportional to the difference of singlet and triplet strong force S-wave scattering lengths, while the strong force effects are enhanced about $10^9$ times due to long range atomic forces. We show that any difference in hyperfine structure of $H$ and $\bar{H}$ (CPT violation) manifests itself in radical change of spin-exchange cross-sections energy behavior.We consider the spin-exchange in ultracold collisions of hydrogen ($H$) and antihydrogen ($\bar{H}$) atoms. The cross sections for transitions between various hyperfine states are calculated. We show that the process of spin exchange in $\bar{H}-H$ collisions is basically driven by the strong force between proton and antiproton, that spin-exchange cross-sections are proportional to the difference of singlet and triplet strong force S-wave scattering lengths, while the strong force effects are enhanced about $10^9$ times due to long range atomic forces. We show that any difference in hyperfine structure of $H$ and $\bar{H}$ (CPT violation) manifests itself in radical change of spin-exchange cross-sections energy behavior.

arXiv:0907.4444Journal of Physics B Atomic Molecular and Optical PhysicsJun 1, 20092 citations

Potential Scattering and Spin-Exchange Cross Sections in Atomic Hydrogen at Very Low Energies

Naoto Koyama, James C. Baird

Potential scattering and spin-exchange scattering cross sections in the energy range from 10 -3 cm -1 to 100 cm -1 have been calculated numerically for hydrogen atoms in collision based on the most accurate Kołos-Woniewicz adiabatic potentials available at present. The scattering lengths for the singlet and triplet states are calculated to be a 0 s =0.595 a.u. and a 0 t =1.34 a.u., respectively. The quasi-bound state with ν=14 and l =4 is found to be at E =1.675 cm -1 above the dissociation limit. The thermally averaged spin-exchange cross section has the low temperature limit \barσ ex (0 K)=0.982 A 2 with a minimum \barσ ex (2.5 K)=0.329 A 2 .Potential scattering and spin-exchange scattering cross sections in the energy range from 10 -3 cm -1 to 100 cm -1 have been calculated numerically for hydrogen atoms in collision based on the most accurate Kołos-Woniewicz adiabatic potentials available at present. The scattering lengths for the singlet and triplet states are calculated to be a 0 s =0.595 a.u. and a 0 t =1.34 a.u., respectively. The quasi-bound state with ν=14 and l =4 is found to be at E =1.675 cm -1 above the dissociation limit. The thermally averaged spin-exchange cross section has the low temperature limit \barσ ex (0 K)=0.982 A 2 with a minimum \barσ ex (2.5 K)=0.329 A 2 .

Journal of the Physical Society of JapanMar 15, 198616 citations

Collisions of cold antiprotonic helium atoms and ions with ordinary helium atoms

Grigory Ya. Korenman, S. N. Yudin

We consider two types of collisional processes with excited antiprotonic helium systems. (i) Transitions between hyperfine structure sublevels in ( He + ) n LFJ are considered at T ≤ 25 K using the coupled-channels method and a model of scalar and tensor interactions between antiprotonic and ordinary He atoms. Inelastic cross sections for the single and double spin-flip transitions are less than elastic ones by four and seven orders of magnitude, respectively. The cross sections show a resonance behaviour at E ∼ 1–4 K, and therefore the relaxation rates, density shift and broadening of the M1 spectral lines decrease with increasing temperature from 3 to 25 K. (ii) Stark transitions and induced annihilation during collisions of the ( He 2+ ) nl ion with He atoms at E ∼ 10 K are considered for all l -states at n ∼ 30 in the framework of the coupled-channels method. In order to take into account complex energy shifts of the ns and np -states, we introduce modified boundary conditions in these channels. The main contribution to elastic scattering, Stark transitions and induced annihilations during collisions comes from the long-range polarization interaction. Admixtures of ns and np -states to nl -states ( l ≥ 2) during collisions induce the effective annihilation cross sections for the initial l up to 15, but don't affect the Stark cross sections for states with nearly-circular orbits. The calculated values for both types of processes are compatible with recent experimental data.We consider two types of collisional processes with excited antiprotonic helium systems. (i) Transitions between hyperfine structure sublevels in ( He + ) n LFJ are considered at T ≤ 25 K using the coupled-channels method and a model of scalar and tensor interactions between antiprotonic and ordinary He atoms. Inelastic cross sections for the single and double spin-flip transitions are less than elastic ones by four and seven orders of magnitude, respectively. The cross sections show a resonance behaviour at E ∼ 1–4 K, and therefore the relaxation rates, density shift and broadening of the M1 spectral lines decrease with increasing temperature from 3 to 25 K. (ii) Stark transitions and induced annihilation during collisions of the ( He 2+ ) nl ion with He atoms at E ∼ 10 K are considered for all l -states at n ∼ 30 in the framework of the coupled-channels method. In order to take into account complex energy shifts of the ns and np -states, we introduce modified boundary conditions in these channels. The main contribution to elastic scattering, Stark transitions and induced annihilations during collisions comes from the long-range polarization interaction. Admixtures of ns and np -states to nl -states ( l ≥ 2) during collisions induce the effective annihilation cross sections for the initial l up to 15, but don't affect the Stark cross sections for states with nearly-circular orbits. The calculated values for both types of processes are compatible with recent experimental data.

Journal of Physics Conference SeriesNov 1, 20079 citations

Cold collisions of spin-polarized metastable hydrogen atoms

Robert C. Forrey, S. Jonsell, Alejandro Sáenz +2 more

Cross sections and rate coefficients for collisions of two spin-polarized metastable hydrogen atoms are calculated at low energies and temperatures using complex scaling and Feshbach projection methods for the determination of the molecular potential-energy curves. The inclusion of the Lamb shift and fine-structure splitting of the excited $n=2$ atoms leads to an attractive van der Waals potential for two ${2s}_{1/2}$ atoms with an exceptionally large coefficient. The quenching of the metastable atoms is dominated at temperatures below 20 mK by ionization. The calculated values for the total loss rate coefficient at 87 \ensuremath{\mu}K and 230 \ensuremath{\mu}K are within a factor of 2 or 3 of the error bars of recent measurements of metastable loss rate coefficients.Cross sections and rate coefficients for collisions of two spin-polarized metastable hydrogen atoms are calculated at low energies and temperatures using complex scaling and Feshbach projection methods for the determination of the molecular potential-energy curves. The inclusion of the Lamb shift and fine-structure splitting of the excited $n=2$ atoms leads to an attractive van der Waals potential for two ${2s}_{1/2}$ atoms with an exceptionally large coefficient. The quenching of the metastable atoms is dominated at temperatures below 20 mK by ionization. The calculated values for the total loss rate coefficient at 87 \ensuremath{\mu}K and 230 \ensuremath{\mu}K are within a factor of 2 or 3 of the error bars of recent measurements of metastable loss rate coefficients.

Physical Review AApr 10, 200315 citations

1

mK to thermal temperatures. We show that spin-flipping transitions are induced by the splitting of the

b {}^{3}{\ensuremath{\Sigma}}_{u}

The pseudopotential molecular-structure method has been used to calculate the

{X}^{1}

\ensuremath{\Sigma} and

{a}^{3}

\ensuremath{\Sigma} interaction potentials for the alkali-metal-atom--hydrogen-atom systems. These potentials were then used in a quantum-mechanical calculation to determine the spin-exchange cross sections in the energy range from 2.5\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}4}$ eV to 2.5 eV. The cross sections follow the general form

{Q}^{1/2}

=a-b lnv. However, abundant structure on the cross sections is present due to orbiting resonances induced by the deeply bound well of the

{X}^{1}

\ensuremath{\Sigma} molecular state. The spin-exchange cross sections range from 17\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$ to 25\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}16}$

{\mathrm{cm}}^{2}

at room temperature for H(F=1) transferring to H(F=0) in collision with unpolarized lithium and cesium, respectively.

We consider the spin-exchange in ultracold collisions of hydrogen (

H

) and antihydrogen (

\bar{H}

) atoms. The cross sections for transitions between various hyperfine states are calculated. We show that the process of spin exchange in

\bar{H}-H

collisions is basically driven by the strong force between proton and antiproton, that spin-exchange cross-sections are proportional to the difference of singlet and triplet strong force S-wave scattering lengths, while the strong force effects are enhanced about

10^9

times due to long range atomic forces. We show that any difference in hyperfine structure of

H

and

\bar{H}

(CPT violation) manifests itself in radical change of spin-exchange cross-sections energy behavior.

n=2

atoms leads to an attractive van der Waals potential for two

{2s}_{1/2}

atoms with an exceptionally large coefficient. The quenching of the metastable atoms is dominated at temperatures below 20 mK by ionization. The calculated values for the total loss rate coefficient at 87 \ensuremath{\mu}K and 230 \ensuremath{\mu}K are within a factor of 2 or 3 of the error bars of recent measurements of metastable loss rate coefficients.