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Reports on Mathematical Physics

Entropy increase for a class of dynamical maps

Garani Ananthakrishna, E. C. G. Sudarshan, Vittorio Gorini

Published Aug 1, 1975• 8 citations
Publisher
DOI
10.1016/0034-4877(75)90015-4

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Entropy plays a fundamental role in several branches of physics. In the quantum setting, one usually considers the von Neumann entropy, but other useful quantities have been proposed in the literature; e.g., the Rényi and the Tsallis entropies. The evolution of an open quantum system, described by a semigroup of dynamical maps (in short, a dynamical semigroup), may decrease a quantum entropy, for some initial condition. We will discuss various characterizations of those dynamical semigroups that, for every initial condition, do not decrease a general class of quantum entropies, which is defined using the notion of Schur concavity of a function. We will not assume that such a dynamical semigroup be completely positive, the physical justification of this condition being controversial. Therefore, we will consider semigroups of trace-preserving, positive — but not necessarily completely positive — linear maps. We will next focus on a special class of (completely positive) dynamical semigroups, the twirling semigroups , having applications in quantum information science. We will argue that the whole class of dynamical semigroups that do not decrease a quantum entropy can be obtained as a suitable generalization of the twirling semigroups.
In the weak-coupling limit approach to open quantum systems, the presence of the bath is eliminated and accounted for by a master equation that introduces dissipative contributions to the system reduced dynamics: within this framework, there are no bath entropy contributions to the entropy balance. We show that, as a consequence, the entropy production fails to be positive for a class of physically legitimate, that is completely positive and trace preserving, non-Markovian dynamical maps. Moreover, in absence of the semigroup property, if the reduced dynamics has a thermal asymptotic state, this need not be stationary. Then even the integrated entropy production becomes negative. These observations imply that, when the conditions leading to reduced dynamics of semigroup type are relaxed, a consistent formulation of the second law of thermodynamics requires that the environment contribution to the entropy balance be explicitly taken into account.
We investigate quantum dynamical systems defined on a finite dimensional Hilbert space and subjected to an interaction with an environment. The rate of decoherence of initially pure states, measured by the increase of their von Neumann entropy, averaged over an ensemble of random pure states, is proved to be bounded from above by the partial entropy used to define the ALF dynamical entropy. The rate of decoherence induced by the sequence of the von Neumann projectors measurements is shown to be maximal, if the measurements are performed in a randomly chosen basis. The numerically observed linear increase of entropies is attributed to free-independence of the measured observable and the unitary dynamical map.